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A series of porous interpenetrating metal–organic frameworks based on fluorescent ligands for nitroaromatic explosive detection 认领 引用 被引量:4
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作者 Xiao-Shan Zeng Hui-Ling Xu +4 位作者 Yu-Ci Xu Xiao-Qing Li Zhao-Yang Nie Shu-Zhen Gao Dong-Rong Xiao 《Inorganic Chemistry Frontiers》 SCIE EI 2018年第7期1622-1632,共11页
Four porous interpenetrating metal–organic frameworks(MOFs),namely,[Cd2(Tipb)2(btc)Cl]·Gx(1),[Cd(Tipb)(tdc)]·Gx2,[Cd(Tipb)(fdc)]·Gx(3),and[Cd5(Tipb)4(btc)2Cl2(DMF)2(H2O... Four porous interpenetrating metal–organic frameworks(MOFs),namely,[Cd2(Tipb)2(btc)Cl]·Gx(1),[Cd(Tipb)(tdc)]·Gx2,[Cd(Tipb)(fdc)]·Gx(3),and[Cd5(Tipb)4(btc)2Cl2(DMF)2(H2O)5]·Cl2·Gx(4)(G=guest molecules,Tipb=1,3,5-tris(p-imidazolylphenyl)benzene,btc=benzene-1,3,5-tricarboxylic acid,tdc=thiophene-2,5-dicarboxylic acid,fdc=furan-2,5-dicarboxylic acid,and DMF=N,N′-dimethylformamide)have been assembled fromπ-electron-rich ligands and cadmium salts.These four MOFs exhibit strong fluorescent emissions upon excitation at room temperature. 展开更多
关键词 electron rich ligands fluorescent ligands cadmium salts nitroaromatic explosive detection metal organic frameworks mofs namely cd tipb btc cl g x cd tipb tdc g x cd tipb fdc g x cd tipb btc cl dmf h o cl g x g guest porous interpenetrating metal organic frameworks cadmium saltsthese
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