Ecological resilience(ER)reflects an ecosystem's capacity to adapt to climate change,natural disturbances,and human-induced stress.This study evaluated ER in the Qinling-Daba Mountains(QDM),China,from 2000 to 2020...Ecological resilience(ER)reflects an ecosystem's capacity to adapt to climate change,natural disturbances,and human-induced stress.This study evaluated ER in the Qinling-Daba Mountains(QDM),China,from 2000 to 2020 using a resistance-robustnessrecovery model.Specifically,the PLUS model was employed to assess the impacts of land use change on ER under three scenarios:natural development(NDS),ecological preservation(EPS),and farmland preservation(FPS).Spatial drivers of ER were analyzed using the geographic detector model and multi-scale geographically weighted regression.The results revealed a significant upward trend in ER,with high values in central and southern QDM and low values in urban lowland areas.Regarding the scenarios,ER improved under EPS,plateaued under NDS,and declined under FPS.The key drivers were found to be NDVI,slope,DEM,temperature,and nighttime light.ER showed positive correlations with high NDVI and slope and negative correlations with low vegetation and flat terrain.These findings provide deeper insight into ER dynamics and scientific guidance for regional ecological protection,planning,and resilience building in the QDM and similar mountainous ecosystems globally.展开更多
Background The differences in egg production performance among hens are closely linked to the efficiency of follicle selection,which is characterized by granulosa cell differentiation and progesterone production.In th...Background The differences in egg production performance among hens are closely linked to the efficiency of follicle selection,which is characterized by granulosa cell differentiation and progesterone production.In this study,by integrating ATAC-seq and mRNA-seq analyses on granulosa cells from pre-hierarchical(Pre-GCs)and hierarchical(Post-GCs)follicles,we set out to identify key regulatory factors involved in chicken follicle selection.Results ATAC-seq analysis revealed 21,616 upregulated and 6,344 downregulated differentially accessible peaks in Post-GCs compared to Pre-GCs.Enrichment analysis of the top 400 upregulated and downregulated peaks(ranked by|log2FC|)identified 106 upregulated and 81 downregulated genes encoding transcription factors(TFs).mRNA-seq analysis showed 1,337 upregulated and 2,282 downregulated differentially expressed genes in Post-GCs compared to Pre-GCs.Among these,146 genes were uniquely expressed in Pre-GCs,and 40 genes were uniquely expressed in Post-GCs.Integrated ATAC-seq and mRNA-seq analyses revealed that chromatin accessibility and gene expression were not always positively correlated.Additionally,four significantly upregulated core TFs(CREM,ESRRB,NR5A1,GATA6)and one significantly downregulated TF(ETS1)genes were identified.The upregulated TFs were associated with 651significantly upregulated target genes across both mRNA and ATAC-seq data,while the downregulated TFs were associated with 236 significantly downregulated target genes.KEGG enrichment of these target genes identified core genes enriched in pathways closely related to follicle selection,such as Wnt signaling pathway.In the protein-protein interaction(PPI)network of core upregulated target genes,genes such as SMAD2 and PPARA occupied central positions,while genes such as LEF1 and RAC2 were central in the PPI network of core downregulated target genes.Among these core TFs,GATA6 is confirmed to promote the expression of key cholesterol and progesterone synthesis genes to enhance both cholesterol and progesterone production,with follicle-stimulating hormone further amplifying its effect on progesterone synthesis.Conclusions Our integrated ATAC-seq and mRNA-seq analyses define key epigenetic and transcriptional changes during chicken follicle selection.We highlight core transcription factors,including CREM,ESRRB,NR5A1,GATA6and ETS1,and their stage-specific target networks.Functional assays show that GATA6 promotes cholesterol and progesterone synthesis,providing mechanistic insight and candidate targets for improving hen reproductive performance.展开更多
The study aims to investigate the carbonated water erosion mechanism of lining concrete in tunnels traversing karst environment and enhance its resistance.In this study,dynamic carbonated water erosion was simulated t...The study aims to investigate the carbonated water erosion mechanism of lining concrete in tunnels traversing karst environment and enhance its resistance.In this study,dynamic carbonated water erosion was simulated to assess erosion depth,microstructure,phase migrations,and pore structure in various tunnel lining cement-based materials.Additionally,Ca2+leaching was analyzed,and impact of Ca/Si molar ratio in hydration products on erosion resistance was discussed by thermodynamic calculations.The results indicate that carbonated water erosion caused rough and porous surface on specimens,with reduced portlandite and CaCO3 content,increased porosity,and an enlargement of pore size.The thermodynamic calculations indicate that the erosion is spontaneous,driven by physical dissolution and chemical reactions dominated by Gibbs free energy.And the erosion reactions proceed more spontaneously and extensively when Ca/Si molar ratio in hydration products was higher.Therefore,cement-based materials with higher portlandite content exhibit weaker erosion resistance.Model-building concrete,with C-S-H gel and portlandite as primary hydration products,has greater erosion susceptibility than shotcrete with ettringite as main hydration product.Moreover,adding silicon-rich mineral admixtures can enhance the erosion resistance.This research offers theory and tech insights to boost cement-based material resistance against carbonated water erosion in karst tunnel engineering.展开更多
BACKGROUND Insomnia is a common sleep disorder that negatively impacts quality of life and is frequently comorbid with depression and anxiety.Chronic insomnia affects approximately 15%of the global population,with hig...BACKGROUND Insomnia is a common sleep disorder that negatively impacts quality of life and is frequently comorbid with depression and anxiety.Chronic insomnia affects approximately 15%of the global population,with higher prevalence among females and the elderly.While existing research suggests a bidirectional relationship between insomnia and emotional disorders,the specific impact of insomnia severity on depression,anxiety,and quality of life remains unclear.This study investigates the correlation between insomnia severity and these factors in psychiatric outpatients,hypothesizing that greater insomnia severity is associated with higher levels of depression and anxiety,as well as poorer quality of life.AIM To explore the correlation between insomnia severity and depression,anxiety,and quality of life in primary chronic insomnia patients.METHODS From June to December 2023,345 patients with primary insomnia in Chifeng city were recruited and divided into three groups based on Pittsburgh sleep quality index(PSQI)scores:Mild(n=137),moderate(n=162),and severe(n=46).Demographic data were collected via questionnaires.Self-rating depression scale(SDS),self-rating anxiety scale(SAS),PSQI,and short form 36(SF-36)scores were compared,and Pearson and partial correlation analyses were performed.RESULTS The greater the degree of insomnia,the greater the symptoms of depression and anxiety(P<0.001).The more severe the insomnia,the lower the SF-36 score(excluding body pain),and the difference between the three groups was statist ically significant(P<0.001).Pearson correlation analysis and partial correlation analysis depicted the SDS score and SAS score were apparently positively correlated with the severity of insomnia(P<0.001).Pearson correlation analysis and partial correlation analysis depicted the SF-36 scores were apparently positively correlated with the severity of insomnia(P<0.05).CONCLUSION Depression and anxiety are independent factors influencing insomnia severity in primary chronic insomnia patients.Higher depression/anxiety levels correlate with worse insomnia,impacting quality of life.展开更多
Micro-arc oxidation (MAO) method was used for the surface modification of an Mg-5wt.%Li alloy. Ceramic coatings were in-situ fabricated on the Mg-Li alloy. The morphology feature,phase composition,and corrosion-resist...Micro-arc oxidation (MAO) method was used for the surface modification of an Mg-5wt.%Li alloy. Ceramic coatings were in-situ fabricated on the Mg-Li alloy. The morphology feature,phase composition,and corrosion-resistance of the formed ceramic coatings were studied by SEM,XRD,and electrochemical methods,respectively. The results showed that the coatings produced in a sodium silicate solution system were composed of MgO and Mg2SiO4. The ceramic coating became thicker and the content of Mg2SiO4 phase increase...展开更多
The precipitation evolution and mechanical properties of a commercial Al-Cu-Li-Mg alloy in natural aging(NA)tempers(T3 and T4)were investigated in detail.It was demonstrated that GPI zones were the pre-dominant precip...The precipitation evolution and mechanical properties of a commercial Al-Cu-Li-Mg alloy in natural aging(NA)tempers(T3 and T4)were investigated in detail.It was demonstrated that GPI zones were the pre-dominant precipitate throughout the NA process.In the T3-aged sample,the precipitation sequence was determined:supersaturated solid solution(SSSS)→atom clusters→GPI zones,whereas in the T4-aged sample,it was SSSS→atom clusters→GPI zones→GPI zones+δ/GPI zones/δ.For samples without NA,the strength of the T3 sample was 76.0 MPa higher than that in the T4 sample,which was attributed to the pre-deformation-introduced dislocations.During the early stage of NA,GPI zone nucleation was substantially restricted in the T3 sample,resulting in a much lower number density of GPI zones.It re-tarded the aging response and strength improvement,consequently narrowing the strength difference between T3 and T4 samples.As the NA process progressed,the average diameter of GPI zones in the T4 sample increased to approximately 4.5 nm,accompanied by the formation ofδ/GPI zones/δcomposite precipitate.However,GPI zone growth andδ/GPI zones/δcomposite precipitate formation were signifi-cantly inhibited in the T3 sample,as evidenced by its much smaller average diameter of approximately 2.1 nm and the absence of composite precipitates.It inhibited the strength improvement of the T3 sam-ple.Therefore,after a long period(5 months)of NA,the strength of the T4 sample was about 13.0 MPa higher than that of the T3 samples,instead.展开更多
Microglia are considered to be potential anti- gen-presenting cells and have the ability to present antigen under pathological conditions. Nevertheless, whether and how microglia are involved in immune regulation are ...Microglia are considered to be potential anti- gen-presenting cells and have the ability to present antigen under pathological conditions. Nevertheless, whether and how microglia are involved in immune regulation are lar- gely unknown. Here, we investigated the suppressive activity of microglia during experimental autoimmune encephalomyelitis (EAE) induced by myelin oligodendro- cyte glycoprotein, with the goal of understanding their role in regulating the T cell reaction. Using flow cytometric analysis, we found that microglia were characterized by increased cell number and up-regulated programmed death ligand-1 (PD-L1) at the peak phase of EAE. Meanwhile, both the CD4+ T cells and microglia that infiltrated the central nervous system expressed higher levels of PD1, the receptor for PD-L1, accompanied by a decline of Thl cells. In an ex vivo co-culture system, microglia from EAE mice inhibited the proliferation of antigen-specific CD4+ T cells and the differentiation of Thl cells, and this was significantly inhibited by PD-L 1 blockade. Further, microglia suppressed Thl cells via nitric oxide (NO), the production of which was dependent on PD-L1. Thus, these data suggest a scenario in which microglia are involved in the regulation of EAE by suppressing Thl-cell differenti- ation via the PD-L1-NO pathway.展开更多
Salt-cavern underground gas storage is technically faced with non-uniform distribution of stratified salt rocks,complex solution mining mechanism,difficult control of solution mining process,less operation safety and ...Salt-cavern underground gas storage is technically faced with non-uniform distribution of stratified salt rocks,complex solution mining mechanism,difficult control of solution mining process,less operation safety and stability of caverns and difficult reconstruction and utilization of old caverns.In view of these technical difficulties,the design concept was fully updated based on the design experience and field practice of Jintan gas storage in Jiangsu,for purpose of maximizing salt layer utilization ratio,improving solution mining efficiency,shortening construction time and ensuring cavity safety.Based on the updated design concept,five series of key technologies were proposed in site evaluation,cavern design and control,stability assessment and storage capacity parameter design,old cavern screening and utilization,and gas storage operation and monitoring.The following results were obtained from the actual application of these key technologies to the Jintan gas storage.First,the actual drilling coincidence rate of geological program is high.Second,the cavern is morphologically coincident with the design.Third,the cavern deformation retract rate is in line with the stability evaluation result.Fourth,old caverns are successfully reconstructed and utilized.Fifth,the arrangement of the monitoring network ensures the operation safety of salt-cavern underground gas storage and makes an important contribution to the peak shaving and supply guarantee of natural gas in the Yangtze River Delta region.In conclusion,the research results provide guidance for the design and engineering implementation of salt-cavern underground gas storage construction program,as well as a theoretical and technical support for the construction of similar gas storages.展开更多
The interaction mechanism between sodium arsenate and fayalite-type copper slag at 1200℃was investigated through XRD,XPS,HRTEM,TCLP and other technical means and methods.The results indicated that the proportions of ...The interaction mechanism between sodium arsenate and fayalite-type copper slag at 1200℃was investigated through XRD,XPS,HRTEM,TCLP and other technical means and methods.The results indicated that the proportions of sodium arsenate in the slag and flue gas phases were approximately 30%and 70%,respectively.The addition of sodium arsenate depolymerized the fayalite structure and changed it from a crystalline state to an amorphous state.The fayalite structural changes indicated that the[AsO4]tetrahedron in sodium arsenate combined with the[SiO4]tetrahedron and[FeO4]tetrahedron through bridging oxygen to form a silicate glass structure.The TCLP test results of the samples before and after the high temperature reaction of fayalite and sodium arsenate showed that after high temperature reaction,fayalite could effectively reduce the leaching toxicity of sodium arsenate,reducing the leaching concentration of arsenic from 3025.52 to 12.8 mg/L before and after reaction,respectively.展开更多
At low temperatures the configurational phase space of a macroscopic complex system(e.g.,a spin-glass)of N-10^23 interacting particles may split into an exponential numberΩs-exp(const×N)of ergodic sub-spaces(the...At low temperatures the configurational phase space of a macroscopic complex system(e.g.,a spin-glass)of N-10^23 interacting particles may split into an exponential numberΩs-exp(const×N)of ergodic sub-spaces(thermodynamic states).It is usually assumed that the equilibrium collective behavior of such a system is determined by its ground thermodynamic states of the minimal free-energy density,and that the equilibrium free energies follow the distribution of exponentied decay.But actually for some complex systems,the equilibrium free-energy values may follow a Gaussian distribution within an intermediate temperature range,and consequently their equilibrium properties are contributed by excited thermodynamic states.Based on this analysis,the re-weighting parameter y in the cavity approach of spin-glasses is easily understood.Depending on the free-energy distribution,the optimal y can either be equal to or be strictly less than the inverse temperatureβ.展开更多
基金National Natural Science Foundation of China,No.42341102,No.42572308,No.42102288The National Key Research and Development Program of China,No.2024YFF1306503+2 种基金The Forestry Science and Technology Innovation Project of Shaanxi Province,No.SXLK2023-02-1The Youth Talent Support Program of Shaanxi Association for Science and Technology,No.20240707The Fundamental Research Funds for the Central Universities,CHD,No.300102294202,No.300102294905。
摘要Ecological resilience(ER)reflects an ecosystem's capacity to adapt to climate change,natural disturbances,and human-induced stress.This study evaluated ER in the Qinling-Daba Mountains(QDM),China,from 2000 to 2020 using a resistance-robustnessrecovery model.Specifically,the PLUS model was employed to assess the impacts of land use change on ER under three scenarios:natural development(NDS),ecological preservation(EPS),and farmland preservation(FPS).Spatial drivers of ER were analyzed using the geographic detector model and multi-scale geographically weighted regression.The results revealed a significant upward trend in ER,with high values in central and southern QDM and low values in urban lowland areas.Regarding the scenarios,ER improved under EPS,plateaued under NDS,and declined under FPS.The key drivers were found to be NDVI,slope,DEM,temperature,and nighttime light.ER showed positive correlations with high NDVI and slope and negative correlations with low vegetation and flat terrain.These findings provide deeper insight into ER dynamics and scientific guidance for regional ecological protection,planning,and resilience building in the QDM and similar mountainous ecosystems globally.
基金supported by the National R&D Program of China(grant number 2021YFD1300100)National Natural Science Foundation of China(grant number 32272869)。
摘要Background The differences in egg production performance among hens are closely linked to the efficiency of follicle selection,which is characterized by granulosa cell differentiation and progesterone production.In this study,by integrating ATAC-seq and mRNA-seq analyses on granulosa cells from pre-hierarchical(Pre-GCs)and hierarchical(Post-GCs)follicles,we set out to identify key regulatory factors involved in chicken follicle selection.Results ATAC-seq analysis revealed 21,616 upregulated and 6,344 downregulated differentially accessible peaks in Post-GCs compared to Pre-GCs.Enrichment analysis of the top 400 upregulated and downregulated peaks(ranked by|log2FC|)identified 106 upregulated and 81 downregulated genes encoding transcription factors(TFs).mRNA-seq analysis showed 1,337 upregulated and 2,282 downregulated differentially expressed genes in Post-GCs compared to Pre-GCs.Among these,146 genes were uniquely expressed in Pre-GCs,and 40 genes were uniquely expressed in Post-GCs.Integrated ATAC-seq and mRNA-seq analyses revealed that chromatin accessibility and gene expression were not always positively correlated.Additionally,four significantly upregulated core TFs(CREM,ESRRB,NR5A1,GATA6)and one significantly downregulated TF(ETS1)genes were identified.The upregulated TFs were associated with 651significantly upregulated target genes across both mRNA and ATAC-seq data,while the downregulated TFs were associated with 236 significantly downregulated target genes.KEGG enrichment of these target genes identified core genes enriched in pathways closely related to follicle selection,such as Wnt signaling pathway.In the protein-protein interaction(PPI)network of core upregulated target genes,genes such as SMAD2 and PPARA occupied central positions,while genes such as LEF1 and RAC2 were central in the PPI network of core downregulated target genes.Among these core TFs,GATA6 is confirmed to promote the expression of key cholesterol and progesterone synthesis genes to enhance both cholesterol and progesterone production,with follicle-stimulating hormone further amplifying its effect on progesterone synthesis.Conclusions Our integrated ATAC-seq and mRNA-seq analyses define key epigenetic and transcriptional changes during chicken follicle selection.We highlight core transcription factors,including CREM,ESRRB,NR5A1,GATA6and ETS1,and their stage-specific target networks.Functional assays show that GATA6 promotes cholesterol and progesterone synthesis,providing mechanistic insight and candidate targets for improving hen reproductive performance.
基金Project(2021YJ059)supported by the Research Project of China Academy of Railway Sciences。
摘要The study aims to investigate the carbonated water erosion mechanism of lining concrete in tunnels traversing karst environment and enhance its resistance.In this study,dynamic carbonated water erosion was simulated to assess erosion depth,microstructure,phase migrations,and pore structure in various tunnel lining cement-based materials.Additionally,Ca2+leaching was analyzed,and impact of Ca/Si molar ratio in hydration products on erosion resistance was discussed by thermodynamic calculations.The results indicate that carbonated water erosion caused rough and porous surface on specimens,with reduced portlandite and CaCO3 content,increased porosity,and an enlargement of pore size.The thermodynamic calculations indicate that the erosion is spontaneous,driven by physical dissolution and chemical reactions dominated by Gibbs free energy.And the erosion reactions proceed more spontaneously and extensively when Ca/Si molar ratio in hydration products was higher.Therefore,cement-based materials with higher portlandite content exhibit weaker erosion resistance.Model-building concrete,with C-S-H gel and portlandite as primary hydration products,has greater erosion susceptibility than shotcrete with ettringite as main hydration product.Moreover,adding silicon-rich mineral admixtures can enhance the erosion resistance.This research offers theory and tech insights to boost cement-based material resistance against carbonated water erosion in karst tunnel engineering.
摘要BACKGROUND Insomnia is a common sleep disorder that negatively impacts quality of life and is frequently comorbid with depression and anxiety.Chronic insomnia affects approximately 15%of the global population,with higher prevalence among females and the elderly.While existing research suggests a bidirectional relationship between insomnia and emotional disorders,the specific impact of insomnia severity on depression,anxiety,and quality of life remains unclear.This study investigates the correlation between insomnia severity and these factors in psychiatric outpatients,hypothesizing that greater insomnia severity is associated with higher levels of depression and anxiety,as well as poorer quality of life.AIM To explore the correlation between insomnia severity and depression,anxiety,and quality of life in primary chronic insomnia patients.METHODS From June to December 2023,345 patients with primary insomnia in Chifeng city were recruited and divided into three groups based on Pittsburgh sleep quality index(PSQI)scores:Mild(n=137),moderate(n=162),and severe(n=46).Demographic data were collected via questionnaires.Self-rating depression scale(SDS),self-rating anxiety scale(SAS),PSQI,and short form 36(SF-36)scores were compared,and Pearson and partial correlation analyses were performed.RESULTS The greater the degree of insomnia,the greater the symptoms of depression and anxiety(P<0.001).The more severe the insomnia,the lower the SF-36 score(excluding body pain),and the difference between the three groups was statist ically significant(P<0.001).Pearson correlation analysis and partial correlation analysis depicted the SDS score and SAS score were apparently positively correlated with the severity of insomnia(P<0.001).Pearson correlation analysis and partial correlation analysis depicted the SF-36 scores were apparently positively correlated with the severity of insomnia(P<0.05).CONCLUSION Depression and anxiety are independent factors influencing insomnia severity in primary chronic insomnia patients.Higher depression/anxiety levels correlate with worse insomnia,impacting quality of life.
摘要Micro-arc oxidation (MAO) method was used for the surface modification of an Mg-5wt.%Li alloy. Ceramic coatings were in-situ fabricated on the Mg-Li alloy. The morphology feature,phase composition,and corrosion-resistance of the formed ceramic coatings were studied by SEM,XRD,and electrochemical methods,respectively. The results showed that the coatings produced in a sodium silicate solution system were composed of MgO and Mg2SiO4. The ceramic coating became thicker and the content of Mg2SiO4 phase increase...
摘要The precipitation evolution and mechanical properties of a commercial Al-Cu-Li-Mg alloy in natural aging(NA)tempers(T3 and T4)were investigated in detail.It was demonstrated that GPI zones were the pre-dominant precipitate throughout the NA process.In the T3-aged sample,the precipitation sequence was determined:supersaturated solid solution(SSSS)→atom clusters→GPI zones,whereas in the T4-aged sample,it was SSSS→atom clusters→GPI zones→GPI zones+δ/GPI zones/δ.For samples without NA,the strength of the T3 sample was 76.0 MPa higher than that in the T4 sample,which was attributed to the pre-deformation-introduced dislocations.During the early stage of NA,GPI zone nucleation was substantially restricted in the T3 sample,resulting in a much lower number density of GPI zones.It re-tarded the aging response and strength improvement,consequently narrowing the strength difference between T3 and T4 samples.As the NA process progressed,the average diameter of GPI zones in the T4 sample increased to approximately 4.5 nm,accompanied by the formation ofδ/GPI zones/δcomposite precipitate.However,GPI zone growth andδ/GPI zones/δcomposite precipitate formation were signifi-cantly inhibited in the T3 sample,as evidenced by its much smaller average diameter of approximately 2.1 nm and the absence of composite precipitates.It inhibited the strength improvement of the T3 sam-ple.Therefore,after a long period(5 months)of NA,the strength of the T4 sample was about 13.0 MPa higher than that of the T3 samples,instead.
基金supported by the National Natural Science Foundation of China(81070961,81273212,81202308,81302604,31300730,81172882and 81241052)the Natural Science Foundation of Shandong Province(ZR2011CM037)
摘要Microglia are considered to be potential anti- gen-presenting cells and have the ability to present antigen under pathological conditions. Nevertheless, whether and how microglia are involved in immune regulation are lar- gely unknown. Here, we investigated the suppressive activity of microglia during experimental autoimmune encephalomyelitis (EAE) induced by myelin oligodendro- cyte glycoprotein, with the goal of understanding their role in regulating the T cell reaction. Using flow cytometric analysis, we found that microglia were characterized by increased cell number and up-regulated programmed death ligand-1 (PD-L1) at the peak phase of EAE. Meanwhile, both the CD4+ T cells and microglia that infiltrated the central nervous system expressed higher levels of PD1, the receptor for PD-L1, accompanied by a decline of Thl cells. In an ex vivo co-culture system, microglia from EAE mice inhibited the proliferation of antigen-specific CD4+ T cells and the differentiation of Thl cells, and this was significantly inhibited by PD-L 1 blockade. Further, microglia suppressed Thl cells via nitric oxide (NO), the production of which was dependent on PD-L1. Thus, these data suggest a scenario in which microglia are involved in the regulation of EAE by suppressing Thl-cell differenti- ation via the PD-L1-NO pathway.
基金supported by the CNPC Major Science and Technology Project“Research and Application of Key Technologies in Geology and Gas Reservoir Engineering of Underground Gas Storage”(No.:2015E-400201).
摘要Salt-cavern underground gas storage is technically faced with non-uniform distribution of stratified salt rocks,complex solution mining mechanism,difficult control of solution mining process,less operation safety and stability of caverns and difficult reconstruction and utilization of old caverns.In view of these technical difficulties,the design concept was fully updated based on the design experience and field practice of Jintan gas storage in Jiangsu,for purpose of maximizing salt layer utilization ratio,improving solution mining efficiency,shortening construction time and ensuring cavity safety.Based on the updated design concept,five series of key technologies were proposed in site evaluation,cavern design and control,stability assessment and storage capacity parameter design,old cavern screening and utilization,and gas storage operation and monitoring.The following results were obtained from the actual application of these key technologies to the Jintan gas storage.First,the actual drilling coincidence rate of geological program is high.Second,the cavern is morphologically coincident with the design.Third,the cavern deformation retract rate is in line with the stability evaluation result.Fourth,old caverns are successfully reconstructed and utilized.Fifth,the arrangement of the monitoring network ensures the operation safety of salt-cavern underground gas storage and makes an important contribution to the peak shaving and supply guarantee of natural gas in the Yangtze River Delta region.In conclusion,the research results provide guidance for the design and engineering implementation of salt-cavern underground gas storage construction program,as well as a theoretical and technical support for the construction of similar gas storages.
基金the financial supports from the National Natural Science Foundation of China(No.51634010)National Key R&D Program of China(No.2018YFC1900300).
摘要The interaction mechanism between sodium arsenate and fayalite-type copper slag at 1200℃was investigated through XRD,XPS,HRTEM,TCLP and other technical means and methods.The results indicated that the proportions of sodium arsenate in the slag and flue gas phases were approximately 30%and 70%,respectively.The addition of sodium arsenate depolymerized the fayalite structure and changed it from a crystalline state to an amorphous state.The fayalite structural changes indicated that the[AsO4]tetrahedron in sodium arsenate combined with the[SiO4]tetrahedron and[FeO4]tetrahedron through bridging oxygen to form a silicate glass structure.The TCLP test results of the samples before and after the high temperature reaction of fayalite and sodium arsenate showed that after high temperature reaction,fayalite could effectively reduce the leaching toxicity of sodium arsenate,reducing the leaching concentration of arsenic from 3025.52 to 12.8 mg/L before and after reaction,respectively.
基金supported by National Natural Science Foundation of China under Grant No.10774150
摘要At low temperatures the configurational phase space of a macroscopic complex system(e.g.,a spin-glass)of N-10^23 interacting particles may split into an exponential numberΩs-exp(const×N)of ergodic sub-spaces(thermodynamic states).It is usually assumed that the equilibrium collective behavior of such a system is determined by its ground thermodynamic states of the minimal free-energy density,and that the equilibrium free energies follow the distribution of exponentied decay.But actually for some complex systems,the equilibrium free-energy values may follow a Gaussian distribution within an intermediate temperature range,and consequently their equilibrium properties are contributed by excited thermodynamic states.Based on this analysis,the re-weighting parameter y in the cavity approach of spin-glasses is easily understood.Depending on the free-energy distribution,the optimal y can either be equal to or be strictly less than the inverse temperatureβ.