The effect from the interaction of the alternating current(AC)magnetic field with kilogram-level test mass(TM)limits the detectivity of the TianQin space-based gravitational wave detection.The quantifed effect require...The effect from the interaction of the alternating current(AC)magnetic field with kilogram-level test mass(TM)limits the detectivity of the TianQin space-based gravitational wave detection.The quantifed effect requires the determination of the AC magnetic susceptibilityχ(f)of the TM.A torque method is proposed to measure theχ(f)of kg-level samples at the mHz band with a precision of 1×10-7.Combined with our previous work[Phys.Rev.Appl.18044010(2022)],the general frequency-dependent susceptibility of the alloy cube with side length L and electrical conductivityσis determined asχ(f)=χ0+(0.24±0.01)σμ0L2f from 0.1 mHz to 1 Hz.The determination is helpful for the preliminary estimation of the in-band eddy current efect in the TianQin noise budget.The technique can be adopted to accurately measureχ(f)of the actual TM in other precision experiments,where the magnetic noise is a signifcant detection limit.展开更多
The basic condition of earthquake disasters in China is featured by high frequency,strong intensity,wide distribution,and heavy losses.Earthquake forecasting plays a critical role in reducing seismic risks.To better a...The basic condition of earthquake disasters in China is featured by high frequency,strong intensity,wide distribution,and heavy losses.Earthquake forecasting plays a critical role in reducing seismic risks.To better advance earthquake predicting efforts,the China Earthquake Administration released the Strategic Plan for Earthquake Forecasting in China(2025−2035)on the occasion of the 50th anniversary of the Haicheng earthquake.Here we briefly introduce the main contents of the Strategic Plan,including the main progress,strategic objectives,and development directions of earthquake forecasting in China.展开更多
The application of poly(butylene adipate-co-terephthalate)(PBAT)biodegradable plastics has long been constrained by insufficient light aging resistance.Hindered amine light stabilizers(HALSs),known as eco-friendly add...The application of poly(butylene adipate-co-terephthalate)(PBAT)biodegradable plastics has long been constrained by insufficient light aging resistance.Hindered amine light stabilizers(HALSs),known as eco-friendly additives,can scavenge free radicals to enhance polymer durability.However,rough choices have resulted in wastage of resources and environmental pressure.Based on the application of plastic films as the background for use,this study systematically evaluates application effects of five HALSs.The films underwent accelerated aging for various durations and were further investigated by a combination of experiments and molecular simulation.Results showed that all HALSs mitigated PBAT light aging,with Chimassorb-944(UV-944)and Tinuvin-770(UV-770)performing the best for real applications.Quantum chemical calculation results showed that UV-944 had stronger anti migration ability.After 300 h of aging,films with UV-944 and UV-770 retained superior tensile strength and elongation at break in the transverse direction compared to neat PBAT films.Polymeric HALSs provided better long-term stability than small-molecule ones.Further spectra analysis indicated that stronger C―O bonds in HALS/PBAT composites correlated with improved photostability.This study offers valuable insights into improving weather resistance of PBAT biodegradable films and optimizing the real application of HALSs.展开更多
BACKGROUND Although Helicobacter pylori(H.pylori)can cause a range of gastric diseases and affects approximately 50% of the global population,its routes of transmission have yet to be sufficiently clarified.In a preli...BACKGROUND Although Helicobacter pylori(H.pylori)can cause a range of gastric diseases and affects approximately 50% of the global population,its routes of transmission have yet to be sufficiently clarified.In a preliminary study,we found that H.pylori can reside within the cells of Candida yeasts,with maternal Candida serving as a potential reservoir for the transmission of H.pylori to neonates during delivery.AIM To study the route of H.pylori transmission from mothers to offspring.METHODS We established vaginal and gastric infection models using female C57BL/6J mice infected with H.pylori 16S rDNA and urease A(ureA)genes-positive Candida.The successfully infective female mice were then mated with normal male mice until conception(classified vaginal and cesarean deliveries).The H.pylori infection status in female mice and their offspring was assessed using enzyme-linked immunosorbent assay,polymerase chain reaction,Candida isolation and culture,and histopathological examination.RESULTS The enzyme-linked immunosorbent assay results showed an increase in H.pylori-specific IgG and IgM serum antibodies in the H.pylori-positive Candida group maternal and offspring mice compared to the control and normal groups.H.pylori 16S rDNA or ureA genes was detected in samples from some of the maternal and offspring mice,including gastric mucosa,intestinal contents,vaginal tissue,placenta,and fetal membranes.In addition,H.pylori 16S rDNA-or ureA gene-positive Candida were successfully isolated from the tissues of some postpartum maternal and offspring mice.Moreover,histopathological examination revealed bleeding spots and inflammatory cell infiltration in the gastric mucosal tissues of some maternal mice and offspring in the H.pylori-positive Candida group.CONCLUSION In conclusion,H.pylori infection of newborns may be acquired through vertical transmission during childbirth,potentially originating from the mother’s Candida that has been internalized by H.pylori.展开更多
Two filamentous cyanobacteria,isolated from different habitats in Yunnan Province,China,were described.Phylogenetic analysis and taxonomic identification were performed using a polyphasic approach that included morpho...Two filamentous cyanobacteria,isolated from different habitats in Yunnan Province,China,were described.Phylogenetic analysis and taxonomic identification were performed using a polyphasic approach that included morphological,ecological,and molecular data.Their morphological characteristics and microscopic structures were observed and recorded using an optical microscope.Filaments of the strain SXACC0113 are yellowish-green and relatively wide,ranging from 1.1 to 4.8μm,and the cells are sometimes inflated.Strain SXACC0116 have no false branching,and the apical cells are cylindrical.Phylogenetic trees were constructed using maximum likelihood(ML)and bayesian inference(BI)based on the 16S rRNA gene sequences.The analysis showed that the algal strain SXACC0113 was distributed in the Elainella clade,and its similarity to the 16S rRNA genes of other species in the genus Elainella was 97.9%–98.2%.The strain SXACC0116 was distributed in the Pegethrix clade,and its similarity to the 16S rRNA genes of other species in the genus Pegethrix was 95.4%–97.3%.Additionally,unique forms were found in the D1-D1ʹ,Box B,and V3 helices of the 16S–23S internal transcribed spacer(ITS)secondary structure in these strains.These findings support the establishment of two new species,named Elainella yunnanensis sp.nov.and Pegethrix yunnanensis sp.nov.This discovery increases the diversity of cyanobacterial species in China,provides a scientific basis for further revision and classification of cyanobacteria,and supplements algae research information in China.展开更多
Manganese-based oxides are widely employed as cathode materials for aqueous zinc ion batteries(AZIBs) due to their low toxicity and high theoretical specific capacity.However,their inherent poor electrical conductivit...Manganese-based oxides are widely employed as cathode materials for aqueous zinc ion batteries(AZIBs) due to their low toxicity and high theoretical specific capacity.However,their inherent poor electrical conductivity,coupled with the dissolution of manganese into the electrolyte,often leads to structural degradation of the cathode.To address these challenges,Mn-MOF was utilized as a precursor to synthesize a corncob popcorn-like Mn2O3@C composite with high activity and long lifespan for AZIBs.This distinctive porous carbon encapsulation architecture leverages oxygen vacancies to modulate the spacing of Mn metal oxide layers and alter the valence states of metal ions,thereby enhancing both structural stability and conductivity,and reducing the Zn2+ diffusion path.The porous structure also improves the wettability of the electrode surface and electrolyte penetration,and provides ample and rapid ion transport channels.Consequently,the fabricated corncob popcorn-like Mn2O3@C exhibits an outstanding specific capacity of 570.5 mA h g-1 at 0.1 A g-1 and a capacity retention of over 95% after 3000 cycles at 1 A g-1.The Zn2+ storage mechanism was elucidated through various ex situ characterizations,revealing that the storage mechanism is governed by a mixed H+/Zn2+ co-insertion/de-insertion process.展开更多
The interfacial stress between silicon bottom cell and perovskite top cell remains a critical challenge for flexible perovskite/silicon tandem solar cells,leading to interfacial delamination and device degradation.In ...The interfacial stress between silicon bottom cell and perovskite top cell remains a critical challenge for flexible perovskite/silicon tandem solar cells,leading to interfacial delamination and device degradation.In this work,the effect of the thickness and pyramid size on mechanical properties of silicon wafers are investigated,demonstrating that thinner wafers and smaller pyramids significantly enhance the flexural strength of thin silicon wafers by mitigating stress concentration effects.Based on these findings,a synergistic optimization strategy is proposed that employs precise wet-etching control to fabricate small-sized,high-density,uniform pyramids on 55μm silicon wafers for efficient and flexible perovskite/silicon tandem solar cells.By optimizing the texturing duration,this approach simultaneously enhances the minority carrier lifetime(τ)and achieves an excellent implied open-circuit voltage(iVoc).Furthermore,the uniform submicron-scale pyramid structure promotes high-quality perovskite film formation and improves interfacial contact properties.As a proof of concept,monolithic flexible perovskite/silicon tandem devices fabricated on such uniformly textured pyramids delivered a power conversion efficiency(PCE)of 30.04%.These devices promise for low-cost,lightweight and flexible photovoltaic applications.展开更多
Traditional tools have limited adaptability in complex machining environments due to their lack of working-condition perception and autonomous regulation.With advances in sensors,materials,and data-processing technolo...Traditional tools have limited adaptability in complex machining environments due to their lack of working-condition perception and autonomous regulation.With advances in sensors,materials,and data-processing technologies,tool design is shifting from a single-function‘mechanical arm’for cutting towards integrated intelligent terminals.This paper systematically reviews progress in intelligent tool technology from two perspectives:design and regulation.For intelligent design,the fundamental principles of condition-perception tools equipped with built-in multi-type sensors are discussed,enabling in situ,real-time monitoring of multidimensional parameters such as cutting force,temperature,and vibration.Force monitoring is achieved through elastic deformation or dynamic charge response,temperature monitoring through the thermoelectric effect,and vibration monitoring through micro-displacement and intensity detection.The design focus emphasises sensor miniaturisation and integration,balancing measurement accuracy with tool stiffness while minimising machining interference.In regulation,key technologies for constructing closed-loop control systems(CLCS)are summarised,which dynamically adjust cutting speed,feed rate,and other parameters based on sensed data,achieving precise control of force,temperature,and vibration via feedback mechanisms and driving units.Breakthroughs in tool wear compensation(TWC)mechanisms are introduced.Multi-source signal fusion combined with deep learning algorithms is further examined for improving monitoring accuracy and remaining useful life(RUL)prediction.Through model predictive control,intelligent regulation of cutting parameters within process flows is realised.Finally,challenges such as sensor reliability,multi-source coupling,and balancing cost with industrial applicability are analysed.Future directions highlight novel structural designs,high-performance material development,and multi-technology integration,aiming to establish a fully intelligent machining system through the integrated design of‘perception-decision-execution’.展开更多
Jojoba[Simmondsia chinensis(Link)Schneider]is sensitive to low temperatures,which hinders its cultivation in temperate arid regions.The apoplast is a cellular component outside the plasma membrane of plant cells and i...Jojoba[Simmondsia chinensis(Link)Schneider]is sensitive to low temperatures,which hinders its cultivation in temperate arid regions.The apoplast is a cellular component outside the plasma membrane of plant cells and is widely involved in the response of plants to environmental stress.Here,we used the infiltration-centrifugation method to extract apoplast fluid from jojoba leaves and analyzed changes in the apoplast proteome after cold acclimation using quantitative proteomics.In total,751 apoplast proteins were identified in jojoba,and the abundance of 200 proteins showed significant changes after cold acclimation.These proteins were primarily involved in defense,cell wall modification,carbohydrate metabolism,and redox balance.We also investigated the function and regulation of a cold acclimation-responsive class III chitinase ScCHIA.The results showed that the overexpression of ScCHIA enhanced the tolerance of Arabidopsis,yeast,and jojoba to low temperature and osmotic stress.Under cold stress,ScCHIA-overexpressing Arabidopsis accumulated more osmolytes,activated antioxidant enzymes,and reduced stomatal aperture size,which may contribute to enhanced tolerance to cold stress.ScCHIA was induced by methyl jasmonate(MeJA)application,and electrophoretic mobility shift assay(EMSA),yeast one-hybrid(Y1H),and luciferase activity assays demonstrated that an E-box cis-acting element on the ScCHIA gene promoter mediated regulation of ScCHIA by MeJA signaling,indicating that elevated levels of MeJA caused by cold acclimation may promote the expression of ScCHIA,thereby enhancing the cold tolerance of jojoba.Our research highlights the important role of the apoplast in plant response to low temperature stress and improves the understanding of the functions and regulatory mechanisms of plant chitinases in abiotic stress response.展开更多
The rapid development of wearable electronics,self-powered systems,and the Internet of Things urgently requires efficient thermal management(TM)technologies and sustainable energy solutions.However,triboelectric nanog...The rapid development of wearable electronics,self-powered systems,and the Internet of Things urgently requires efficient thermal management(TM)technologies and sustainable energy solutions.However,triboelectric nanogenerator(TENG)and their integrated electronic components inevitably generate or accumulate Joule thermal.It led to performance degradation or even device failure.This review focuses on the research progress in integrating advanced TM technologies into TENGs,aiming to provide comprehensive insights for constructing high-performance and highly stable self-powered systems.The scope of this review encompasses:(i)systematically summarizing the design and development of TM-TENG systems based on key materials,such as graphene,carbon nanotubes,MXene,cellulose,and phase change materials,(ii)elucidating the bidirectional coupling mechanism between triboelectric charge generation and thermal management,along with a critical analysis of existing theoretical models,and(iii)detailing the multifunctional integration and applications potential of TM-TENGs in the fields including thermal conversion,thermal energy harvesting,storage,actuation,and conduction.The bidirectional coupling mechanisms between triboelectric charge generation and thermal management are thoroughly dissected at a theoretical level.The predominant physical models explaining the interaction phenomena between frictional heating and thermal management are reviewed,with critical analysis of their applicability and limitations.Furthermore,this work discusses the current challenges and future directions in this field and proposes strategic recommendations for realizing more advanced TM-TENG systems.The primary objectives of this review are to synthesize existing knowledge,clarify interaction mechanisms,and promote interdisciplinary development at the intersection of thermal management and energy harvesting.展开更多
Increasing the sucrose content of sugarcane,a major sugar crop,is a key breeding objective.However,the complex genetic background of sugarcane affects development of sugarcane hybrids.In this study,we sequenced 292 su...Increasing the sucrose content of sugarcane,a major sugar crop,is a key breeding objective.However,the complex genetic background of sugarcane affects development of sugarcane hybrids.In this study,we sequenced 292 sugarcane germplasm accessions and identified 2,542,965 single nucleotide polymorphisms(SNPs) and insertions/deletions(InDels).We performed a genome-wide association study(GWAS) for two important sugarcane traits:sucrose content and stem diameter.Both traits followed a normal distribution and showed typical characteristics of quantitative traits.Population structure analysis revealed four subpopulations with an average genetic distance of 0.236.GWAS of the sucrose content detected 27 SNPs.After annotating genes at or near significant loci,17 candidate genes were screened.For stem diameter,GWAS revealed 19 SNPs,from which 9 candidate genes were identified.These results improve our understanding of genetic mechanisms affecting sucrose content in sugarcane,and identify important genetic resources to accelerate breeding of new sugarcane varieties with high sucrose content.展开更多
Bats represent a remarkable mammalian lineage,distinguished by the evolution of powered flight,sophisticated echolocation,exceptional longevity,and robust resistance to viral infections.These adaptations have contribu...Bats represent a remarkable mammalian lineage,distinguished by the evolution of powered flight,sophisticated echolocation,exceptional longevity,and robust resistance to viral infections.These adaptations have contributed to their rapid and extensive diversification over a short evolutionary period.Extensive research on bat biology has elucidated key aspects of species diversity,adaptive evolution,and the molecular frameworks that confer resistance to viral pathogens.Recent integration of high-resolution multi-omics,single-cell transcriptomics,and advanced three-dimensional culture systems has significantly expanded exploration of bat biology at the molecular and cellular levels.This review consolidates current advances in our understanding of bat species diversification,development,and immunological adaptations with relevance to human health.Emphasis is placed on emerging technologies and methodologies that have transformed the study of bat physiology and hostpathogen interactions.Prospective avenues for research are also outlined,including the development of new animal models and the application of cutting-edge biotechniques.These advances are anticipated to expand the utility of bats as a critical platform for biomedical and evolutionary insight.展开更多
Photothermal coupling catalytic CO2/H2O to CH4 is recognized as an effective strategy for addressing environmental concerns and energy crisis.However,hydrogen evolution reaction(HER)competition and weak inter...Photothermal coupling catalytic CO2/H2O to CH4 is recognized as an effective strategy for addressing environmental concerns and energy crisis.However,hydrogen evolution reaction(HER)competition and weak intermediate adsorption limiting CH4 selectivity and yield during the reaction process.Herein,we incorporate Bi into the In2O3 lattice to create an oxygen-bridged asymmetric bimetallic In-O-Bi(In-O-Bi bridge)sites.The optimized Bi/In2O3 catalyst achieves CH4 yield of 214.1μmol·g-1 with 96.7%selectivity.The exceptional catalytic activity of Bi/In2O3 stems from two key synergistic effects:(1)the cooperative interaction between Bi and In as p-block metals effectively suppress the competing HER,and(2)the unique In-O-Bi bridge configuration induces significant electron delocalization through p-orbital hybridization.This electronic modulation creates highly active catalytic centers,with In sites preferentially facilitating H2O dissociation while Bi sites selectively promote CO2 reduction.Moreover,the electron delocalization effect in the In-O-Bi bridge sites enhances the adsorption and electron transfer capabilities of the Bi/In2O3 surface for key CHO species,and reduces the energy barrier,thereby enabling efficient CH4 production.These findings provide crucial insights into the design of photothermal catalysts,highlighting the transformative potential of oxygen-bridged asymmetric bimetallic units in efficient CO2 methanation and sustainable energy technologies.展开更多
The domestically developed prompt fission neutron uranium logging(PFNUL)instrument for uranium exploration represents a significant advancement in China’s deep uranium mining efforts,although it has considerable chal...The domestically developed prompt fission neutron uranium logging(PFNUL)instrument for uranium exploration represents a significant advancement in China’s deep uranium mining efforts,although it has considerable challenges and complexity.This paper presents the development of a new prompt fission neutron uranium logging instrument(named UNL4)that integrates a domestic D-T neutron generator,two 3He proportional detectors,a lanthanum bromide(LaBr3)gamma-ray detector,and a digital multi-channel pulse amplitude analyzer.The near 3He detector is shielded with 1 mm of cadmium(Cd)and 5 mm of high-density polyethylene(HDPE),enabling efficient epithermal neutron detection,whereas the far 3He detector measures thermal neutrons.A LaBr3 detector is employed for gamma-ray detection,primarily originating from uranium decay.Highspeed analog-to-digital converter(ADC)and field-programmable gate array(FPGA)technologies are used to achieve rapid acquisition and transmission of both dual-energy neutron time spectra and gamma spectra.Moreover,this paper proposes a fast signal-shaping method,which reduces the dead time effect in 3He detectors on neutron time spectra.Experiments conducted in standard model boreholes with varying uranium contents demonstrated a strong linear relationship between the epithermal-to-thermal neutron ratio(E/T)and uranium content,with a fitting coefficient of R2>0.999,confirming the accuracy of the instrument.The E/T value repeatability,in both short-term(3.16%RSD)and long-term(1.2%RSD)measurements,showed excellent stability.In addition,the instrument demonstrated good performance at neutron-logging speeds of 0.3∼3 m∕min(E/T values)and gamma logging speeds of 1∼10 m∕min.Through measurements in two ore sections of the PU model with uranium contents of 87.1 ppm and 45.6 ppm showed that RD remained below approximately 10%at logging speeds of 0–2 m/s in both cases,satisfying the requirements for engineering applications.This marks the first successful development of a neutron-logging instrument for uranium exploration based on a domestic neutron generator and signifies an important contribution to uranium resource exploration.展开更多
Palladium(Pd)has long been constrained as a potential catalyst for CO2reduction reactions(CO2RR)due to significant deactivation caused by strongly adsorbed carbonaceous intermediates on its surface,severely limi...Palladium(Pd)has long been constrained as a potential catalyst for CO2reduction reactions(CO2RR)due to significant deactivation caused by strongly adsorbed carbonaceous intermediates on its surface,severely limiting its catalytic activity and stability.To address this critical bottleneck,this study proposes and implements a synergistic regulation strategy combining alloying and spatial confinement effects.This approach designs a composite catalyst by encapsulating boron-silver co-doped palladium alloy nanoparticles(B-Ag4Pd6)within hollow porous resin carbon spheres(HPRCS).In an H-cell,this catalyst achieved a CO Faradaic efficiency of 96.19%at jCO=24.8 mA/cm2 and maintained stable performance for 80 h.Even under flow cell conditions,it sustained 91.23%CO selectivity at jCO=157.86 mA/cm2 over 60 h.Experimental comparisons confirmed the significant promoting effect of spatial confinement on CO2RR.Furthermore,in situ ATR-FTIR spectroscopy and density functional theory(DFT)calculations reveal that B/Ag alloying downshifts the Pd d-band center,optimizes(*)^COOH and(*)^CO adsorption,and the confined Hmicroenvironment accelerates CO formation while suppressing hydrogen evolution.This study not only successfully addressed the issue of carbon intermediate poisoning on Pd surfaces through alloying and microenvironmental regulation,but also provides novel insights and approaches for designing high-performance CO2RR catalysts that integrate electronic structure control with microenvironmental engineering.展开更多
Capillary barriers offer a cost-effective and environmentally friendly method for acid mine drainage(AMD)control.Existing studies primarily focus on arid and semi-arid climates,whereas few address humid climates with ...Capillary barriers offer a cost-effective and environmentally friendly method for acid mine drainage(AMD)control.Existing studies primarily focus on arid and semi-arid climates,whereas few address humid climates with high precipitation,where AMD risks are more severe.This study evaluated the hydro-chemical performance of two anti-seepage-enhanced triple-layer capillary barriers constructed from copper mine wastes,using rainfall simulation,sensor monitoring,and water balance analysis in a model box.An extreme rainfall event(354 mm over 24 h)followed by a 30-d drying period was simulated sequentially.The top two layers of Model Boxes Ⅰ and Ⅱ withstood 60-and 10-year return period rainfalls,respectively,while the bottom layers delayed percolation by 39.4 h and 81.4 h,respectively,after lateral drainage in the coarse-grained layer(CGL).Despite a significant increase in equivalent permeability at CGL breakthrough(e.g.from 9.9×10⁻¹²m/s to 9.3×10⁻¹⁰m/s in Model Box Ⅰ),stable infiltration and low permeability limited percolation to less than 2.5%of rainfall in both barriers.Based on effective particle size and thickness,two empirical relationships were developed to describe the peak capacity and cumulative release rate of the fine-grained layer.Furthermore,the pH and heavy-metal ion concentrations in the lateral drainage remained within standards throughout the 2184.0 h monitoring period,explained by inhibition of the oxidation reaction.In addition,compared to the untreated waste dump,the predicted runoff removal rates achieved by the barriers were 73.4%and 64.8%for Model Boxes Ⅰ and Ⅱ,respectively.展开更多
This study focuses on the phenomenon of rotor beat frequency vibration(BFV)in a 2-pole magnetic levitation induction machine(MLIM),systematically investigating its dynamic mechanisms and subsequently applying an estab...This study focuses on the phenomenon of rotor beat frequency vibration(BFV)in a 2-pole magnetic levitation induction machine(MLIM),systematically investigating its dynamic mechanisms and subsequently applying an established method for its suppression.First,the BFV synthesis process is described.Subsequently,three primary disturbance sources in the magnetic bearing(MB)system are identified and analyzed,including rotor unbalance,unbalanced magnetic pull(UMP)and magnetostrictive effect.Through numerical solution of a fourdegree-of-freedom(4-DOF)rotor dynamic model,the theoretical analysis reveals that MLIM-induced BFV consists of three spectral components:(i)rotor rotational frequency(RRF),(ii)electrical fundamental frequency(EFF),and(iii)the sum of EFF and slip frequency(EFF+SF).Building on these findings,we propose the adoption of a well-established notch filtering technique as an effective means to suppress the BFV.The experimental results confirm the correctness of the analysis of the BFV generation mechanism,and in particular of the EFF disturbance mechanism,and also demonstrate the effectiveness of the vibration suppression method.展开更多
Blue light and ultraviolet-A(UV-A)radiation are critical light-quality regulators that coordinately modulate plant growth and quality in protected horticulture.However,their interactive effects on celery(Apium graveol...Blue light and ultraviolet-A(UV-A)radiation are critical light-quality regulators that coordinately modulate plant growth and quality in protected horticulture.However,their interactive effects on celery(Apium graveolens L.)remain inadequately characterized.In the present study,we quantified the individual and combined impacts of supplemental UV-A and blue light on the growth,biomass accumulation,photosynthetic performance,and nutritional quality of celery(cv.Dayehuang)in a plant factory with artificial lighting.Our results demonstrated that sole UV-A or blue light application significantly increased biomass,nutritional quality,and light use efficiency(LUE)of celery.Notably,combined supplementation with UV-A and blue light did not enhance chlorophyll content,biomass accumulation,or nutritional quality in celery relative to supplementation with either light quality alone.The principal component analysis(PCA)score plot exhibited clear separation among the four light treatments,with the UV-A treatment distinctly separated along the positive PC1 axis.Our findings demonstrate that UV-A and blue light regulate plant growth and quality via interactive rather than additive effects.Additionally,sole UV-A irradiation significantly improved celery growth and LUE.These findings provide a theoretical foundation for optimizing the light environment for celery under protected cultivation.展开更多
Ultrasonic imaging technology(UIT) has emerged as a pivotal non-destructive detection method for lithium ion batteries(LIBs),addressing critical challenges in ensuring battery safety and performance.This review compre...Ultrasonic imaging technology(UIT) has emerged as a pivotal non-destructive detection method for lithium ion batteries(LIBs),addressing critical challenges in ensuring battery safety and performance.This review comprehensively explores the working principles of UIT, including ultrasonic reflection,refraction,and attenuation,and its applications in LIB inspection.It systematically elaborates on the advancements and applications of UIT for high-resolution imaging of electrode microstructures,realtime monitoring of electrolyte wetting and dry-out,and precise detection of defects such as lithium plating,gas evolution,and electrode delamination.We also discuss the non-invasive assessment of state-ofcharge and state-of-health of LIBs by correlating acoustic properties with structural changes during battery cycling.Comparative analyses highlight the superiority of UIT over traditional destructive methods and complementary technologies.Furthermore,this review rigorously examines the current challenges and future development prospects of UIT.Despite challenges in resolving nanoscale defects and adapting to complex battery architectures,UIT shows promise when integrated with AI-driven data analysis and advanced transducers.Finally,we also envision emerging applications of UIT in the broader renewable energy sector,aiming to provide scientific insights for optimizing manufacturing,lifecycle management,and safety assurance of the battery industry.展开更多
Local gradient metasurfaces have realized multiple beam splitting(BS)functions,enabling various applications in on-chip quantum information.However,nonlocal metasurface BS with the utilization of wavelength and moment...Local gradient metasurfaces have realized multiple beam splitting(BS)functions,enabling various applications in on-chip quantum information.However,nonlocal metasurface BS with the utilization of wavelength and momentum selectivity remains unexplored.Here,we demonstrate the framework of a multidegree-of-freedom multiport BS on a single nonlocal phase gradient metasurface.The BS,constructed by its momentum-polarization mode subspaces,is co-modulated by wavelengths,polarization,and angles of incident light.With the unique capability of multimode interference,this multiport BS can facilitate quantum state engineering,especially multimode high-dimensional quantum entanglement.Then,four-mode highphoton NOON states,manifested as polarization-path-locked properties,are prepared with high success probability and fidelity.For example,four-photon and eight-photon NOON states are obtained with success probabilities of 33.7%and 12.5%,respectively.The efficient generation of multimode high-photon NOON states on a single metasurface improves the precision of on-chip quantum measurement and significantly enhances the integration of quantum information platforms.展开更多
基金supported by the National Key R&D Program of China(Grant No.2020YFC2200500)the Key Laboratory of Tian Qin Project(Sun Yat-sen University),Ministry of Education+1 种基金the National Natural Science Foundation of China(Grant Nos.12075325,12005308,and 11605065)the Doctoral Research Foundation Project of Hubei University of Arts and Science(Grant No.kyqdf2059017)。
摘要The effect from the interaction of the alternating current(AC)magnetic field with kilogram-level test mass(TM)limits the detectivity of the TianQin space-based gravitational wave detection.The quantifed effect requires the determination of the AC magnetic susceptibilityχ(f)of the TM.A torque method is proposed to measure theχ(f)of kg-level samples at the mHz band with a precision of 1×10-7.Combined with our previous work[Phys.Rev.Appl.18044010(2022)],the general frequency-dependent susceptibility of the alloy cube with side length L and electrical conductivityσis determined asχ(f)=χ0+(0.24±0.01)σμ0L2f from 0.1 mHz to 1 Hz.The determination is helpful for the preliminary estimation of the in-band eddy current efect in the TianQin noise budget.The technique can be adopted to accurately measureχ(f)of the actual TM in other precision experiments,where the magnetic noise is a signifcant detection limit.
摘要The basic condition of earthquake disasters in China is featured by high frequency,strong intensity,wide distribution,and heavy losses.Earthquake forecasting plays a critical role in reducing seismic risks.To better advance earthquake predicting efforts,the China Earthquake Administration released the Strategic Plan for Earthquake Forecasting in China(2025−2035)on the occasion of the 50th anniversary of the Haicheng earthquake.Here we briefly introduce the main contents of the Strategic Plan,including the main progress,strategic objectives,and development directions of earthquake forecasting in China.
基金supported by the Key Research and Development Task Project of Xinjiang Uygur Autonomous Region(No.2022B02033)the National Natural Science Foundation of China(Nos.42211530566 and 42311530066)+2 种基金the NSFC-FNRS Joint Program BIOAGRIFILM(No.FNRS PINT-BILATM 2022)the Science and Technology Project of Bijie Tobacco Company of Guizhou Province(No.2022520500240192)the Agricultural Science and Technology Innovation Program(ASTIP)。
摘要The application of poly(butylene adipate-co-terephthalate)(PBAT)biodegradable plastics has long been constrained by insufficient light aging resistance.Hindered amine light stabilizers(HALSs),known as eco-friendly additives,can scavenge free radicals to enhance polymer durability.However,rough choices have resulted in wastage of resources and environmental pressure.Based on the application of plastic films as the background for use,this study systematically evaluates application effects of five HALSs.The films underwent accelerated aging for various durations and were further investigated by a combination of experiments and molecular simulation.Results showed that all HALSs mitigated PBAT light aging,with Chimassorb-944(UV-944)and Tinuvin-770(UV-770)performing the best for real applications.Quantum chemical calculation results showed that UV-944 had stronger anti migration ability.After 300 h of aging,films with UV-944 and UV-770 retained superior tensile strength and elongation at break in the transverse direction compared to neat PBAT films.Polymeric HALSs provided better long-term stability than small-molecule ones.Further spectra analysis indicated that stronger C―O bonds in HALS/PBAT composites correlated with improved photostability.This study offers valuable insights into improving weather resistance of PBAT biodegradable films and optimizing the real application of HALSs.
基金Supported by National Natural Science Foundation of China,No.82260402Research Foundation of The Affiliated Hospital of Guizhou Medical University,No.GYFYMF002 and No.GYFYMF001+4 种基金Central-Guided Local Science and Technology Projects of Guizhou Province,No.Qiankehe[2025]024Guizhou Key Laboratory,No.ZDSYS[2023]004Guizhou Provincial Key Laboratory for Digestive System Diseases,No.ZSYS[2025]021Basic Research Program of Guizhou Science and Technology Plan,No.ZK[2022]341 and No.ZK[2022]368National Science Foundation of Hainan,No.821QN0993.
摘要BACKGROUND Although Helicobacter pylori(H.pylori)can cause a range of gastric diseases and affects approximately 50% of the global population,its routes of transmission have yet to be sufficiently clarified.In a preliminary study,we found that H.pylori can reside within the cells of Candida yeasts,with maternal Candida serving as a potential reservoir for the transmission of H.pylori to neonates during delivery.AIM To study the route of H.pylori transmission from mothers to offspring.METHODS We established vaginal and gastric infection models using female C57BL/6J mice infected with H.pylori 16S rDNA and urease A(ureA)genes-positive Candida.The successfully infective female mice were then mated with normal male mice until conception(classified vaginal and cesarean deliveries).The H.pylori infection status in female mice and their offspring was assessed using enzyme-linked immunosorbent assay,polymerase chain reaction,Candida isolation and culture,and histopathological examination.RESULTS The enzyme-linked immunosorbent assay results showed an increase in H.pylori-specific IgG and IgM serum antibodies in the H.pylori-positive Candida group maternal and offspring mice compared to the control and normal groups.H.pylori 16S rDNA or ureA genes was detected in samples from some of the maternal and offspring mice,including gastric mucosa,intestinal contents,vaginal tissue,placenta,and fetal membranes.In addition,H.pylori 16S rDNA-or ureA gene-positive Candida were successfully isolated from the tissues of some postpartum maternal and offspring mice.Moreover,histopathological examination revealed bleeding spots and inflammatory cell infiltration in the gastric mucosal tissues of some maternal mice and offspring in the H.pylori-positive Candida group.CONCLUSION In conclusion,H.pylori infection of newborns may be acquired through vertical transmission during childbirth,potentially originating from the mother’s Candida that has been internalized by H.pylori.
基金Supported by the National Natural Science Foundation of China(Nos.32000167,32270220)the Shanxi Key Laboratory of Earth Surface Processes and Resource Ecological Security in Fenhe River Basin,Taiyuan Normal University。
摘要Two filamentous cyanobacteria,isolated from different habitats in Yunnan Province,China,were described.Phylogenetic analysis and taxonomic identification were performed using a polyphasic approach that included morphological,ecological,and molecular data.Their morphological characteristics and microscopic structures were observed and recorded using an optical microscope.Filaments of the strain SXACC0113 are yellowish-green and relatively wide,ranging from 1.1 to 4.8μm,and the cells are sometimes inflated.Strain SXACC0116 have no false branching,and the apical cells are cylindrical.Phylogenetic trees were constructed using maximum likelihood(ML)and bayesian inference(BI)based on the 16S rRNA gene sequences.The analysis showed that the algal strain SXACC0113 was distributed in the Elainella clade,and its similarity to the 16S rRNA genes of other species in the genus Elainella was 97.9%–98.2%.The strain SXACC0116 was distributed in the Pegethrix clade,and its similarity to the 16S rRNA genes of other species in the genus Pegethrix was 95.4%–97.3%.Additionally,unique forms were found in the D1-D1ʹ,Box B,and V3 helices of the 16S–23S internal transcribed spacer(ITS)secondary structure in these strains.These findings support the establishment of two new species,named Elainella yunnanensis sp.nov.and Pegethrix yunnanensis sp.nov.This discovery increases the diversity of cyanobacterial species in China,provides a scientific basis for further revision and classification of cyanobacteria,and supplements algae research information in China.
基金financially supported by the Natural Science Research Project of Anhui Educational Committee(Grant No.2024AH050395)。
摘要Manganese-based oxides are widely employed as cathode materials for aqueous zinc ion batteries(AZIBs) due to their low toxicity and high theoretical specific capacity.However,their inherent poor electrical conductivity,coupled with the dissolution of manganese into the electrolyte,often leads to structural degradation of the cathode.To address these challenges,Mn-MOF was utilized as a precursor to synthesize a corncob popcorn-like Mn2O3@C composite with high activity and long lifespan for AZIBs.This distinctive porous carbon encapsulation architecture leverages oxygen vacancies to modulate the spacing of Mn metal oxide layers and alter the valence states of metal ions,thereby enhancing both structural stability and conductivity,and reducing the Zn2+ diffusion path.The porous structure also improves the wettability of the electrode surface and electrolyte penetration,and provides ample and rapid ion transport channels.Consequently,the fabricated corncob popcorn-like Mn2O3@C exhibits an outstanding specific capacity of 570.5 mA h g-1 at 0.1 A g-1 and a capacity retention of over 95% after 3000 cycles at 1 A g-1.The Zn2+ storage mechanism was elucidated through various ex situ characterizations,revealing that the storage mechanism is governed by a mixed H+/Zn2+ co-insertion/de-insertion process.
基金supported by the National Natural Science Foundation of China(Grant Nos.T2322028,62474184,and 62004208)the National Key R&D Program of China(Grant No.2025YFF0516403)+5 种基金the CAS Project for Young Scientists in Basic Research(Grant No.YSBR-102)the Talent Plan of Shanghai Branch,Chinese Academy of Sciences(Grant No.CASSHB-QNPD-2023-001)the Shanghai Rising-Star Program(Grant No.23QA1411100)the Science and Technology Commission of Shanghai Municipality(Grant No.22ZR1473200)the Postdoctoral Fellowship Program of CPSF(Grant No.GZB20250031)China Postdoctoral Science Foundation(Grant No.2025M780190).
摘要The interfacial stress between silicon bottom cell and perovskite top cell remains a critical challenge for flexible perovskite/silicon tandem solar cells,leading to interfacial delamination and device degradation.In this work,the effect of the thickness and pyramid size on mechanical properties of silicon wafers are investigated,demonstrating that thinner wafers and smaller pyramids significantly enhance the flexural strength of thin silicon wafers by mitigating stress concentration effects.Based on these findings,a synergistic optimization strategy is proposed that employs precise wet-etching control to fabricate small-sized,high-density,uniform pyramids on 55μm silicon wafers for efficient and flexible perovskite/silicon tandem solar cells.By optimizing the texturing duration,this approach simultaneously enhances the minority carrier lifetime(τ)and achieves an excellent implied open-circuit voltage(iVoc).Furthermore,the uniform submicron-scale pyramid structure promotes high-quality perovskite film formation and improves interfacial contact properties.As a proof of concept,monolithic flexible perovskite/silicon tandem devices fabricated on such uniformly textured pyramids delivered a power conversion efficiency(PCE)of 30.04%.These devices promise for low-cost,lightweight and flexible photovoltaic applications.
基金financially supported by the National Natural Science Foundation of China(Nos.52575504,52175415,52205475,and 92160301).
摘要Traditional tools have limited adaptability in complex machining environments due to their lack of working-condition perception and autonomous regulation.With advances in sensors,materials,and data-processing technologies,tool design is shifting from a single-function‘mechanical arm’for cutting towards integrated intelligent terminals.This paper systematically reviews progress in intelligent tool technology from two perspectives:design and regulation.For intelligent design,the fundamental principles of condition-perception tools equipped with built-in multi-type sensors are discussed,enabling in situ,real-time monitoring of multidimensional parameters such as cutting force,temperature,and vibration.Force monitoring is achieved through elastic deformation or dynamic charge response,temperature monitoring through the thermoelectric effect,and vibration monitoring through micro-displacement and intensity detection.The design focus emphasises sensor miniaturisation and integration,balancing measurement accuracy with tool stiffness while minimising machining interference.In regulation,key technologies for constructing closed-loop control systems(CLCS)are summarised,which dynamically adjust cutting speed,feed rate,and other parameters based on sensed data,achieving precise control of force,temperature,and vibration via feedback mechanisms and driving units.Breakthroughs in tool wear compensation(TWC)mechanisms are introduced.Multi-source signal fusion combined with deep learning algorithms is further examined for improving monitoring accuracy and remaining useful life(RUL)prediction.Through model predictive control,intelligent regulation of cutting parameters within process flows is realised.Finally,challenges such as sensor reliability,multi-source coupling,and balancing cost with industrial applicability are analysed.Future directions highlight novel structural designs,high-performance material development,and multi-technology integration,aiming to establish a fully intelligent machining system through the integrated design of‘perception-decision-execution’.
基金supported by the Yunnan Fundamental Research Projects(Grant No.202401BE070001-046)the Key Laboratory of Ecology and Environment in Minority Areas(Minzu University of China),the National Ethnic Affairs Commission(Grant No.KLEEMA202106)the Beijing Advanced Discipline for Mass Spectrometry Imaging and Metabonomics(Grant No.104-01900403).
摘要Jojoba[Simmondsia chinensis(Link)Schneider]is sensitive to low temperatures,which hinders its cultivation in temperate arid regions.The apoplast is a cellular component outside the plasma membrane of plant cells and is widely involved in the response of plants to environmental stress.Here,we used the infiltration-centrifugation method to extract apoplast fluid from jojoba leaves and analyzed changes in the apoplast proteome after cold acclimation using quantitative proteomics.In total,751 apoplast proteins were identified in jojoba,and the abundance of 200 proteins showed significant changes after cold acclimation.These proteins were primarily involved in defense,cell wall modification,carbohydrate metabolism,and redox balance.We also investigated the function and regulation of a cold acclimation-responsive class III chitinase ScCHIA.The results showed that the overexpression of ScCHIA enhanced the tolerance of Arabidopsis,yeast,and jojoba to low temperature and osmotic stress.Under cold stress,ScCHIA-overexpressing Arabidopsis accumulated more osmolytes,activated antioxidant enzymes,and reduced stomatal aperture size,which may contribute to enhanced tolerance to cold stress.ScCHIA was induced by methyl jasmonate(MeJA)application,and electrophoretic mobility shift assay(EMSA),yeast one-hybrid(Y1H),and luciferase activity assays demonstrated that an E-box cis-acting element on the ScCHIA gene promoter mediated regulation of ScCHIA by MeJA signaling,indicating that elevated levels of MeJA caused by cold acclimation may promote the expression of ScCHIA,thereby enhancing the cold tolerance of jojoba.Our research highlights the important role of the apoplast in plant response to low temperature stress and improves the understanding of the functions and regulatory mechanisms of plant chitinases in abiotic stress response.
基金support from the National Natural Science Foundation of China(22478036)the Fundamental Research Funds for the Central Universities(QNTD202507).
摘要The rapid development of wearable electronics,self-powered systems,and the Internet of Things urgently requires efficient thermal management(TM)technologies and sustainable energy solutions.However,triboelectric nanogenerator(TENG)and their integrated electronic components inevitably generate or accumulate Joule thermal.It led to performance degradation or even device failure.This review focuses on the research progress in integrating advanced TM technologies into TENGs,aiming to provide comprehensive insights for constructing high-performance and highly stable self-powered systems.The scope of this review encompasses:(i)systematically summarizing the design and development of TM-TENG systems based on key materials,such as graphene,carbon nanotubes,MXene,cellulose,and phase change materials,(ii)elucidating the bidirectional coupling mechanism between triboelectric charge generation and thermal management,along with a critical analysis of existing theoretical models,and(iii)detailing the multifunctional integration and applications potential of TM-TENGs in the fields including thermal conversion,thermal energy harvesting,storage,actuation,and conduction.The bidirectional coupling mechanisms between triboelectric charge generation and thermal management are thoroughly dissected at a theoretical level.The predominant physical models explaining the interaction phenomena between frictional heating and thermal management are reviewed,with critical analysis of their applicability and limitations.Furthermore,this work discusses the current challenges and future directions in this field and proposes strategic recommendations for realizing more advanced TM-TENG systems.The primary objectives of this review are to synthesize existing knowledge,clarify interaction mechanisms,and promote interdisciplinary development at the intersection of thermal management and energy harvesting.
基金supported by the National Natural Science Foundation of China (32060505, 31660418)the Project of National Key Laboratory for Tropical Crop Breeding, China (NKLTCB202318)+3 种基金the Yunnan Seed Laboratory, China (202205AR070001-13)the Technology Innovation Talents in Yunnan Province, China (202305AD160041)the National Sugar Industry Technology System, China (CARS-170101)the High-performance Computing Platform of YaZhou Bay Science and Technology City Advanced Computation Center, China。
摘要Increasing the sucrose content of sugarcane,a major sugar crop,is a key breeding objective.However,the complex genetic background of sugarcane affects development of sugarcane hybrids.In this study,we sequenced 292 sugarcane germplasm accessions and identified 2,542,965 single nucleotide polymorphisms(SNPs) and insertions/deletions(InDels).We performed a genome-wide association study(GWAS) for two important sugarcane traits:sucrose content and stem diameter.Both traits followed a normal distribution and showed typical characteristics of quantitative traits.Population structure analysis revealed four subpopulations with an average genetic distance of 0.236.GWAS of the sucrose content detected 27 SNPs.After annotating genes at or near significant loci,17 candidate genes were screened.For stem diameter,GWAS revealed 19 SNPs,from which 9 candidate genes were identified.These results improve our understanding of genetic mechanisms affecting sucrose content in sugarcane,and identify important genetic resources to accelerate breeding of new sugarcane varieties with high sucrose content.
基金supported by the National Key R&D Program of China(2023YFA1800500)National Natural Science Foundation of China(32192422,32330014,U23A20452,32525015,32400342)+1 种基金Yunnan Revitalization Talent Support Program Top team(202505AT350003,202405AS350022)Major Science and Technique Programs in Yunnan Province(202102AA310055)。
摘要Bats represent a remarkable mammalian lineage,distinguished by the evolution of powered flight,sophisticated echolocation,exceptional longevity,and robust resistance to viral infections.These adaptations have contributed to their rapid and extensive diversification over a short evolutionary period.Extensive research on bat biology has elucidated key aspects of species diversity,adaptive evolution,and the molecular frameworks that confer resistance to viral pathogens.Recent integration of high-resolution multi-omics,single-cell transcriptomics,and advanced three-dimensional culture systems has significantly expanded exploration of bat biology at the molecular and cellular levels.This review consolidates current advances in our understanding of bat species diversification,development,and immunological adaptations with relevance to human health.Emphasis is placed on emerging technologies and methodologies that have transformed the study of bat physiology and hostpathogen interactions.Prospective avenues for research are also outlined,including the development of new animal models and the application of cutting-edge biotechniques.These advances are anticipated to expand the utility of bats as a critical platform for biomedical and evolutionary insight.
摘要Photothermal coupling catalytic CO2/H2O to CH4 is recognized as an effective strategy for addressing environmental concerns and energy crisis.However,hydrogen evolution reaction(HER)competition and weak intermediate adsorption limiting CH4 selectivity and yield during the reaction process.Herein,we incorporate Bi into the In2O3 lattice to create an oxygen-bridged asymmetric bimetallic In-O-Bi(In-O-Bi bridge)sites.The optimized Bi/In2O3 catalyst achieves CH4 yield of 214.1μmol·g-1 with 96.7%selectivity.The exceptional catalytic activity of Bi/In2O3 stems from two key synergistic effects:(1)the cooperative interaction between Bi and In as p-block metals effectively suppress the competing HER,and(2)the unique In-O-Bi bridge configuration induces significant electron delocalization through p-orbital hybridization.This electronic modulation creates highly active catalytic centers,with In sites preferentially facilitating H2O dissociation while Bi sites selectively promote CO2 reduction.Moreover,the electron delocalization effect in the In-O-Bi bridge sites enhances the adsorption and electron transfer capabilities of the Bi/In2O3 surface for key CHO species,and reduces the energy barrier,thereby enabling efficient CH4 production.These findings provide crucial insights into the design of photothermal catalysts,highlighting the transformative potential of oxygen-bridged asymmetric bimetallic units in efficient CO2 methanation and sustainable energy technologies.
基金supported by the National Natural Science Foundation of China(No.42374226)Jiangxi Provincial Natural Science Foundation(Nos.20232BCJ23006,gpyc20240073,20252BAC240173 and 20243BCE51132)National Key Laboratory of Uranium Resource Exploration-Mining and Nuclear Remote Sensing(2024QZ-TD-09,2024HDX10,2025QZ018).
摘要The domestically developed prompt fission neutron uranium logging(PFNUL)instrument for uranium exploration represents a significant advancement in China’s deep uranium mining efforts,although it has considerable challenges and complexity.This paper presents the development of a new prompt fission neutron uranium logging instrument(named UNL4)that integrates a domestic D-T neutron generator,two 3He proportional detectors,a lanthanum bromide(LaBr3)gamma-ray detector,and a digital multi-channel pulse amplitude analyzer.The near 3He detector is shielded with 1 mm of cadmium(Cd)and 5 mm of high-density polyethylene(HDPE),enabling efficient epithermal neutron detection,whereas the far 3He detector measures thermal neutrons.A LaBr3 detector is employed for gamma-ray detection,primarily originating from uranium decay.Highspeed analog-to-digital converter(ADC)and field-programmable gate array(FPGA)technologies are used to achieve rapid acquisition and transmission of both dual-energy neutron time spectra and gamma spectra.Moreover,this paper proposes a fast signal-shaping method,which reduces the dead time effect in 3He detectors on neutron time spectra.Experiments conducted in standard model boreholes with varying uranium contents demonstrated a strong linear relationship between the epithermal-to-thermal neutron ratio(E/T)and uranium content,with a fitting coefficient of R2>0.999,confirming the accuracy of the instrument.The E/T value repeatability,in both short-term(3.16%RSD)and long-term(1.2%RSD)measurements,showed excellent stability.In addition,the instrument demonstrated good performance at neutron-logging speeds of 0.3∼3 m∕min(E/T values)and gamma logging speeds of 1∼10 m∕min.Through measurements in two ore sections of the PU model with uranium contents of 87.1 ppm and 45.6 ppm showed that RD remained below approximately 10%at logging speeds of 0–2 m/s in both cases,satisfying the requirements for engineering applications.This marks the first successful development of a neutron-logging instrument for uranium exploration based on a domestic neutron generator and signifies an important contribution to uranium resource exploration.
基金financial support from the National Natural Science Foundation of China(72088101,22474157)the Major Program from Xiangjiang Laboratory(23XJ01010,23XJ01011)+2 种基金the Natural Science Foundation of Hunan Province(2024JJ5417)the Innovation-Driven Project of Central South University(2023CXQD048)the Changsha Natural Science Foundation Project(kq2402199)。
摘要Palladium(Pd)has long been constrained as a potential catalyst for CO2reduction reactions(CO2RR)due to significant deactivation caused by strongly adsorbed carbonaceous intermediates on its surface,severely limiting its catalytic activity and stability.To address this critical bottleneck,this study proposes and implements a synergistic regulation strategy combining alloying and spatial confinement effects.This approach designs a composite catalyst by encapsulating boron-silver co-doped palladium alloy nanoparticles(B-Ag4Pd6)within hollow porous resin carbon spheres(HPRCS).In an H-cell,this catalyst achieved a CO Faradaic efficiency of 96.19%at jCO=24.8 mA/cm2 and maintained stable performance for 80 h.Even under flow cell conditions,it sustained 91.23%CO selectivity at jCO=157.86 mA/cm2 over 60 h.Experimental comparisons confirmed the significant promoting effect of spatial confinement on CO2RR.Furthermore,in situ ATR-FTIR spectroscopy and density functional theory(DFT)calculations reveal that B/Ag alloying downshifts the Pd d-band center,optimizes(*)^COOH and(*)^CO adsorption,and the confined Hmicroenvironment accelerates CO formation while suppressing hydrogen evolution.This study not only successfully addressed the issue of carbon intermediate poisoning on Pd surfaces through alloying and microenvironmental regulation,but also provides novel insights and approaches for designing high-performance CO2RR catalysts that integrate electronic structure control with microenvironmental engineering.
基金funding support from the National Natural Science Foundation of China(Grant No.42177118)the Ministry of Science and Technology of China(Grant No.2019YFC1805002)the ScientificResearch Fund of Zhejiang University(Grant No.XY2024021)。
摘要Capillary barriers offer a cost-effective and environmentally friendly method for acid mine drainage(AMD)control.Existing studies primarily focus on arid and semi-arid climates,whereas few address humid climates with high precipitation,where AMD risks are more severe.This study evaluated the hydro-chemical performance of two anti-seepage-enhanced triple-layer capillary barriers constructed from copper mine wastes,using rainfall simulation,sensor monitoring,and water balance analysis in a model box.An extreme rainfall event(354 mm over 24 h)followed by a 30-d drying period was simulated sequentially.The top two layers of Model Boxes Ⅰ and Ⅱ withstood 60-and 10-year return period rainfalls,respectively,while the bottom layers delayed percolation by 39.4 h and 81.4 h,respectively,after lateral drainage in the coarse-grained layer(CGL).Despite a significant increase in equivalent permeability at CGL breakthrough(e.g.from 9.9×10⁻¹²m/s to 9.3×10⁻¹⁰m/s in Model Box Ⅰ),stable infiltration and low permeability limited percolation to less than 2.5%of rainfall in both barriers.Based on effective particle size and thickness,two empirical relationships were developed to describe the peak capacity and cumulative release rate of the fine-grained layer.Furthermore,the pH and heavy-metal ion concentrations in the lateral drainage remained within standards throughout the 2184.0 h monitoring period,explained by inhibition of the oxidation reaction.In addition,compared to the untreated waste dump,the predicted runoff removal rates achieved by the barriers were 73.4%and 64.8%for Model Boxes Ⅰ and Ⅱ,respectively.
基金supported in part by the National Natural Science Foundation of China under Grants 52425701 and 52477046。
摘要This study focuses on the phenomenon of rotor beat frequency vibration(BFV)in a 2-pole magnetic levitation induction machine(MLIM),systematically investigating its dynamic mechanisms and subsequently applying an established method for its suppression.First,the BFV synthesis process is described.Subsequently,three primary disturbance sources in the magnetic bearing(MB)system are identified and analyzed,including rotor unbalance,unbalanced magnetic pull(UMP)and magnetostrictive effect.Through numerical solution of a fourdegree-of-freedom(4-DOF)rotor dynamic model,the theoretical analysis reveals that MLIM-induced BFV consists of three spectral components:(i)rotor rotational frequency(RRF),(ii)electrical fundamental frequency(EFF),and(iii)the sum of EFF and slip frequency(EFF+SF).Building on these findings,we propose the adoption of a well-established notch filtering technique as an effective means to suppress the BFV.The experimental results confirm the correctness of the analysis of the BFV generation mechanism,and in particular of the EFF disturbance mechanism,and also demonstrate the effectiveness of the vibration suppression method.
基金the Priority Academic Program Development of Jiangsu Higher Education Institutions(No.PAPD-2023-87)Jiangsu Provincial Frontier Technology R&D Program(Modern Agriculture)(No.BF2025314)+3 种基金the Modern Agricultural Industrial Technology System of Shandong Province(No.SDAIT-05)the Key Research and Development Program of Shandong Province(2021TZXD007)Youth Innovation Team Plan of Colleges and Universities of Shandong Province(2023KJ167)the Foundation for High-level Talents of Qingdao Agricultural University(6631120098).
摘要Blue light and ultraviolet-A(UV-A)radiation are critical light-quality regulators that coordinately modulate plant growth and quality in protected horticulture.However,their interactive effects on celery(Apium graveolens L.)remain inadequately characterized.In the present study,we quantified the individual and combined impacts of supplemental UV-A and blue light on the growth,biomass accumulation,photosynthetic performance,and nutritional quality of celery(cv.Dayehuang)in a plant factory with artificial lighting.Our results demonstrated that sole UV-A or blue light application significantly increased biomass,nutritional quality,and light use efficiency(LUE)of celery.Notably,combined supplementation with UV-A and blue light did not enhance chlorophyll content,biomass accumulation,or nutritional quality in celery relative to supplementation with either light quality alone.The principal component analysis(PCA)score plot exhibited clear separation among the four light treatments,with the UV-A treatment distinctly separated along the positive PC1 axis.Our findings demonstrate that UV-A and blue light regulate plant growth and quality via interactive rather than additive effects.Additionally,sole UV-A irradiation significantly improved celery growth and LUE.These findings provide a theoretical foundation for optimizing the light environment for celery under protected cultivation.
基金Science and Technology Department of Zhejiang Province(Grant No.2023C01231)Natural Science Foundation of Zhejiang Province(Grant No.LD25E020003,LQ23E020009)+7 种基金National Natural Science Foundation of China(Grant Nos.52372235,U20A20253,22379020,22279116)Key Scientific Research Project of Hangzhou(Grant No.2024SzD1B12)State Key Laboratory of New Textile Materials and Advanced Processing Technologies(Grant No.FZ2024009)Science and Technology Project of Huzhou(Grant No.2024GZ02)National Science Foundation of Sichuan Province(Grant No.2024NSFSC0951)Zhejiang Provincial Postdoctoral Research Project(Grant No.ZJ2023080)China Postdoctoral Science Foundation(2024M750347)Key Laboratory of Engineering Dielectrics and Its Application(Harbin University of Science and Technology),Ministry of Education(Grant No.KFM 202303)。
摘要Ultrasonic imaging technology(UIT) has emerged as a pivotal non-destructive detection method for lithium ion batteries(LIBs),addressing critical challenges in ensuring battery safety and performance.This review comprehensively explores the working principles of UIT, including ultrasonic reflection,refraction,and attenuation,and its applications in LIB inspection.It systematically elaborates on the advancements and applications of UIT for high-resolution imaging of electrode microstructures,realtime monitoring of electrolyte wetting and dry-out,and precise detection of defects such as lithium plating,gas evolution,and electrode delamination.We also discuss the non-invasive assessment of state-ofcharge and state-of-health of LIBs by correlating acoustic properties with structural changes during battery cycling.Comparative analyses highlight the superiority of UIT over traditional destructive methods and complementary technologies.Furthermore,this review rigorously examines the current challenges and future development prospects of UIT.Despite challenges in resolving nanoscale defects and adapting to complex battery architectures,UIT shows promise when integrated with AI-driven data analysis and advanced transducers.Finally,we also envision emerging applications of UIT in the broader renewable energy sector,aiming to provide scientific insights for optimizing manufacturing,lifecycle management,and safety assurance of the battery industry.
基金supported by the National Natural Science Foundation of China(Grant Nos.U25D9003 and 12474370)the Quantum Science and Technology-National Science and Technology Major Project(Grant No.2021ZD0301500)。
摘要Local gradient metasurfaces have realized multiple beam splitting(BS)functions,enabling various applications in on-chip quantum information.However,nonlocal metasurface BS with the utilization of wavelength and momentum selectivity remains unexplored.Here,we demonstrate the framework of a multidegree-of-freedom multiport BS on a single nonlocal phase gradient metasurface.The BS,constructed by its momentum-polarization mode subspaces,is co-modulated by wavelengths,polarization,and angles of incident light.With the unique capability of multimode interference,this multiport BS can facilitate quantum state engineering,especially multimode high-dimensional quantum entanglement.Then,four-mode highphoton NOON states,manifested as polarization-path-locked properties,are prepared with high success probability and fidelity.For example,four-photon and eight-photon NOON states are obtained with success probabilities of 33.7%and 12.5%,respectively.The efficient generation of multimode high-photon NOON states on a single metasurface improves the precision of on-chip quantum measurement and significantly enhances the integration of quantum information platforms.