This paper discusses the design of event-triggered output-feedback controller for a class of nonlinear time-delay systems with multiple uncertainties. In sharp contrast to previous works, the considered systems posses...This paper discusses the design of event-triggered output-feedback controller for a class of nonlinear time-delay systems with multiple uncertainties. In sharp contrast to previous works, the considered systems possess two important characteristics: (i) The uncertain nonlinear terms meet the linearly unmeasurable-states dependent growth with the growth rate being an unknown function of the input and output. (ii) There exist input matching uncertainty and unknown measurement sensitivity. By introducing a single dynamic gain and employing a cleverly devised event-triggering mechanism (ETM), we design a new gain-based event-triggered output-feedback controller, which globally regulates all states of the considered systems and maintains global boundedness of the closed-loop system. Furthermore, the estimation of input matching uncertainty achieves convergence towards its actual value, and Zeno behavior does not happen. Two simulation examples including a practical one show that the proposed approach is effective.展开更多
The control of the condensed superstructure of light-emitting conjugated polymers(LCPs)is a crucial factor to obtain high performance and stable organic optoelectronic devices.Side-chain engineering strategy is an eff...The control of the condensed superstructure of light-emitting conjugated polymers(LCPs)is a crucial factor to obtain high performance and stable organic optoelectronic devices.Side-chain engineering strategy is an effective platform to tune inter chain aggregation and photophysical behaviour of LCPs.Herein,we systematically investigated the alkyl-chain branched effecton the conformational transition and photophysical behaviour of polydiarylfluorenes toward efficient blue optoelectronic devices.The branched side chain will improve materials solubility to inhibit interchain aggregation in solution according to DLS and optical analysis,which is useful to obtain high quality film.Therefore,our branched PEODPF,POYDPF pristine film present high luminance efficiency of 36.1%and 39.6%,enhanced about 20%relative to that of PODPF.Compared to the liner-type sides'chain,these branched chains also suppress chain planarization and improve film morphological stability effectively.Interestingly,the branched polymer also had excellent stable amplified spontaneous emission(ASE)behaviour with low threshold(4.72μJ/cm2)and a center peak of 465 nm,even thermal annealing at 220℃in the air atmosphere.Therefore,side-chain branched strategy for LCPs is an effective means to control interchain aggregation,film morphology and photophysical property of LCPs.展开更多
The interface deformation and liquid breakup in vapor-liquid two-phase flow are ubiquitous in natural phenomena and industrial applications.It is crucial to understand the corresponding mechanism correctly.The droplet...The interface deformation and liquid breakup in vapor-liquid two-phase flow are ubiquitous in natural phenomena and industrial applications.It is crucial to understand the corresponding mechanism correctly.The droplet and liquid ligament dynamic behaviors are investigated in this work by simulating three benchmark cases through adopting a three-dimensional(3D)phase-field-based lattice Boltzmann model,and vapor-liquid phase interface deformation and liquid breakup mechanisms including the capillary instability and end-pinching mechanism are analyzed.The analysis results show that the capillary instability is the driving mechanism of the liquid breakup and the secondary droplet production at a large Weber number,which is different from the Rayleigh-Taylor instability and Kelvin-Helmholtz instability characterizing the vapor-liquid interface deformation.In addition,as another liquid breakup mechanism,the end-pinching mechanism,which describes the back-flow phenomenon of the liquid phase,works at each breakup point,thus resulting in capillary instability on the liquid phase structure.In essence,it is the fundamental mechanism for the liquid breakup and the immanent cause of capillary instability.展开更多
By choosing a PVC slice to simulate flexible vegetation,we carried out experiments in an open channel with submerged flexible vegetation.A 3D acoustic Doppler velocimeter(micro ADV)was used to measure local flow veloc...By choosing a PVC slice to simulate flexible vegetation,we carried out experiments in an open channel with submerged flexible vegetation.A 3D acoustic Doppler velocimeter(micro ADV)was used to measure local flow velocities and Reynolds stress.The results show that hydraulic characteristics in non-vegetation and vegetation layers are totally different.In a region above the vegetation,Reynolds stress distribution is linear,and the measured velocity profile is a classical logarithmic one.Based on the concept of new-riverbed,the river compression parameter representing the impact of vegetation on river is given,and a new assumption of mixing length expression is made.The formula for time-averaged velocity derived from the expression requires less parameters and simple calculation,and is useful in applications.展开更多
Molecular-level encapsulation of conjugated polymers serves as a potent approach to isolate the conjugated backbone for reducing intermolecular interactions and manipulating optoelectronic properties in solid state.He...Molecular-level encapsulation of conjugated polymers serves as a potent approach to isolate the conjugated backbone for reducing intermolecular interactions and manipulating optoelectronic properties in solid state.Herein,by tuning the generation of dendritic carbazoles(Cz)in side chains,polydiarylfluorenes with efficient deep-blue emission have been successfully synthesized and explored.The nonplanar twisted Cz dendrons endow their photoluminescence(PL)spectra with enhanced air-aging stability and thermal stability owing to the formation of a self-encapsulation layer.Their impact on solutionstate chain conformation and aggregation was thoroughly studied,combining small-angle neutron scattering(SANS)and dynamic light scattering(DLS).Furthermore,benefiting from the suppressed intermolecular interactions,their films exhibit optimal behavior of singlet excitons in the excited state.Polymer light-emitting diodes(PLEDs)adopting the spin-coated and blade-coated films both present comparable properties and stable electroluminescence(EL)spectra,with Commission Internationale de L'Eclairage(CIE)coordinates(x+y)<0.3,demonstrating the feasibility of a self-encapsulated molecular design strategy.展开更多
In the design of conjugated molecules,modular production enables materials to easily realize structure modification and precisely tune their photoelectrical property.Construction of a novel and universal building bloc...In the design of conjugated molecules,modular production enables materials to easily realize structure modification and precisely tune their photoelectrical property.Construction of a novel and universal building block is crucial to design and manufacture high performance and stable conjugated molecules for optoelectronic application.Herein,we originally demonstrated a universal 4-qualifiable fluorene-based building block,which is a fundamental molecular segment to functionalize and obtain novel conjugated materials.Compared to the traditional modification at 9-site,additional 4-position functionalization provided an exciting blueprint to not only tune electronic structure and excited state via p-n molecular design engineering and space charge-transfer strategy,but also allow for optimizing intermolecular arrangement and obtaining solution-processing ability.The introduction of the 4-site substituent in fluorene based semiconductors may endow materials with unique properties.Finally,we successfully prepared two stable deep-blue light-emitting conjugated polymer,PODOPF and PODOF,by utilizing the 4-substituent fluorene based building block.It is believable that the performance,stability and processibility of reported outstanding fluorene-based conjugated molecules can be further optimized based on this universal building block.展开更多
Two-dimensional layered material/semiconductor heterostructures have emerged as a category of fascinating architectures for developing highly efficient and low-cost photodetection devices.Herein,we present the constru...Two-dimensional layered material/semiconductor heterostructures have emerged as a category of fascinating architectures for developing highly efficient and low-cost photodetection devices.Herein,we present the construction of a highly efficient flexible light detector operating in the visible-near infrared wavelength regime by integrating a PdTe2 multilayer on a thin Si film.A representative device achieves a good photoresponse performance at zero bias including a sizeable current on/off ratio exceeding 105,a decent responsivity of~343 mA/W,a respectable specific detectivity of~2.56×1012Jones,and a rapid response time of 4.5/379μs,under 730 nm light irradiation.The detector also displays an outstanding long-term air stability and operational durability.In addition,thanks to the excellent flexibility,the device can retain its prominent photodetection performance at various bending radii of curvature and upon hundreds of bending tests.Furthermore,the large responsivity and rapid response speed endow the photodetector with the ability to accurately probe heart rate,suggesting a possible application in the area of flexible and wearable health monitoring.展开更多
目的探讨以问题为基础的学习(problem based learning,PBL)联合翻转课堂(flipped classroom,FC)教学方法在心血管疾病个体化用药教学中的应用。方法将学生随机分为试验组(PBL+FC教学法)和对照组(传统教学法),通过考核和问卷调查方式评...目的探讨以问题为基础的学习(problem based learning,PBL)联合翻转课堂(flipped classroom,FC)教学方法在心血管疾病个体化用药教学中的应用。方法将学生随机分为试验组(PBL+FC教学法)和对照组(传统教学法),通过考核和问卷调查方式评价两种教学方法联合在心血管疾病个体化用药教学中的应用效果。结果试验组的成绩高于传统教学组(P<0.05)。与传统教学法相比,PBL+FC教学法能够增强学生学习兴趣,提高学生自主学习、分析解决问题能力。结论 PBL+FC教学方法优于传统教学法。展开更多
The intrinsically rigid and limited strain of most conjugated polymers has encouraged us to optimize the extensible properties of conjugated polymers.Herein,learning from the hydrogen bonds in glucose,which were facil...The intrinsically rigid and limited strain of most conjugated polymers has encouraged us to optimize the extensible properties of conjugated polymers.Herein,learning from the hydrogen bonds in glucose,which were facilitated to the toughness enhancement of cellulose,we introduced interchain hydrogen bonds to polydiarylfluorene by amide-containing side chains.Through tuning the copolymerization ratio,we systematically investigated their influence on the hierarchical condensed structures,rheology behavior,tensile performances,and optoelectronic properties of conjugated polymers.Compared to the reference copolymers with a low ratio of amide units,copolymers with 30%and 40%amide units present a feature of the shearthinning process that resembled the non-Newtonian fluid,which was enabled by the interchain dynamic hydrogen bonds.Besides,we developed a practical and universal method for measuring the intrinsic mechanical properties of conjugated polymers.We demonstrated the significant impact of hydrogen bonds in solution gelation,material crystallization,and thin film stretchability.Impressively,the breaking elongation for P4 was even up to~30%,which confirmed the partially enhanced film ductility and toughness due to the increased amide groups.Furthermore,polymer light-emitting devices(PLEDs)based on these copolymers presented comparable performances and stable electroluminescence(EL).Thin films of these copolymers also exhibited random laser emission with the threshold as low as 0.52μJ/cm2,suggesting the wide prospective application in the field of flexible optoelectronic devices.展开更多
基金supported by the fund of Beijing Municipal Commission of Education(KM202210017001 and 22019821001)the Natural Science Foundation of Henan Province(222300420253).
摘要This paper discusses the design of event-triggered output-feedback controller for a class of nonlinear time-delay systems with multiple uncertainties. In sharp contrast to previous works, the considered systems possess two important characteristics: (i) The uncertain nonlinear terms meet the linearly unmeasurable-states dependent growth with the growth rate being an unknown function of the input and output. (ii) There exist input matching uncertainty and unknown measurement sensitivity. By introducing a single dynamic gain and employing a cleverly devised event-triggering mechanism (ETM), we design a new gain-based event-triggered output-feedback controller, which globally regulates all states of the considered systems and maintains global boundedness of the closed-loop system. Furthermore, the estimation of input matching uncertainty achieves convergence towards its actual value, and Zeno behavior does not happen. Two simulation examples including a practical one show that the proposed approach is effective.
基金supported by the National Natural Science Foundation of China(Nos.61874053,21774061,91833306)Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions,PAPD(No.YX03002)+10 种基金the Six Peak Talents Foundation of Jiangsu Province(No.XCL-CXTD-009)Natural Science Funds of the Education Committee of Jiangsu Province(No.18KJA430009)"High-Level Talents in Six Industries"of Jiangsu Province(No.XYDXX-019)Program for Postgraduates Research Innovation in University of Jiangsu Province(No.KYCX17_0752)the open research fund from Key Laboratory for Organic Electronics and Information Display&and State Key Laboratory of Supramolecular Structure and Materials(No.sklssm2019017)Overseas Merit Foundation of Science and Technology of Nanjingfinancial support from the Regional Government of Madrid through NMAT2D-CM Project(No.S2018/NMT-4511)the Spanish Ministry of Economy and Competitiveness through project RTI2018-097508-B-I00through the Severo Ochoa Program for Centers of Excellence(No.SEV-2016-0686)the Campus of International Excellence(CEI)UAM+CSICthe China Scholarship Council(No.201608390023)for a PhD sponsorship
摘要The control of the condensed superstructure of light-emitting conjugated polymers(LCPs)is a crucial factor to obtain high performance and stable organic optoelectronic devices.Side-chain engineering strategy is an effective platform to tune inter chain aggregation and photophysical behaviour of LCPs.Herein,we systematically investigated the alkyl-chain branched effecton the conformational transition and photophysical behaviour of polydiarylfluorenes toward efficient blue optoelectronic devices.The branched side chain will improve materials solubility to inhibit interchain aggregation in solution according to DLS and optical analysis,which is useful to obtain high quality film.Therefore,our branched PEODPF,POYDPF pristine film present high luminance efficiency of 36.1%and 39.6%,enhanced about 20%relative to that of PODPF.Compared to the liner-type sides'chain,these branched chains also suppress chain planarization and improve film morphological stability effectively.Interestingly,the branched polymer also had excellent stable amplified spontaneous emission(ASE)behaviour with low threshold(4.72μJ/cm2)and a center peak of 465 nm,even thermal annealing at 220℃in the air atmosphere.Therefore,side-chain branched strategy for LCPs is an effective means to control interchain aggregation,film morphology and photophysical property of LCPs.
基金the National Natural Science Foundation of China(Grant No.51776031)the Fundamental Research Funds for Zhejiang Provincial Universities and Research Institutes,Chinathe Key Project of Science and Technology Development of Henan Province,China(Grant No.222102220033)。
摘要The interface deformation and liquid breakup in vapor-liquid two-phase flow are ubiquitous in natural phenomena and industrial applications.It is crucial to understand the corresponding mechanism correctly.The droplet and liquid ligament dynamic behaviors are investigated in this work by simulating three benchmark cases through adopting a three-dimensional(3D)phase-field-based lattice Boltzmann model,and vapor-liquid phase interface deformation and liquid breakup mechanisms including the capillary instability and end-pinching mechanism are analyzed.The analysis results show that the capillary instability is the driving mechanism of the liquid breakup and the secondary droplet production at a large Weber number,which is different from the Rayleigh-Taylor instability and Kelvin-Helmholtz instability characterizing the vapor-liquid interface deformation.In addition,as another liquid breakup mechanism,the end-pinching mechanism,which describes the back-flow phenomenon of the liquid phase,works at each breakup point,thus resulting in capillary instability on the liquid phase structure.In essence,it is the fundamental mechanism for the liquid breakup and the immanent cause of capillary instability.
基金supported by the National Natural Science Foundation of China(Nos.50679061,50709025,50749031)
摘要By choosing a PVC slice to simulate flexible vegetation,we carried out experiments in an open channel with submerged flexible vegetation.A 3D acoustic Doppler velocimeter(micro ADV)was used to measure local flow velocities and Reynolds stress.The results show that hydraulic characteristics in non-vegetation and vegetation layers are totally different.In a region above the vegetation,Reynolds stress distribution is linear,and the measured velocity profile is a classical logarithmic one.Based on the concept of new-riverbed,the river compression parameter representing the impact of vegetation on river is given,and a new assumption of mixing length expression is made.The formula for time-averaged velocity derived from the expression requires less parameters and simple calculation,and is useful in applications.
基金support from the National Natural Science Foundation of China(No.62205141,62105262,62288102,22075136,62405134)supported by the Natural Science Funds of the Education Committee of Jiangsu Province(No.23KJA430010)+5 种基金the Open Fund of the Key Labora-tory of Advanced Display and System Applications,Min-istry of Education,Shanghai University(OF202505)supported by the Natural Science Foundation of Jiangsu Province for Youth(No.BK20230342)supported by the China Postdoctoral Science Foundation(No.2024M753737)the Shenzhen Science and Tech-nology Program(No.RCBS20231211090610014)support from the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX25-1710)The SANS experiments were performed on the small-angle neutron scattering instrument at the China Spallation Neutron Source(CSNS),Dongguan,China(Project ID:P0123122600014).
摘要Molecular-level encapsulation of conjugated polymers serves as a potent approach to isolate the conjugated backbone for reducing intermolecular interactions and manipulating optoelectronic properties in solid state.Herein,by tuning the generation of dendritic carbazoles(Cz)in side chains,polydiarylfluorenes with efficient deep-blue emission have been successfully synthesized and explored.The nonplanar twisted Cz dendrons endow their photoluminescence(PL)spectra with enhanced air-aging stability and thermal stability owing to the formation of a self-encapsulation layer.Their impact on solutionstate chain conformation and aggregation was thoroughly studied,combining small-angle neutron scattering(SANS)and dynamic light scattering(DLS).Furthermore,benefiting from the suppressed intermolecular interactions,their films exhibit optimal behavior of singlet excitons in the excited state.Polymer light-emitting diodes(PLEDs)adopting the spin-coated and blade-coated films both present comparable properties and stable electroluminescence(EL)spectra,with Commission Internationale de L'Eclairage(CIE)coordinates(x+y)<0.3,demonstrating the feasibility of a self-encapsulated molecular design strategy.
基金supported by the Natural Science Foundation of Jiangsu Province(No.BK20200700)National Natural Science Foundation of China(Nos.22075136,61874053)+4 种基金Natural Science Funds of the Education Committee of Jiangsu Province(No.18KJA430009)"High-Level Talents in Six Industries"of Jiangsu Province(No.XYDXX-019)Postgraduate Research&Practice Innovation Program of Jiangsu Province(Nos.KYCX21_1097,KYCX21_0771)Nanjing Vocational University of Industry Technology Start-up Fund(No.YK21-02-07)the open research fund from Anhui Province Key Laboratory of Environment-friendly Polymer Materials and Anhui Province Key Laboratory of Optoelectronic Materials Science and Technology.
摘要In the design of conjugated molecules,modular production enables materials to easily realize structure modification and precisely tune their photoelectrical property.Construction of a novel and universal building block is crucial to design and manufacture high performance and stable conjugated molecules for optoelectronic application.Herein,we originally demonstrated a universal 4-qualifiable fluorene-based building block,which is a fundamental molecular segment to functionalize and obtain novel conjugated materials.Compared to the traditional modification at 9-site,additional 4-position functionalization provided an exciting blueprint to not only tune electronic structure and excited state via p-n molecular design engineering and space charge-transfer strategy,but also allow for optimizing intermolecular arrangement and obtaining solution-processing ability.The introduction of the 4-site substituent in fluorene based semiconductors may endow materials with unique properties.Finally,we successfully prepared two stable deep-blue light-emitting conjugated polymer,PODOPF and PODOF,by utilizing the 4-substituent fluorene based building block.It is believable that the performance,stability and processibility of reported outstanding fluorene-based conjugated molecules can be further optimized based on this universal building block.
基金supported by the National Natural Science Foundation of China(NSFC,Nos.62275002,51902078,62074048,62075053)the Anhui Provincial Natural Science Foundation(2008085MF205)the Fundamental Research Funds for the Central Universities(JZ2020HGTB0051,PA2020GDKC0024).
摘要Two-dimensional layered material/semiconductor heterostructures have emerged as a category of fascinating architectures for developing highly efficient and low-cost photodetection devices.Herein,we present the construction of a highly efficient flexible light detector operating in the visible-near infrared wavelength regime by integrating a PdTe2 multilayer on a thin Si film.A representative device achieves a good photoresponse performance at zero bias including a sizeable current on/off ratio exceeding 105,a decent responsivity of~343 mA/W,a respectable specific detectivity of~2.56×1012Jones,and a rapid response time of 4.5/379μs,under 730 nm light irradiation.The detector also displays an outstanding long-term air stability and operational durability.In addition,thanks to the excellent flexibility,the device can retain its prominent photodetection performance at various bending radii of curvature and upon hundreds of bending tests.Furthermore,the large responsivity and rapid response speed endow the photodetector with the ability to accurately probe heart rate,suggesting a possible application in the area of flexible and wearable health monitoring.
摘要目的探讨以问题为基础的学习(problem based learning,PBL)联合翻转课堂(flipped classroom,FC)教学方法在心血管疾病个体化用药教学中的应用。方法将学生随机分为试验组(PBL+FC教学法)和对照组(传统教学法),通过考核和问卷调查方式评价两种教学方法联合在心血管疾病个体化用药教学中的应用效果。结果试验组的成绩高于传统教学组(P<0.05)。与传统教学法相比,PBL+FC教学法能够增强学生学习兴趣,提高学生自主学习、分析解决问题能力。结论 PBL+FC教学方法优于传统教学法。
基金The work was supported by the National Natural Science Foundation of China(61874053)Natural Science Funds of the Education Committee of Jiangsu Province(18KJA430009)+6 种基金Natural Science Foundation of Jiangsu Province(BK20171470)“High-Level Talents in Six Industries”of Jiangsu Province(XYDXX-019)The open research fund from Key Laboratory for Organic Electronics and Information Display,State Key Laboratory of Supramolecular Structure and Materials(sklssm202014)Program for Postgraduates Research Innovation in University of Jiangsu Province(KYCX20-0996,KYCX18-1121)National Key Research and Development Program of China(2017YFB0404500)Major Program of National Natural Science Foundation of China(91833306)Overseas Merit Foundation of Science and Technology of Nanjing.
摘要The intrinsically rigid and limited strain of most conjugated polymers has encouraged us to optimize the extensible properties of conjugated polymers.Herein,learning from the hydrogen bonds in glucose,which were facilitated to the toughness enhancement of cellulose,we introduced interchain hydrogen bonds to polydiarylfluorene by amide-containing side chains.Through tuning the copolymerization ratio,we systematically investigated their influence on the hierarchical condensed structures,rheology behavior,tensile performances,and optoelectronic properties of conjugated polymers.Compared to the reference copolymers with a low ratio of amide units,copolymers with 30%and 40%amide units present a feature of the shearthinning process that resembled the non-Newtonian fluid,which was enabled by the interchain dynamic hydrogen bonds.Besides,we developed a practical and universal method for measuring the intrinsic mechanical properties of conjugated polymers.We demonstrated the significant impact of hydrogen bonds in solution gelation,material crystallization,and thin film stretchability.Impressively,the breaking elongation for P4 was even up to~30%,which confirmed the partially enhanced film ductility and toughness due to the increased amide groups.Furthermore,polymer light-emitting devices(PLEDs)based on these copolymers presented comparable performances and stable electroluminescence(EL).Thin films of these copolymers also exhibited random laser emission with the threshold as low as 0.52μJ/cm2,suggesting the wide prospective application in the field of flexible optoelectronic devices.