Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and...Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and hierarchical.Due to their porous nature,interfacial compatibility,and electrical conductivity,biomass materials hold significant potential as EMI shielding materials.Despite concerted efforts on the EMI shielding of biomass materials have been reported,this research area is still relatively new compared to traditional EMI shielding materials.In particular,a more comprehensive study and summary of the factors influencing biomass EMI shielding materials including the pore structure adjustment,preparation process,and micro-control would be valuable.The preparation methods and characteristics of wood,bamboo,cellulose and lignin in EMI shielding field are critically discussed in this paper,and similar biomass EMI materials are summarized and analyzed.The composite methods and fillers of various biomass materials were reviewed.this paper also highlights the mechanism of EMI shielding as well as existing prospects and challenges for development trends in this field.展开更多
Background:The study was conducted with the interest of exploring the effects of Qingre Yangyin Chushi pill as anti-inflammatory agent in gout treatment based on the NLRP3/GSDMD coke death pathway.Methods:In this stud...Background:The study was conducted with the interest of exploring the effects of Qingre Yangyin Chushi pill as anti-inflammatory agent in gout treatment based on the NLRP3/GSDMD coke death pathway.Methods:In this study,48 male SD rats were randomly divided into 6 groups,namely model group,blank control group(BC),Qingre Yangyin Chushi pill low-dose treatment group(MSD1),medium-dose treatment group(MSD2),high-dose treatment group(MSD3),and colchicine group(PC),with eight members in each group.The BC and model groups were administered with saline twice a day.The MSD1,MSD2,and MSD3 groups were administered with Qingre Yangyin Chushi pill at a dose of 1.8 g·kg^?1,3.6 g·kg^?1,and 7.2 g·kg^?1 twice a day.The colchicine group was administered with a colchicine suspension at a dose of 0.6×10^?3 g kg^?1 twice a day for 7 days.After gavage of animals in each group for 4 days,the rats'ankle joints were injected with sodium urate suspension×3 days to induce a gouty arthritis model.Then,serum and tissue samples were collected on the third and seventh day after gavage.The synovial tissue from the rat ankle joints was taken,and immunohistochemical technique was used to detect NOD-like receptor protein 3(NLRP3),inflammatory bodies,cysteine protease-1(Caspase-1),and Gasdermin-D protein(GSDMD)expression.Image-Pro Plus image analysis system was used to measure the average integrated absorbance and calculate IHS.Integral enzyme-linked immunosorbent assay was used to determine the interleukin 1β(IL-1β)and interleukin 18(IL-18)expression of tumor necrosis factor-α(TNF-α).Western blot was used to detect NLRP3,Caspase-1,GSDMD,and apoptosis-associated speck-like protein containing a CARD(ASC)expression levels.Results:After 48 hours of modeling,compared with the PC group,the arthritis indices of the MSD1,MSD2,and MSD3 groups were insignificant(P>0.05).The levels of IL-1β,IL-18,and TNF-αwere lower in the PC and MSD2 groups compared with the BC group.However,compared with the control group,MSD1,MSD2,and PC groups had lower levels of IL-1βand IL-18.Regarding TNF-αlevels(P<0.05);compared with the PC group,the levels of IL-1β,IL-18,and TNF-αin MSD2 decreased more significantly(P<0.05).The levels of NLRP3,Caspase-1,GSDMD,ASC,IHS score,and mRNA were lower in the PC and MSD2 groups(P<0.05)compared with the control group.The MSD1 and MSD2 groups had lower levels of NLRP3,Caspase-1,GSDMD,ASC protein levels,IHS points,and mRNA levels(P<0.05)compared with the PC group.Moreover,NLRP3,Caspase-1,GSDMD,ASC protein levels,IHS points,and mRNA levels were more reduced in the MSD2 group(P<0.05).Conclusion:Qingre Yangyin Chushi pill can inhibit the activation of the NLPR3 inflammatory complex,reduce the production of GSDMD protein,regulate the occurrence of pyroptosis,reduce the expression of inflammatory factors,and thus reduce arthritis.All these processes are achieved through the NLRP3/GSDMD pathway.展开更多
This study establishes a high-speed nano-positioning stage composed of a symmetrically driven structure with multiple parallel-bonded thin piezoelectric ceramic layers capable of performing micro-or nanoscale manipula...This study establishes a high-speed nano-positioning stage composed of a symmetrically driven structure with multiple parallel-bonded thin piezoelectric ceramic layers capable of performing micro-or nanoscale manipulations.Accordingly,a neural-network-based switching output regulation controller(NNSORC)was developed to compensate for the associated hysteresis nonlinearity.To address the challenges of slow floating-point computation speeds and low compilation efficiency,a closed-loop control system with a field-programmable gate array–central processing unit(FPGA–CPU)dual-layer data-processing framework was developed.A feedback linearization method was designed to linearize the hysteresis nonlinearity of the framework,resulting in a switching-tracking error system.With the assistance of Lyapunov theory and an average dwell time technique,sufficient conditions were derived to ensure the asymptotic stability of the NN-SORC governing closed-loop system using the switching reference signals often encountered in realistic micro-ano-scale detection and manufacturing processes.Finally,extensive comparative experiments were conducted to verify the effectiveness and superiority of the proposed NN-SORC scheme.展开更多
Magnesium hydride(MgH2)has received widespread attention because of its high hydrogen capacity and low cost,but the sluggish kinetics limited its practical application.Herein,the two-dimensional Mo2C MXene was c...Magnesium hydride(MgH2)has received widespread attention because of its high hydrogen capacity and low cost,but the sluggish kinetics limited its practical application.Herein,the two-dimensional Mo2C MXene was constructed to motivate the efficient hydrogen storage in MgH2for the first time.After doping 10 wt%Mo2C MXene,the starting dehydriding temperature was lowered to 225℃,presenting a 117℃ reduction compared with that of as-received MgH2.The 10 wt%Mo2C-containing MgH2sample could rapidly release 6.7 wt%H2in 13 min at 300℃,and the product after hydrogen release could absorb 6.0 wt%H2in 12 min at 200℃,showing superior hydriding and dehydriding kinetics.Moreover,the activation energy(Ea)of MgH2–10 wt%Mo2C(107.58±1.57 kJ/mol)was obviously lower than that of pure MgH2(130.45±1.97 kJ/mol),and the reduced activation energy explained the reduced dehydrogenation temperature and enhanced kinetics.Microstructure characterization revealed that Mo-species(Mo0and Mo2+)formed during ball milling served as active species accelerated the hydriding/dehydriding reactions,and the uniformly distributed active species and the interaction between Mo and O jointly promoted the hydrogen storage properties of MgH2.展开更多
The original intention of Model Predictive Control(MPC)was to bridge the gap between advanced control theories and the application of complex practical engineering systems.Since its emergence in the 1970s,it has been ...The original intention of Model Predictive Control(MPC)was to bridge the gap between advanced control theories and the application of complex practical engineering systems.Since its emergence in the 1970s,it has been one of the core technologies in the Advanced Process Control(APC)system.Owing to its receding horizon optimization mechanism and capability to handle constraints,MPC has consistently attracted attention from both academia and industry,and has been successfully applied in numerous industries such as petrochemicals,metallurgy,pharmaceuticals,electric power,water treatment,and power electronics.According to statistics from the International Federation of Automatic Control and industrial data,MPC has been deployed in some form in more than 50% of large-scale industrial control systems worldwide.展开更多
The skin repair process is significantly influenced by the regulation of a dynamic mechanical microenvironment.However,traditional single-layer scaffolds face limitations,including poor mechanical compatibility and we...The skin repair process is significantly influenced by the regulation of a dynamic mechanical microenvironment.However,traditional single-layer scaffolds face limitations,including poor mechanical compatibility and weak interfacial adhesion.These drawbacks stem from their inability to mimic the multilayer heterogeneous structure and functional synergy of natural skin.In this paper,a biomimetic skin extracellular matrix(ECM)scaffold with a layered structure bio-polycaprolactone(PCL)skin(BPS)is proposed,consisting of three layers:a surface layer(SL),a support layer(PL),and a base layer(BL).The SL consists of a 3D-printed microporous PCL structure,which simulates the epidermal barrier’s antibacterial and breathable properties.The PL,a surface-modified multilayer PCL scaffold,mimics the dermal layer and provides essential mechanical support and elasticity.The BL,a hydrogel coated onto the surface of the PL,provides excellent biological properties.Genipin serves as a crosslinker,and ethylenediamine is used for amination treatment of the PCL scaffold surface.This chemical crosslinking strengthens interlayer connections,enhancing functional synergy and tripling the anti-swelling properties of the hydrogel.Additionally,it improves the wet adhesion of the scaffold to skin tissue,ensuring stable adherence to the wound surface.Compared to traditional scaffolds,this multilayer structure effectively integrates biological functions with mechanical performance,providing sustained protection and support during wound healing.展开更多
Unmanned Aerial Vehicles(UAVs)are increasingly deployed in safety-critical missions that demand advanced control strategies capable of addressing nonlinear dynamics,stringent constraints,and uncertain environments.Mod...Unmanned Aerial Vehicles(UAVs)are increasingly deployed in safety-critical missions that demand advanced control strategies capable of addressing nonlinear dynamics,stringent constraints,and uncertain environments.Model Predictive Control(MPC)has emerged as a powerful framework for these challenges,yet its finite-horizon nature requires additional stabilizing mechanisms to ensure reliable closed-loop performance.Among the existing stabilizing strategies,Lyapunov-based MPC has attracted significant attention for embedding explicit stability conditions into the optimization problem,providing a flexible and computationally efficient alternative to terminal-ingredient formulations.This paper provides a comprehensive survey of Lyapunovbased MPC for UAVs,examining its stabilizing mechanism and tracing its evolution from a theoretical tool to a practical framework.The survey classifies existing contributions according to control tasks,modeling fidelity,system architectures,stability assurance mechanisms,and validation strategies.Beyond a descriptive review,the survey critically analyzes fundamental limitations and deployment bottlenecks related to conservatism,assumptions,and real-time implementation.Finally,key research directions are outlined,focusing on reducing conservatism,improving scalability,enhancing robustness,and strengthening implementation-aware validation.These findings position Lyapunov-based MPC as a promising framework for next-generation UAV autonomy.展开更多
The Fushan Depression is one of the petroliferous depressions in the Beibuwan Basin,South China Sea.Previous studies have preliminarily explored the origin and source of crude oils in some areas of this depression.Nev...The Fushan Depression is one of the petroliferous depressions in the Beibuwan Basin,South China Sea.Previous studies have preliminarily explored the origin and source of crude oils in some areas of this depression.Nevertheless,no systematic investigations on the classification and origin of oils and hy-drocarbon migration processes have been made for the entire petroleum system in this depression,which has significantly hindered the hydrocarbon exploration in the region.A total of 32 mudstone and 58 oil samples from the Fushan Depression were analyzed to definite the detailed oil-source correlation within the sequence and sedimentary framework.The organic matter of third member of Paleogene Liushagang Formation(Els(3))source rocks,both deltaic and lacustrine mudstone,are algal-dominated with high abundance of C23tricyclic terpane and C304-methylsteranes.The deltaic source rocks occur-ring in the first member(Els1)and second member(Els2)of the Paleogene Liushagang Formation are characterized by high abundance of C19+20tricyclic terpane and oleanane,reflecting a more terrestrial plants contribution.While lacustrine source rocks of Els1and Els2display the reduced input of terrige-nous organic matter with relatively low abundance of C 19+20 tricyclic terpane and oleanane.Three types of oils were identified by their biomarker compositions in this study.Most of the oils discovered in the Huachang and Bailian Els1reservoir belong to group A and were derived from lacustrine source rocks of Els1and Els2.Group B oils are found within the Els1and Els2reservoirs,showing a close relation to the deltaic source rocks of Els1and Els2,respectively.Group C oils,occurring in the Els3 reservoirs,have a good affinity with the Els3 source rocks.The spatial distribution and accumulation of different groups of oils are mainly controlled by the sedimentary facies and specific structural conditions.The Els2reservoir in the Yong'an area belonging to Group B oil,are adjacent to the source kitchen and could be considered as the favorable exploration area in the future.展开更多
Carbon quantum dots are a new type of fluorescent nanomaterials with broad applications in drug delivery,bioimaging,solar cells,and photocatalysis due to their unique biocompatibility,optical properties and easy funct...Carbon quantum dots are a new type of fluorescent nanomaterials with broad applications in drug delivery,bioimaging,solar cells,and photocatalysis due to their unique biocompatibility,optical properties and easy functionalization.In the meantime,because of its high carbon content,renewable nature,and environmental friendliness,lignin has drawn the attention of researchers as a desirable raw material for creating carbon quantum dots.Here we review the synthesis of carbon quantum dots from lignin,focusing on synthetic methods,properties,and applications in energy,and photocatalysis.Later,we propose some new development prospects from preparation methods,luminescence mechanism research,application,and commercial cost of lignin carbon quantum dots.Finally,based on this,the development prospects of this field are prospected and summarized.展开更多
Dear Editor,This letter proposes a deep synchronization control(DSC) method to synchronize grid-forming converters with power grids. The method involves constructing a novel controller for grid-forming converters base...Dear Editor,This letter proposes a deep synchronization control(DSC) method to synchronize grid-forming converters with power grids. The method involves constructing a novel controller for grid-forming converters based on the stable deep dynamics model. To enhance the performance of the controller, the dynamics model is optimized within the deep reinforcement learning(DRL) framework. Simulation results verify that the proposed method can reduce frequency deviation and improve active power responses.展开更多
BACKGROUND Krüppel-like factor-5(KLF5)is a zinc-finger transcription factor related to tumor progression.However,the relationship between KLF5 and lung cancer remains to be identified.AIM To investigate the clini...BACKGROUND Krüppel-like factor-5(KLF5)is a zinc-finger transcription factor related to tumor progression.However,the relationship between KLF5 and lung cancer remains to be identified.AIM To investigate the clinical value of KLF5 and interference with KLF5 mRNA transcription on the effects of biological behaviors in lung squamous-cell carcinoma(LUSC).METHODS Lung KLF5 mRNA data were extracted from bioinformatics databases.Blood and tissues from a cohort of patients with benign or malignant lung diseases were collected with ethical committee consent to validate KLF5 expression via multiplex immunofluorescence and immunohistochemistry,Western blot,Enzyme Linked Immunosorbent Assay or quantitative polymerase chain reaction.Furthermore,KLF5 mRNA was silenced in lung A549 cells to validate biological behaviors in vitro and nude mouse xenograft growth in vivo,respectively.RESULTS A cohort of bioinformatics databases revealed high KLF5 mRNA expression in LUSC(P<0.001)but lower KLF5 mRNA expression in lung adenocarcinoma.Upregulated KLF5 in the lung or sera of patients with lung cancer(P<0.001)were confirmed that related to poor differentiation,lymph node or distant metastasis.Furthermore,the incidence of KLF5 levels greater than 500 ng/mL in LUSC patients was 86.7%,which was significantly greater(P<0.001)than that in cases with benign lung diseases(13.3%)or healthy controls.Functionally,silencing KLF5 mRNA with a specific shRNA significantly suppressed A549 cell proliferation,decreased cell migration,increased the ratio of G2 phase cells in vitro,and inhibited the growth of nude mouse xenografts in vivo.CONCLUSION KLF5 is a novel diagnostic biomarker or potential therapeutic target for LUSC.展开更多
Lithium(Li)deposition and nucleation at solid electrolyte interphase(SEI)is the main origin for the capacity decay in Li metal batteries(LMBs).SEI conversion with enhanced electrochemical and mechanical properties is ...Lithium(Li)deposition and nucleation at solid electrolyte interphase(SEI)is the main origin for the capacity decay in Li metal batteries(LMBs).SEI conversion with enhanced electrochemical and mechanical properties is an effective approach to achieve uniform nucleation of Li+and stabilize the lithium metal anode.However,complex interfacial reaction mechanisms and interface compatibility issues hinder the development of SEI conversion strategies for stabilizing lithium metal anodes.Herein,we presented the release of I3-in–NH2-modified metal–organic frameworks for a Li metal surface SEI phase conversion strategy.The–NH2group in MOF pores induced the formation of I3-from I2,which was further spontaneously reacted with inactive Li2O transforming into high-performance LiI and LiIO3interphase.Furthermore,theoretical calculation provided deeply insight into the unique reconstructed interfacial formation and electrochemical mechanism of rich LiI and LiIO3SEI.As a result,the Li+deposition and nucleation were improved,facilitating the transport kinetics of Li+and inhibiting the growth of lithium dendrites.The assembled solid-state Li||LiFePO4full cells exhibited superior long-term stability of 800 cycles and high Coulombic efficiency(>99%),Li||LiNi0.8Co0.1Mn0.1O2pouch cell also displayed superior practical performance over 200 cycles at 2 C,high loading of 5 mg cm-2and safety performance.This innovative SEI design strategy promotes the development of high-performance solid-state Li metal batteries.展开更多
Switched systems play an imperative role in modeling many real industrial systems with abrupt changes.Due to possible exposure to unreliable and complex physical environments,switching dynamics may simultaneously face...Switched systems play an imperative role in modeling many real industrial systems with abrupt changes.Due to possible exposure to unreliable and complex physical environments,switching dynamics may simultaneously face multiple faults,including the unexpected controller disconnect,the temporary mismatch between subsystems and desired corresponding controllers,and the intermittent disordering of mode transitions.These commonly arising faults may result in severe and detrimental impacts on the reliability and convergence of the closed-loop solution,thereby bringing significant yet challenging issues to be tackled.This paper provides the first attempt to investigate the stabilization problem for a class of constrained switched linear systems with multiple faults under mode-dependent dwell time(MDT).From a set-theory perspective,we demonstrate a critical necessary and sufficient stability condition for switched systems without uncertainties.Moreover,the non-conservative stability criterion is further extended to the perturbed switched systems with rigorous proof.A switching communication network example verifies the validity of the theoretical result and demonstrates their advantages.展开更多
Recurrent neural networks(RNNs)have been employed extensively as intelligent control approaches across various industrial control fields.However,existing research often lacks sufficient focus on discrete-form time-var...Recurrent neural networks(RNNs)have been employed extensively as intelligent control approaches across various industrial control fields.However,existing research often lacks sufficient focus on discrete-form time-variant problems and disturbance rejection capability.This paper proposes a novel discrete-form integral-reinforcing RNN(DF-IR-RNN)approach.This approach integrates an innovative integral-reinforcing RNN(IR-RNN)design thought into the RNN approach to enhance the disturbance rejection capability in controlling the Stewart platform under discrete-form time-variant environment.Compared to traditional approaches,the proposed approach overcomes their limitations of disturbance rejection.The experimental results demonstrate that the proposed approach is highly effective in disturbance rejection and accurate trajectory tracking.展开更多
基金National Natural Science Foundation of China(32201491)Young Elite Scientists Sponsorship Program by CAST(2023QNRC001)The authors extend their appreciation to the Deanship of Scientific Research at Northern Border University,Arar,KSA for funding this research work through the project number“NBU-FPEJ-2024-1101-02”.
摘要Research efforts on electromagnetic interference(EMI)shielding materials have begun to converge on green and sustainable biomass materials.These materials offer numerous advantages such as being lightweight,porous,and hierarchical.Due to their porous nature,interfacial compatibility,and electrical conductivity,biomass materials hold significant potential as EMI shielding materials.Despite concerted efforts on the EMI shielding of biomass materials have been reported,this research area is still relatively new compared to traditional EMI shielding materials.In particular,a more comprehensive study and summary of the factors influencing biomass EMI shielding materials including the pore structure adjustment,preparation process,and micro-control would be valuable.The preparation methods and characteristics of wood,bamboo,cellulose and lignin in EMI shielding field are critically discussed in this paper,and similar biomass EMI materials are summarized and analyzed.The composite methods and fillers of various biomass materials were reviewed.this paper also highlights the mechanism of EMI shielding as well as existing prospects and challenges for development trends in this field.
基金This study was supported by the General Project of Beijing Natural Science Foundation(No.7172101)the Beijing Municipal Hospital Research and Cultivation Project(No.PZ2017015)the Beijing Hospital of Traditional Chinese Medicine Gospital-Level Project(No.YJ-201807).
摘要Background:The study was conducted with the interest of exploring the effects of Qingre Yangyin Chushi pill as anti-inflammatory agent in gout treatment based on the NLRP3/GSDMD coke death pathway.Methods:In this study,48 male SD rats were randomly divided into 6 groups,namely model group,blank control group(BC),Qingre Yangyin Chushi pill low-dose treatment group(MSD1),medium-dose treatment group(MSD2),high-dose treatment group(MSD3),and colchicine group(PC),with eight members in each group.The BC and model groups were administered with saline twice a day.The MSD1,MSD2,and MSD3 groups were administered with Qingre Yangyin Chushi pill at a dose of 1.8 g·kg^?1,3.6 g·kg^?1,and 7.2 g·kg^?1 twice a day.The colchicine group was administered with a colchicine suspension at a dose of 0.6×10^?3 g kg^?1 twice a day for 7 days.After gavage of animals in each group for 4 days,the rats'ankle joints were injected with sodium urate suspension×3 days to induce a gouty arthritis model.Then,serum and tissue samples were collected on the third and seventh day after gavage.The synovial tissue from the rat ankle joints was taken,and immunohistochemical technique was used to detect NOD-like receptor protein 3(NLRP3),inflammatory bodies,cysteine protease-1(Caspase-1),and Gasdermin-D protein(GSDMD)expression.Image-Pro Plus image analysis system was used to measure the average integrated absorbance and calculate IHS.Integral enzyme-linked immunosorbent assay was used to determine the interleukin 1β(IL-1β)and interleukin 18(IL-18)expression of tumor necrosis factor-α(TNF-α).Western blot was used to detect NLRP3,Caspase-1,GSDMD,and apoptosis-associated speck-like protein containing a CARD(ASC)expression levels.Results:After 48 hours of modeling,compared with the PC group,the arthritis indices of the MSD1,MSD2,and MSD3 groups were insignificant(P>0.05).The levels of IL-1β,IL-18,and TNF-αwere lower in the PC and MSD2 groups compared with the BC group.However,compared with the control group,MSD1,MSD2,and PC groups had lower levels of IL-1βand IL-18.Regarding TNF-αlevels(P<0.05);compared with the PC group,the levels of IL-1β,IL-18,and TNF-αin MSD2 decreased more significantly(P<0.05).The levels of NLRP3,Caspase-1,GSDMD,ASC,IHS score,and mRNA were lower in the PC and MSD2 groups(P<0.05)compared with the control group.The MSD1 and MSD2 groups had lower levels of NLRP3,Caspase-1,GSDMD,ASC protein levels,IHS points,and mRNA levels(P<0.05)compared with the PC group.Moreover,NLRP3,Caspase-1,GSDMD,ASC protein levels,IHS points,and mRNA levels were more reduced in the MSD2 group(P<0.05).Conclusion:Qingre Yangyin Chushi pill can inhibit the activation of the NLPR3 inflammatory complex,reduce the production of GSDMD protein,regulate the occurrence of pyroptosis,reduce the expression of inflammatory factors,and thus reduce arthritis.All these processes are achieved through the NLRP3/GSDMD pathway.
基金supported in part by the National Key Research and Development Program of China(2022ZD0119601)the National Natural Science Foundation of China(52188102,62225306,and U2141235)the Guangdong Basic and Applied Research Foundation(2022B1515120069)。
摘要This study establishes a high-speed nano-positioning stage composed of a symmetrically driven structure with multiple parallel-bonded thin piezoelectric ceramic layers capable of performing micro-or nanoscale manipulations.Accordingly,a neural-network-based switching output regulation controller(NNSORC)was developed to compensate for the associated hysteresis nonlinearity.To address the challenges of slow floating-point computation speeds and low compilation efficiency,a closed-loop control system with a field-programmable gate array–central processing unit(FPGA–CPU)dual-layer data-processing framework was developed.A feedback linearization method was designed to linearize the hysteresis nonlinearity of the framework,resulting in a switching-tracking error system.With the assistance of Lyapunov theory and an average dwell time technique,sufficient conditions were derived to ensure the asymptotic stability of the NN-SORC governing closed-loop system using the switching reference signals often encountered in realistic micro-ano-scale detection and manufacturing processes.Finally,extensive comparative experiments were conducted to verify the effectiveness and superiority of the proposed NN-SORC scheme.
基金financially supported by the National Natural Science Foundation of China(U22A20120,52071135,51871090,U1804135,and 52401274)the Natural Science Foundation of Hebei Province for Innovation Groups Program(C2022203003)the Fundamental Research Funds for the Universities of Henan Province(NSFRF220201)+2 种基金Key R&D Special Project of Henan Province(241111240200)the Key Project of Henan Provincial Natural Science Foundation(242300421184)the Henan Province Science and Technology Research Projects(242102241035 and 232102231048).
摘要Magnesium hydride(MgH2)has received widespread attention because of its high hydrogen capacity and low cost,but the sluggish kinetics limited its practical application.Herein,the two-dimensional Mo2C MXene was constructed to motivate the efficient hydrogen storage in MgH2for the first time.After doping 10 wt%Mo2C MXene,the starting dehydriding temperature was lowered to 225℃,presenting a 117℃ reduction compared with that of as-received MgH2.The 10 wt%Mo2C-containing MgH2sample could rapidly release 6.7 wt%H2in 13 min at 300℃,and the product after hydrogen release could absorb 6.0 wt%H2in 12 min at 200℃,showing superior hydriding and dehydriding kinetics.Moreover,the activation energy(Ea)of MgH2–10 wt%Mo2C(107.58±1.57 kJ/mol)was obviously lower than that of pure MgH2(130.45±1.97 kJ/mol),and the reduced activation energy explained the reduced dehydrogenation temperature and enhanced kinetics.Microstructure characterization revealed that Mo-species(Mo0and Mo2+)formed during ball milling served as active species accelerated the hydriding/dehydriding reactions,and the uniformly distributed active species and the interaction between Mo and O jointly promoted the hydrogen storage properties of MgH2.
摘要The original intention of Model Predictive Control(MPC)was to bridge the gap between advanced control theories and the application of complex practical engineering systems.Since its emergence in the 1970s,it has been one of the core technologies in the Advanced Process Control(APC)system.Owing to its receding horizon optimization mechanism and capability to handle constraints,MPC has consistently attracted attention from both academia and industry,and has been successfully applied in numerous industries such as petrochemicals,metallurgy,pharmaceuticals,electric power,water treatment,and power electronics.According to statistics from the International Federation of Automatic Control and industrial data,MPC has been deployed in some form in more than 50% of large-scale industrial control systems worldwide.
基金supported by the Huzhou Science and Technology Plan Project(No.2023YZ42)the Zhejiang Provincial Key Research and Development Program(No.2024C03081)the Construction of Zhejiang Key Laboratory of Industrial Solid Waste Thermal Hydrolysis Technology and Intelligent Equipment(No.2025ZY01056),China.
摘要The skin repair process is significantly influenced by the regulation of a dynamic mechanical microenvironment.However,traditional single-layer scaffolds face limitations,including poor mechanical compatibility and weak interfacial adhesion.These drawbacks stem from their inability to mimic the multilayer heterogeneous structure and functional synergy of natural skin.In this paper,a biomimetic skin extracellular matrix(ECM)scaffold with a layered structure bio-polycaprolactone(PCL)skin(BPS)is proposed,consisting of three layers:a surface layer(SL),a support layer(PL),and a base layer(BL).The SL consists of a 3D-printed microporous PCL structure,which simulates the epidermal barrier’s antibacterial and breathable properties.The PL,a surface-modified multilayer PCL scaffold,mimics the dermal layer and provides essential mechanical support and elasticity.The BL,a hydrogel coated onto the surface of the PL,provides excellent biological properties.Genipin serves as a crosslinker,and ethylenediamine is used for amination treatment of the PCL scaffold surface.This chemical crosslinking strengthens interlayer connections,enhancing functional synergy and tripling the anti-swelling properties of the hydrogel.Additionally,it improves the wet adhesion of the scaffold to skin tissue,ensuring stable adherence to the wound surface.Compared to traditional scaffolds,this multilayer structure effectively integrates biological functions with mechanical performance,providing sustained protection and support during wound healing.
基金supported by the Natural Sciences and Engineering Research Council of Canada(NSERC)。
摘要Unmanned Aerial Vehicles(UAVs)are increasingly deployed in safety-critical missions that demand advanced control strategies capable of addressing nonlinear dynamics,stringent constraints,and uncertain environments.Model Predictive Control(MPC)has emerged as a powerful framework for these challenges,yet its finite-horizon nature requires additional stabilizing mechanisms to ensure reliable closed-loop performance.Among the existing stabilizing strategies,Lyapunov-based MPC has attracted significant attention for embedding explicit stability conditions into the optimization problem,providing a flexible and computationally efficient alternative to terminal-ingredient formulations.This paper provides a comprehensive survey of Lyapunovbased MPC for UAVs,examining its stabilizing mechanism and tracing its evolution from a theoretical tool to a practical framework.The survey classifies existing contributions according to control tasks,modeling fidelity,system architectures,stability assurance mechanisms,and validation strategies.Beyond a descriptive review,the survey critically analyzes fundamental limitations and deployment bottlenecks related to conservatism,assumptions,and real-time implementation.Finally,key research directions are outlined,focusing on reducing conservatism,improving scalability,enhancing robustness,and strengthening implementation-aware validation.These findings position Lyapunov-based MPC as a promising framework for next-generation UAV autonomy.
基金funded by the South Oil Exploration and Development Company of PetroChina(2021-HNYJ-010).
摘要The Fushan Depression is one of the petroliferous depressions in the Beibuwan Basin,South China Sea.Previous studies have preliminarily explored the origin and source of crude oils in some areas of this depression.Nevertheless,no systematic investigations on the classification and origin of oils and hy-drocarbon migration processes have been made for the entire petroleum system in this depression,which has significantly hindered the hydrocarbon exploration in the region.A total of 32 mudstone and 58 oil samples from the Fushan Depression were analyzed to definite the detailed oil-source correlation within the sequence and sedimentary framework.The organic matter of third member of Paleogene Liushagang Formation(Els(3))source rocks,both deltaic and lacustrine mudstone,are algal-dominated with high abundance of C23tricyclic terpane and C304-methylsteranes.The deltaic source rocks occur-ring in the first member(Els1)and second member(Els2)of the Paleogene Liushagang Formation are characterized by high abundance of C19+20tricyclic terpane and oleanane,reflecting a more terrestrial plants contribution.While lacustrine source rocks of Els1and Els2display the reduced input of terrige-nous organic matter with relatively low abundance of C 19+20 tricyclic terpane and oleanane.Three types of oils were identified by their biomarker compositions in this study.Most of the oils discovered in the Huachang and Bailian Els1reservoir belong to group A and were derived from lacustrine source rocks of Els1and Els2.Group B oils are found within the Els1and Els2reservoirs,showing a close relation to the deltaic source rocks of Els1and Els2,respectively.Group C oils,occurring in the Els3 reservoirs,have a good affinity with the Els3 source rocks.The spatial distribution and accumulation of different groups of oils are mainly controlled by the sedimentary facies and specific structural conditions.The Els2reservoir in the Yong'an area belonging to Group B oil,are adjacent to the source kitchen and could be considered as the favorable exploration area in the future.
基金Sponsorship Program by CAST(2023QNRC001)University-Industry Collaborative Education Program(220901115200913,220901115201954)+2 种基金Hunan Provincial Natural Science Foundation of China(2022JJ40007)Jiangsu Agricultural Science and Technology Innovation Fund(CX(22)3047)the National Natural Science Foundation of China(32201491)。
摘要Carbon quantum dots are a new type of fluorescent nanomaterials with broad applications in drug delivery,bioimaging,solar cells,and photocatalysis due to their unique biocompatibility,optical properties and easy functionalization.In the meantime,because of its high carbon content,renewable nature,and environmental friendliness,lignin has drawn the attention of researchers as a desirable raw material for creating carbon quantum dots.Here we review the synthesis of carbon quantum dots from lignin,focusing on synthetic methods,properties,and applications in energy,and photocatalysis.Later,we propose some new development prospects from preparation methods,luminescence mechanism research,application,and commercial cost of lignin carbon quantum dots.Finally,based on this,the development prospects of this field are prospected and summarized.
基金supported in part by the National Natural Science Foundation of China(62033005,62273270)the Natural Science Foundation of Shaanxi Province(2023JC-XJ17)
摘要Dear Editor,This letter proposes a deep synchronization control(DSC) method to synchronize grid-forming converters with power grids. The method involves constructing a novel controller for grid-forming converters based on the stable deep dynamics model. To enhance the performance of the controller, the dynamics model is optimized within the deep reinforcement learning(DRL) framework. Simulation results verify that the proposed method can reduce frequency deviation and improve active power responses.
基金Supported by Jiangsu Commission of Health of China,No.M2020096.
摘要BACKGROUND Krüppel-like factor-5(KLF5)is a zinc-finger transcription factor related to tumor progression.However,the relationship between KLF5 and lung cancer remains to be identified.AIM To investigate the clinical value of KLF5 and interference with KLF5 mRNA transcription on the effects of biological behaviors in lung squamous-cell carcinoma(LUSC).METHODS Lung KLF5 mRNA data were extracted from bioinformatics databases.Blood and tissues from a cohort of patients with benign or malignant lung diseases were collected with ethical committee consent to validate KLF5 expression via multiplex immunofluorescence and immunohistochemistry,Western blot,Enzyme Linked Immunosorbent Assay or quantitative polymerase chain reaction.Furthermore,KLF5 mRNA was silenced in lung A549 cells to validate biological behaviors in vitro and nude mouse xenograft growth in vivo,respectively.RESULTS A cohort of bioinformatics databases revealed high KLF5 mRNA expression in LUSC(P<0.001)but lower KLF5 mRNA expression in lung adenocarcinoma.Upregulated KLF5 in the lung or sera of patients with lung cancer(P<0.001)were confirmed that related to poor differentiation,lymph node or distant metastasis.Furthermore,the incidence of KLF5 levels greater than 500 ng/mL in LUSC patients was 86.7%,which was significantly greater(P<0.001)than that in cases with benign lung diseases(13.3%)or healthy controls.Functionally,silencing KLF5 mRNA with a specific shRNA significantly suppressed A549 cell proliferation,decreased cell migration,increased the ratio of G2 phase cells in vitro,and inhibited the growth of nude mouse xenografts in vivo.CONCLUSION KLF5 is a novel diagnostic biomarker or potential therapeutic target for LUSC.
基金financial support from National Natural Science Foundation of China(22271178,U2032131,21972103)International Cooperation Key Project of Science and Technology Department of Shaanxi,China(2022KWZ-06)+3 种基金the Youth Talent Promotion Project of Science and Technology Association of Universities of Shaanxi Province(20210602)Research Project of Xi’an Science and Technology Bureau(2022GXFW0011)Science and Technology New Star in Shaanxi Province(2023KJXX-045)Shaanxi Provincial Department of Education Service Local Special Project,Industrialization Cultivation Project(23JC007)。
摘要Lithium(Li)deposition and nucleation at solid electrolyte interphase(SEI)is the main origin for the capacity decay in Li metal batteries(LMBs).SEI conversion with enhanced electrochemical and mechanical properties is an effective approach to achieve uniform nucleation of Li+and stabilize the lithium metal anode.However,complex interfacial reaction mechanisms and interface compatibility issues hinder the development of SEI conversion strategies for stabilizing lithium metal anodes.Herein,we presented the release of I3-in–NH2-modified metal–organic frameworks for a Li metal surface SEI phase conversion strategy.The–NH2group in MOF pores induced the formation of I3-from I2,which was further spontaneously reacted with inactive Li2O transforming into high-performance LiI and LiIO3interphase.Furthermore,theoretical calculation provided deeply insight into the unique reconstructed interfacial formation and electrochemical mechanism of rich LiI and LiIO3SEI.As a result,the Li+deposition and nucleation were improved,facilitating the transport kinetics of Li+and inhibiting the growth of lithium dendrites.The assembled solid-state Li||LiFePO4full cells exhibited superior long-term stability of 800 cycles and high Coulombic efficiency(>99%),Li||LiNi0.8Co0.1Mn0.1O2pouch cell also displayed superior practical performance over 200 cycles at 2 C,high loading of 5 mg cm-2and safety performance.This innovative SEI design strategy promotes the development of high-performance solid-state Li metal batteries.
基金supported in part by the Natural Sciences and Engineering Research Council of Canada(NSERC)supported by the National Natural Science Foundation of China under Grant 62303403Zhejiang Provincial Natural Science Foundation of China under Grants LR25F030004 and LQ24F030022。
摘要Switched systems play an imperative role in modeling many real industrial systems with abrupt changes.Due to possible exposure to unreliable and complex physical environments,switching dynamics may simultaneously face multiple faults,including the unexpected controller disconnect,the temporary mismatch between subsystems and desired corresponding controllers,and the intermittent disordering of mode transitions.These commonly arising faults may result in severe and detrimental impacts on the reliability and convergence of the closed-loop solution,thereby bringing significant yet challenging issues to be tackled.This paper provides the first attempt to investigate the stabilization problem for a class of constrained switched linear systems with multiple faults under mode-dependent dwell time(MDT).From a set-theory perspective,we demonstrate a critical necessary and sufficient stability condition for switched systems without uncertainties.Moreover,the non-conservative stability criterion is further extended to the perturbed switched systems with rigorous proof.A switching communication network example verifies the validity of the theoretical result and demonstrates their advantages.
基金supported by the National Natural Science Foundation of China(No.62476236)Yangzhou University Top-Level Talents Support Program(2021)+2 种基金Qinglan Project of Yangzhou University(2021)Postgraduate Research and Practice Innovation Program of Jiangsu Province(Nos.KYCX24_3748 and KYCX24_3749)the"Savas Parastatidis"Named Scholarship by the Bodossaki Foundation.
摘要Recurrent neural networks(RNNs)have been employed extensively as intelligent control approaches across various industrial control fields.However,existing research often lacks sufficient focus on discrete-form time-variant problems and disturbance rejection capability.This paper proposes a novel discrete-form integral-reinforcing RNN(DF-IR-RNN)approach.This approach integrates an innovative integral-reinforcing RNN(IR-RNN)design thought into the RNN approach to enhance the disturbance rejection capability in controlling the Stewart platform under discrete-form time-variant environment.Compared to traditional approaches,the proposed approach overcomes their limitations of disturbance rejection.The experimental results demonstrate that the proposed approach is highly effective in disturbance rejection and accurate trajectory tracking.