The aim of the present paper is to study 2-complex symmetric bounded weighted composition operators on the Fock space of CN with the conjugations J and Jt,A,b defined by ■ respectively,where k(z1,...,z_N)=(...The aim of the present paper is to study 2-complex symmetric bounded weighted composition operators on the Fock space of CN with the conjugations J and Jt,A,b defined by ■ respectively,where k(z1,...,z_N)=(■,...,■),t∈C,b∈CN and A is a linear operator on CN.An example of 2-complex symmetric bounded weighted composition operator with the conjugation Jt,A,b is given.展开更多
While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor ...While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor often overlooked.Disordered interfaces exhibit thermodynamic metastability,where ion diffusion induces sequential phase transitions from low-n to high-n phases.Here,we construct atomically ordered 2D/3D interfaces using phase-pure 2D perovskite capping layers,which reduce the interfacial phase transition rate by 95%and effectively suppress ion migration.As a result,devices exhibit outstanding operational stability,retaining over 99%of their initial power conversion efficiency after 1500 h of continuous operation,along with excellent thermal durability at 85℃.These findings identify interfacial order as a critical parameter for regulating ion dynamics and phase behavior,providing a robust design principle for achieving high-efficiency,long-lifetime perovskite technologies.展开更多
By using the two-mode Fresnel operator we derive a multiplication rule of two-dimensional (2D) Collins diffraction formula, the inverse of 2D Collins diffraction integration can also be conveniently derived in this ...By using the two-mode Fresnel operator we derive a multiplication rule of two-dimensional (2D) Collins diffraction formula, the inverse of 2D Collins diffraction integration can also be conveniently derived in this way in the context of quantum optics theory.展开更多
In this paper,we are concerned with the existence of the positive bounded and blow-up radial solutions of the(k1,k2)-Hessian system■where G is a nonlinear operator,Ki=Ski(λ(D2 zi))+ψi(|x|)|▽zi|ki,i=...In this paper,we are concerned with the existence of the positive bounded and blow-up radial solutions of the(k1,k2)-Hessian system■where G is a nonlinear operator,Ki=Ski(λ(D2 zi))+ψi(|x|)|▽zi|ki,i=1,2.Under the appropriate conditions on gi and g2,our main results are obtained by using the monotone iterative method and the Arzela-Ascoli theorem.Furthermore,our main results also extend the previous existence results for both the single equation and systems.展开更多
Phase-pure two-dimensional(2D)interfacial passivation has emerged as an effective strategy for addressing the intrinsic instability and interfacial defects of three-dimensional(3D)perovskite absorbers.However,conventi...Phase-pure two-dimensional(2D)interfacial passivation has emerged as an effective strategy for addressing the intrinsic instability and interfacial defects of three-dimensional(3D)perovskite absorbers.However,conventionally formed 2D layers often suffer from mixed-n phases,heterogeneous quantum-well distributions,and disordered orientation,which impede charge transport,distort energy-level alignment,and accelerate structural degradation.In this review,we elucidate the thermodynamic and kinetic origins of mixed-phase formation and discuss how dimensional heterogeneity adversely impacts carrier dynamics and device stability.We then summarize recent advances in achieving phase-pure 2D perovskite interlayers that enable precise n-value control,favorable crystal orientation,and optimized interfacial energetics.These strategies yield highly ordered 2D/3D heterostructures that effectively suppress ion migration,mitigate non-radiative recombination,and significantly enhance longterm operational stability.Finally,we outline the remaining challenges and emerging opportunities for scalable,phase-pure engineering toward high-efficiency and stable perovskite photovoltaic technologies.Overall,this review provides a unified framework linking phase purity,interfacial ordering,and device stability,offering guidance for the development of next-generation robust perovskite photovoltaics.展开更多
In this paper by Sobolev imbedding theorem and characterization theorem of generalized operators the existence of P(φ)2 quantum fields as generalized operators is obtained and a rigorous mathematical interpretation o...In this paper by Sobolev imbedding theorem and characterization theorem of generalized operators the existence of P(φ)2 quantum fields as generalized operators is obtained and a rigorous mathematical interpretation of renormalization procedure is given under white noise theory.展开更多
The electrochemical CO2 reduction(CO2R)holds the potential to manufacture carbon-based chemicals and fuels while advancing toward carbon neutrality.On the path to achieving practical CO2R,a significant challe...The electrochemical CO2 reduction(CO2R)holds the potential to manufacture carbon-based chemicals and fuels while advancing toward carbon neutrality.On the path to achieving practical CO2R,a significant challenge lies in the formation of carbonate salts due to the interplay between CO2,local alkalinity and metal cations.The carbonate issue leads to the wastage of CO2 reactant,thus resulting in low carbon utilization efficiency and high costs for carbonate regeneration.Additionally,such salt formation can threaten the operation stability of the CO2R in electrolyzers equipped with gas diffusion electrodes(GDE).These challenges motivate us to conduct the present review,aiming to provide a comprehensive understanding and propose solution strategies for the carbonate problem.We start from the mechanism insights into carbonate formation with specific analysis on the kinetics of carbonate formation,mass transfer process,and the influence of interfacial p H,followed by the exposition of advanced techniques to monitor the carbonate accumulation.Next,the design strategies to solve the carbonate problem including the optimization of electrolyte,electrode,membranes and operation conditions,are presented,with a highlight on acidic CO2 electrolysis system without introducing metal cations into electrolyte systems.We finally end up by offering future opportunities in this evolving field.These timely and inspiring perspectives can guide researchers in addressing carbonate-related issues and advance CO2R toward practical feasibility.展开更多
In this paper, we introduce the reduced matrix in kq representation and provide the reduced matrix elements of a projection operator P on the rational noncommutative orbifold T^2/Z_4.we give the closed form for the pr...In this paper, we introduce the reduced matrix in kq representation and provide the reduced matrix elements of a projection operator P on the rational noncommutative orbifold T^2/Z_4.we give the closed form for the projector by Jacobi elliptical functions. Since projectors correspond to soliton solutions of the field theory on the noncommutative orbifold, we thus present a corresponding soliton solution.展开更多
【目的】为解决碳捕集、利用与封存(Carbon Capture,Utilization and Storage,CCUS)工程中短距离CO2输送问题,利用管道管输气态CO2是一种经济的解决方案。但CO2管道在严重的内腐蚀与外部应力环境中易发生应力腐蚀开裂(Stress C...【目的】为解决碳捕集、利用与封存(Carbon Capture,Utilization and Storage,CCUS)工程中短距离CO2输送问题,利用管道管输气态CO2是一种经济的解决方案。但CO2管道在严重的内腐蚀与外部应力环境中易发生应力腐蚀开裂(Stress Corrosion Cracking,SCC),使得气态CO2输送管道的服役可靠性问题日益受到关注。【方法】对不同相态CO2管道SCC的研究现状进行全面梳理,并聚焦气态CO2输送的特殊环境,探讨了其腐蚀行为、裂纹萌生及扩展机理;在此基础上,重点阐述了气态CO2环境中阳极溶解-薄膜破裂机制与氢致开裂的协同作用过程,进而系统分析了材料、环境以及应力状态对管线钢SCC敏感性的多因素耦合影响机制,并总结了现有研究的不足之处。【结果】气态CO2压力较低,水相以微滴形式局部凝结于管壁,形成不连续、多孔的FeCO3腐蚀产物膜,难以提供有效保护;在微观组织中,细针状铁素体因高位错密度有利于钝化膜形核;非金属夹杂物通过引入界面应力集中、充当氢陷阱及引发微电偶腐蚀,显著促进裂纹形核;气态CO2中的杂质气体通过改变水相析出行为、参与阴极反应、破坏产物膜稳定性等方式,显著提高SCC敏感性;水分是诱导管道局部腐蚀与内壁顶部腐蚀的关键因素,其冷凝行为受温度与压力影响。【结论】当前对气态CO2管道的SCC机理研究仍较少,要实现CO2输送管道的安全平稳运行,今后的研究中应重点关注的问题包括:明确流速、剪切力及相变对气态CO2环境中局部腐蚀坑形成与扩展的影响;含微量水的气态CO2环境耦合外加应力原位腐蚀电化学数据的监测与分析;加快建立在役油气管道改输气态CO2的管道SCC评价体系。(图2,参96)展开更多
Based on the residual implication of continuous triangular norms,we obtain the expression of residual operator for extended operators(type-2 triangular norms)of continuous triangular norms on convex normal upper semi-...Based on the residual implication of continuous triangular norms,we obtain the expression of residual operator for extended operators(type-2 triangular norms)of continuous triangular norms on convex normal upper semi-continuous fuzzy truth values,answering an open problem in[D.LI,Inf.Sci.,2015,317:259-277].展开更多
We consider the quantum mechanical SU(2) transformation e^2λJzJ±e^-2λJz = e^±2λJ±as if the meaning of squeezing with e^±2λ being squeezing parameter. By studying SU(2) operators (J±,...We consider the quantum mechanical SU(2) transformation e^2λJzJ±e^-2λJz = e^±2λJ±as if the meaning of squeezing with e^±2λ being squeezing parameter. By studying SU(2) operators (J±, Jz) from the point of view of squeezing we find that (J±,Jz) can also be realized in terms of 3-mode bosonic operators. Employing this realization, we find the natural representation (the eigenvectors of J+ or J-) of the 3-mode squeezing operator e^2λJz. The idea of considering quantum SU(2) transformation as if squeezing is liable for us to obtain the new bosonic operator realization of SU(2) and new squeezing operators.展开更多
Capacitor-less 2T0C dynamic random-access memory(DRAM)employing oxide semiconductors(OSs)as a channel has great potential in the development of highly scaled three dimensional(3D)-structured devices.However,the use of...Capacitor-less 2T0C dynamic random-access memory(DRAM)employing oxide semiconductors(OSs)as a channel has great potential in the development of highly scaled three dimensional(3D)-structured devices.However,the use of OS and such device structures presents certain challenges,including the trade-off relationship between the field-effect mobility and stability of OSs.Conventional 4-line-based operation of the 2T0C enlarges the entire cell volume and complicates the peripheral circuit.Herein,we proposed an IGO(In-Ga-O)channel 2-line-based 2T0C cell design and operating sequences comparable to those of the conventional Si-channel 1 T1C DRAM.IGO was adopted to achieve high thermal stability above 800℃,and the process conditions were optimized to simultaneously obtain a high μFE of 90.7 cm2·V-1·s-1,positive Vth of 0.34 V,superior reliability,and uniformity.The proposed 2-line-based 2T0C DRAM cell successfully exhibited multi-bit operation,with the stored voltage varying from 0 V to 1 V at 0.1 V intervals.Furthermore,for stored voltage intervals of 0.1 V and 0.5 V,the refresh time was 10 s and 1000 s in multi-bit operation;these values were more than 150 and 15000 times longer than those of the conventional Si channel 1T1C DRAM,respectively.A monolithic stacked 2-line-based 2T0C DRAM was fabricated,and a multi-bit operation was confirmed.展开更多
The large charging overpotential and sluggish kinetics of Li-CO2 batteries originate from both the high energy barrier for decomposing insulating discharge products and the mismatch between constantcurrent charging...The large charging overpotential and sluggish kinetics of Li-CO2 batteries originate from both the high energy barrier for decomposing insulating discharge products and the mismatch between constantcurrent charging and dynamic reaction kinetics.While cathode catalyst design dominates research,charging protocol optimization remains a critically underexplored avenue.Herein,we demonstrate that a constant-voltage(CV)charging strategy,as opposed to the conventional constant-current(CC)mode,dramatically enhances the charging rate,energy efficiency,and cyclability.Using a Ru@rGO cathode,the 4.0 V CV-charging protocol CV charging is identified as optimal,enabling rapid charging(~13.6 min),high energy efficiency of 72%,and stable cycling over 200 cycles.In-situ differential electrochemical mass spectrometry reveals rapid and efficient CO2 evolution kinetics under the 4.0 V CVcharging mode.Combined with X-ray photoelectron spectroscopy and Raman mapping,it is shown that this protocol ensures near-complete decomposition of both Li2 CO3 and Li2C2O4,whereas CC-charging and suboptimal CV-charging protocols leave significant residues or induce severe parasitic reactions.This work establishes CV-charging as an effective strategy to overcome the kinetic limitations of Li-CO2 batteries for a specific configuration,and provides a framework for optimizing charging protocols across battery systems.展开更多
Ion migration and electrode corrosion limit the operational stability of perovskite solar cells(PSCs),hindering their commercialization.Herein,we demonstrate that Nb2O5films effectively address these challenges ...Ion migration and electrode corrosion limit the operational stability of perovskite solar cells(PSCs),hindering their commercialization.Herein,we demonstrate that Nb2O5films effectively address these challenges when incorporated as buffer layers between the electron transport layer(ETL)and the metal electrode.Electrochemical analysis combined with density functional theory(DFT)calculations reveals that Nb2O5exhibits exceptional corrosion resistance against iodide-induced degradation,effectively blocking bidirectional diffusion of iodide ions and metal atoms.Furthermore,the Nb2O5buffer layer optimizes energy band alignment and interfacial contact,strengthens the built-in electric field,and suppresses non-radiative recombination,enabling efficient electron extraction.As a result of these synergistic effects,the Nb2O5modified PSCs achieve a champion power conversion efficiency(PCE)of 25.85%,with an open-circuit voltage of 1.194 V and a fill factor of 85.35%,significantly outperforming the control device with a PCE of 23.97%.The Nb2O5modified devices demonstrate excellent operational stability.The device retains 94%of its initial PCE after 500 h of maximum power point(MPP)tracking under ambient conditions with 60-65%relative humidity.This cost-effective approach establishes oxide buffer layers as a practical strategy to advance the commercial viability of PSCs,and provides fundamental insights into interface corrosion mechanisms and engineering principles of ETL/electrode interfaces for long-term device stability.展开更多
The utilization of gradient operators is prevalent in image processing,as they effectively detect edges and provide directional information.However,these operators only differentiate the horizontal and vertical direct...The utilization of gradient operators is prevalent in image processing,as they effectively detect edges and provide directional information.However,these operators only differentiate the horizontal and vertical directions,ignoring details and causing loss of information in other directions.This paper introduces the shear gradient operator to overcome this limitation by capturing details accurately in multiple directions.It investigates the properties of the shear gradient operator and proposes the shear total variation(STV)norm for image deblurring.By combining non-convex regularization to avoid excessive penalty and retain image details,a novel deblurring model integrating the STV norm and the L1/L2 minimization is proposed.The alternating direction method of multipliers(ADMM)algorithm is employed to solve this computationally challenging model,demonstrating exceptional performance in non-blind image deblurring through experiments.展开更多
基金Supported by Sichuan Science and Technology Program (No.2022ZYD0010)。
摘要The aim of the present paper is to study 2-complex symmetric bounded weighted composition operators on the Fock space of CN with the conjugations J and Jt,A,b defined by ■ respectively,where k(z1,...,z_N)=(■,...,■),t∈C,b∈CN and A is a linear operator on CN.An example of 2-complex symmetric bounded weighted composition operator with the conjugation Jt,A,b is given.
基金funding supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB1140000)National Natural Science Foundation of China(22379156,U23A20141)+1 种基金Qingdao New Energy Shandong Laboratory(QIBEBT/SEI/QNESL S202305)Key R&D Program of Shandong Province,China(2024SFGC0102)。
摘要While 2D/3D heterostructures are widely employed to improve the stability of perovskite optoelectronic devices,their effectiveness is fundamentally governed by the crystallinity of the interfacial structure -a factor often overlooked.Disordered interfaces exhibit thermodynamic metastability,where ion diffusion induces sequential phase transitions from low-n to high-n phases.Here,we construct atomically ordered 2D/3D interfaces using phase-pure 2D perovskite capping layers,which reduce the interfacial phase transition rate by 95%and effectively suppress ion migration.As a result,devices exhibit outstanding operational stability,retaining over 99%of their initial power conversion efficiency after 1500 h of continuous operation,along with excellent thermal durability at 85℃.These findings identify interfacial order as a critical parameter for regulating ion dynamics and phase behavior,providing a robust design principle for achieving high-efficiency,long-lifetime perovskite technologies.
基金supported by the Doctoral Scientific Research Startup Fund of Anhui University, China (Grant No. 33190059)the National Natural Science Foundation of China (Grant No. 10874174)+1 种基金the Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20113401120004)the Open Funds from National Laboratory for Infrared Physics, Chinese Academy of Sciences (Grant No. 201117)
摘要By using the two-mode Fresnel operator we derive a multiplication rule of two-dimensional (2D) Collins diffraction formula, the inverse of 2D Collins diffraction integration can also be conveniently derived in this way in the context of quantum optics theory.
基金supported by NSFC(12001344)the Graduate Education and Teaching Innovation Project of Shanxi,China(2021YJJG142)+1 种基金the Natural Science Foundation of Chongqing(cstc2020jcyj-msxmX0123)the Technology Research Foundation of Chongqing Educational Committee(KJQN201900539 and KJQN202000528)。
摘要In this paper,we are concerned with the existence of the positive bounded and blow-up radial solutions of the(k1,k2)-Hessian system■where G is a nonlinear operator,Ki=Ski(λ(D2 zi))+ψi(|x|)|▽zi|ki,i=1,2.Under the appropriate conditions on gi and g2,our main results are obtained by using the monotone iterative method and the Arzela-Ascoli theorem.Furthermore,our main results also extend the previous existence results for both the single equation and systems.
基金National Key Research and Development Program of China,Grant/Award Number:2024YFB4205201National Natural Science Foundation of China+5 种基金Grant/Award Numbers:22422901,22379010,22309190,22025208Fundamental Research Funds for the Central UniversitiesGrant/Award Number:2025-JYB-JBGS-036Postdoctoral Fellowship Program(Grade C)of China Postdoctoral Science FoundationGrant/Award Number:GZC20250707Chinese Academy of Sciences。
摘要Phase-pure two-dimensional(2D)interfacial passivation has emerged as an effective strategy for addressing the intrinsic instability and interfacial defects of three-dimensional(3D)perovskite absorbers.However,conventionally formed 2D layers often suffer from mixed-n phases,heterogeneous quantum-well distributions,and disordered orientation,which impede charge transport,distort energy-level alignment,and accelerate structural degradation.In this review,we elucidate the thermodynamic and kinetic origins of mixed-phase formation and discuss how dimensional heterogeneity adversely impacts carrier dynamics and device stability.We then summarize recent advances in achieving phase-pure 2D perovskite interlayers that enable precise n-value control,favorable crystal orientation,and optimized interfacial energetics.These strategies yield highly ordered 2D/3D heterostructures that effectively suppress ion migration,mitigate non-radiative recombination,and significantly enhance longterm operational stability.Finally,we outline the remaining challenges and emerging opportunities for scalable,phase-pure engineering toward high-efficiency and stable perovskite photovoltaic technologies.Overall,this review provides a unified framework linking phase purity,interfacial ordering,and device stability,offering guidance for the development of next-generation robust perovskite photovoltaics.
基金Project supported by NSFC (10171035) and Hubei University Youth Foundation (97A012)
摘要In this paper by Sobolev imbedding theorem and characterization theorem of generalized operators the existence of P(φ)2 quantum fields as generalized operators is obtained and a rigorous mathematical interpretation of renormalization procedure is given under white noise theory.
基金supported by NSFC(Nos.22322902,U22A20396,and 22211540385)the National Key Research and Development Program of China(No.2021YFA1502000)+2 种基金the Science and Technology Innovation Program of Hunan Province(No.2021RC3065)Postgraduate Scientific Research Innovation Project of Hunan Province(No.CX20230455)the Shenzhen Science and Technology Program(Nos.JCYJ20210324120800002,JCYJ20220818100012025,and JCYJ20230807122007015)。
摘要The electrochemical CO2 reduction(CO2R)holds the potential to manufacture carbon-based chemicals and fuels while advancing toward carbon neutrality.On the path to achieving practical CO2R,a significant challenge lies in the formation of carbonate salts due to the interplay between CO2,local alkalinity and metal cations.The carbonate issue leads to the wastage of CO2 reactant,thus resulting in low carbon utilization efficiency and high costs for carbonate regeneration.Additionally,such salt formation can threaten the operation stability of the CO2R in electrolyzers equipped with gas diffusion electrodes(GDE).These challenges motivate us to conduct the present review,aiming to provide a comprehensive understanding and propose solution strategies for the carbonate problem.We start from the mechanism insights into carbonate formation with specific analysis on the kinetics of carbonate formation,mass transfer process,and the influence of interfacial p H,followed by the exposition of advanced techniques to monitor the carbonate accumulation.Next,the design strategies to solve the carbonate problem including the optimization of electrolyte,electrode,membranes and operation conditions,are presented,with a highlight on acidic CO2 electrolysis system without introducing metal cations into electrolyte systems.We finally end up by offering future opportunities in this evolving field.These timely and inspiring perspectives can guide researchers in addressing carbonate-related issues and advance CO2R toward practical feasibility.
基金Supported by the Natural Science Foundation of China under Grant Nos. 10575080, 11047025, 11075126 the Project of Knowledge Innovation Program (PKIP) of Chinese Academy of Sciences
摘要In this paper, we introduce the reduced matrix in kq representation and provide the reduced matrix elements of a projection operator P on the rational noncommutative orbifold T^2/Z_4.we give the closed form for the projector by Jacobi elliptical functions. Since projectors correspond to soliton solutions of the field theory on the noncommutative orbifold, we thus present a corresponding soliton solution.
基金Supported by the Natural Science Foundation of Sichuan Province(Grant No.2022NSFSC1821)the National Natural Science Foundation of China(Grant No.12261018)+2 种基金Universities Key Laboratory of Mathematical Modeling and Data Mining in Guizhou Province(Grant No.2023013)High Level Innovative Talent Training Plan Project of Guizhou Province(Grant No.GCC[2023]006)the Key Natural Science Foundation of Universities in Guangdong Province(Grant No.2019KZDXM027)。
摘要Based on the residual implication of continuous triangular norms,we obtain the expression of residual operator for extended operators(type-2 triangular norms)of continuous triangular norms on convex normal upper semi-continuous fuzzy truth values,answering an open problem in[D.LI,Inf.Sci.,2015,317:259-277].
基金supported by the National Natural Science Foundation of China(Grant Nos.11175113 and 11275123)the Key Project of Natural Science Fund of Anhui Province,China(Grant No.KJ2013A261)
摘要We consider the quantum mechanical SU(2) transformation e^2λJzJ±e^-2λJz = e^±2λJ±as if the meaning of squeezing with e^±2λ being squeezing parameter. By studying SU(2) operators (J±, Jz) from the point of view of squeezing we find that (J±,Jz) can also be realized in terms of 3-mode bosonic operators. Employing this realization, we find the natural representation (the eigenvectors of J+ or J-) of the 3-mode squeezing operator e^2λJz. The idea of considering quantum SU(2) transformation as if squeezing is liable for us to obtain the new bosonic operator realization of SU(2) and new squeezing operators.
基金supported by the Technology Innovation Program(Grant Nos.20017382 and 20023023)funded by the Ministry of Trade,Industry&Energy(MOTIE,Republic of Korea)supported by a National Research Foundation of Korea(NRF)grant funded by the Korean Government(MSIT)(Grant No.RS-2023-00260527).
摘要Capacitor-less 2T0C dynamic random-access memory(DRAM)employing oxide semiconductors(OSs)as a channel has great potential in the development of highly scaled three dimensional(3D)-structured devices.However,the use of OS and such device structures presents certain challenges,including the trade-off relationship between the field-effect mobility and stability of OSs.Conventional 4-line-based operation of the 2T0C enlarges the entire cell volume and complicates the peripheral circuit.Herein,we proposed an IGO(In-Ga-O)channel 2-line-based 2T0C cell design and operating sequences comparable to those of the conventional Si-channel 1 T1C DRAM.IGO was adopted to achieve high thermal stability above 800℃,and the process conditions were optimized to simultaneously obtain a high μFE of 90.7 cm2·V-1·s-1,positive Vth of 0.34 V,superior reliability,and uniformity.The proposed 2-line-based 2T0C DRAM cell successfully exhibited multi-bit operation,with the stored voltage varying from 0 V to 1 V at 0.1 V intervals.Furthermore,for stored voltage intervals of 0.1 V and 0.5 V,the refresh time was 10 s and 1000 s in multi-bit operation;these values were more than 150 and 15000 times longer than those of the conventional Si channel 1T1C DRAM,respectively.A monolithic stacked 2-line-based 2T0C DRAM was fabricated,and a multi-bit operation was confirmed.
基金financially supported by the Natural Science Foundation of Shandong Province(ZR2025MS807,ZR2020QE012)the National Natural Science Foundation of China(52201254,52422213,52272212)+4 种基金the Jining City Key Research and Development Program(2025KJHZ018)the Taishan Scholar Project of Shan-dong Province(tspd20240813)the Introducing Major Universities and Research Institutions to Jointly Build Innovative Carrier Project of Jining City(2023DYDS022)the Scientific Research Foundation for New Talents in University of Jinan(XRC2406)the support provided by the Shandong Province Laboratory of Technology and Equipment for Molecular Diagnosis。
摘要The large charging overpotential and sluggish kinetics of Li-CO2 batteries originate from both the high energy barrier for decomposing insulating discharge products and the mismatch between constantcurrent charging and dynamic reaction kinetics.While cathode catalyst design dominates research,charging protocol optimization remains a critically underexplored avenue.Herein,we demonstrate that a constant-voltage(CV)charging strategy,as opposed to the conventional constant-current(CC)mode,dramatically enhances the charging rate,energy efficiency,and cyclability.Using a Ru@rGO cathode,the 4.0 V CV-charging protocol CV charging is identified as optimal,enabling rapid charging(~13.6 min),high energy efficiency of 72%,and stable cycling over 200 cycles.In-situ differential electrochemical mass spectrometry reveals rapid and efficient CO2 evolution kinetics under the 4.0 V CVcharging mode.Combined with X-ray photoelectron spectroscopy and Raman mapping,it is shown that this protocol ensures near-complete decomposition of both Li2 CO3 and Li2C2O4,whereas CC-charging and suboptimal CV-charging protocols leave significant residues or induce severe parasitic reactions.This work establishes CV-charging as an effective strategy to overcome the kinetic limitations of Li-CO2 batteries for a specific configuration,and provides a framework for optimizing charging protocols across battery systems.
基金supported by the National Natural Science Foundation of China(52172238,52102304)Guangdong Basic and Applied Basic Research Foundation(2025A1515011362)+1 种基金Open Project of Shaanxi Laboratory of Aerospace Power(2021SXSYS-01-03)“Special Lubrication and Sealing for Aerospace”Shaanxi Provincial Science and Technology Innovation Team(2024RS-CXTD-63)。
摘要Ion migration and electrode corrosion limit the operational stability of perovskite solar cells(PSCs),hindering their commercialization.Herein,we demonstrate that Nb2O5films effectively address these challenges when incorporated as buffer layers between the electron transport layer(ETL)and the metal electrode.Electrochemical analysis combined with density functional theory(DFT)calculations reveals that Nb2O5exhibits exceptional corrosion resistance against iodide-induced degradation,effectively blocking bidirectional diffusion of iodide ions and metal atoms.Furthermore,the Nb2O5buffer layer optimizes energy band alignment and interfacial contact,strengthens the built-in electric field,and suppresses non-radiative recombination,enabling efficient electron extraction.As a result of these synergistic effects,the Nb2O5modified PSCs achieve a champion power conversion efficiency(PCE)of 25.85%,with an open-circuit voltage of 1.194 V and a fill factor of 85.35%,significantly outperforming the control device with a PCE of 23.97%.The Nb2O5modified devices demonstrate excellent operational stability.The device retains 94%of its initial PCE after 500 h of maximum power point(MPP)tracking under ambient conditions with 60-65%relative humidity.This cost-effective approach establishes oxide buffer layers as a practical strategy to advance the commercial viability of PSCs,and provides fundamental insights into interface corrosion mechanisms and engineering principles of ETL/electrode interfaces for long-term device stability.
基金Supported by the National Natural Science Foundation of China(61701004)。
摘要The utilization of gradient operators is prevalent in image processing,as they effectively detect edges and provide directional information.However,these operators only differentiate the horizontal and vertical directions,ignoring details and causing loss of information in other directions.This paper introduces the shear gradient operator to overcome this limitation by capturing details accurately in multiple directions.It investigates the properties of the shear gradient operator and proposes the shear total variation(STV)norm for image deblurring.By combining non-convex regularization to avoid excessive penalty and retain image details,a novel deblurring model integrating the STV norm and the L1/L2 minimization is proposed.The alternating direction method of multipliers(ADMM)algorithm is employed to solve this computationally challenging model,demonstrating exceptional performance in non-blind image deblurring through experiments.