The mechanism of decomposition of calcium inosilicate(CaSiO_3) synthesized through chemical deposition method using analytical reagent NaSiO_3·9H_2O and CaCl_2 during the alkali fusion process using NaOH was inve...The mechanism of decomposition of calcium inosilicate(CaSiO_3) synthesized through chemical deposition method using analytical reagent NaSiO_3·9H_2O and CaCl_2 during the alkali fusion process using NaOH was investigated by Raman spectroscopy in situ,X-ray diffraction and Fourier transform infrared spectrometer(FTIR).The results show that the tetrahedral silica chains within CaSiO_3 are gradually disrupted and transformed into nesosilicate with the isolated SiO_4 tetrahedra at the beginning of the alkali fusion process.The three intermediates including Ca_2SiO_4,Na_2CaSiO_4 and Na_2SiO_3 appear simultaneously in the decomposition of CaSiO_3,while the final products are Ca(OH)_2 and Na_4SiO_4.It can be concluded that there exist two reaction pathways in the alkali fusion process of CaSiO_3:one is ion exchange,the other is in the main form of the framework structure change of silicate.The reaction pathway is led by silicate structure transformation in the alkali fusion process.展开更多
Magnetized target fusion is an alternative method to fulfill the goal of controlled fusion, which combines advan- tages of both magnetic confinement fusion and inertial confinement fusion since its parameter space lie...Magnetized target fusion is an alternative method to fulfill the goal of controlled fusion, which combines advan- tages of both magnetic confinement fusion and inertial confinement fusion since its parameter space lies between the two traditional ways. Field reversed configuration (FFtC) is a good candidate of magnetized targets due to its translatable, compressible, high /3 and high energy density properties. Dynamic formation process of high density FFtC is observed on the YingGuang 1 device for the first time in China. The evolution of a magnetic field is detected with magnetic probes, and the compression process can be clearly seen from images taken with a high-speed multi-frame CCD camera. The process is also studied with two-dimensional magneto hydrodynamic code MPF-2D theoretically, and the results agree well with the experiment. Combining the experimental data and the theoretical analysis, the length of the formed FRC is about 39 cm, the diameter is about 2-2. 7cm, the average density is 1.3× 1016 cm-3, and the average temperature is 137eV.展开更多
采用激光粉末床熔融(laser powder bed fusion,LPBF)技术制备K418B高温合金,利用光学显微镜、扫描电镜和硬度仪分析工艺参数激光功率(140~220 W)和扫描速度(600~1400 mm/s)对显微缺陷、致密度、微观组织及硬度的影响。结果表明,激光功...采用激光粉末床熔融(laser powder bed fusion,LPBF)技术制备K418B高温合金,利用光学显微镜、扫描电镜和硬度仪分析工艺参数激光功率(140~220 W)和扫描速度(600~1400 mm/s)对显微缺陷、致密度、微观组织及硬度的影响。结果表明,激光功率和扫描速度均显著影响样品的相对密度与缺陷分布。低能量密度易产生不规则孔洞,高能量密度则易形成球形气孔与凝固裂纹;体积能量密度(volume energy density,VED)过低或过高都会降低致密度和性能。最佳工艺参数为激光功率180 W、扫描速度1400 mm/s,在该条件下样品致密度可达99.95%以上,表面缺陷少,仅有少量凝固裂纹,显微组织呈明显熔池边界和胞状结构,维氏硬度达366.8HV0.2。微观组织观察显示,熔池边界处晶粒较粗大,内部可见细胞状柱状晶,局部连续跨越多个熔池,表现出快速凝固特征。硬度随VED先升后降,与孔隙含量及致密度变化一致。研究揭示热应力是裂纹产生的主要原因,为K418B合金LPBF成形的参数优化提供依据,对提升航空发动机关键部件制造质量具有工程应用价值。展开更多
基金Project(20112120120003)supported by the Science and Technology Projects of Ministry of Education of ChinaProject(L2014120)supported by the Educational Commission of Liaoning Province,China
摘要The mechanism of decomposition of calcium inosilicate(CaSiO_3) synthesized through chemical deposition method using analytical reagent NaSiO_3·9H_2O and CaCl_2 during the alkali fusion process using NaOH was investigated by Raman spectroscopy in situ,X-ray diffraction and Fourier transform infrared spectrometer(FTIR).The results show that the tetrahedral silica chains within CaSiO_3 are gradually disrupted and transformed into nesosilicate with the isolated SiO_4 tetrahedra at the beginning of the alkali fusion process.The three intermediates including Ca_2SiO_4,Na_2CaSiO_4 and Na_2SiO_3 appear simultaneously in the decomposition of CaSiO_3,while the final products are Ca(OH)_2 and Na_4SiO_4.It can be concluded that there exist two reaction pathways in the alkali fusion process of CaSiO_3:one is ion exchange,the other is in the main form of the framework structure change of silicate.The reaction pathway is led by silicate structure transformation in the alkali fusion process.
基金Supported by the Development Foundation of China Academy of Engineering Physics under Grant No 2011B0402009the National Natural Science Foundation of China under Grant Nos 11375163,11575029 and 11175028
摘要Magnetized target fusion is an alternative method to fulfill the goal of controlled fusion, which combines advan- tages of both magnetic confinement fusion and inertial confinement fusion since its parameter space lies between the two traditional ways. Field reversed configuration (FFtC) is a good candidate of magnetized targets due to its translatable, compressible, high /3 and high energy density properties. Dynamic formation process of high density FFtC is observed on the YingGuang 1 device for the first time in China. The evolution of a magnetic field is detected with magnetic probes, and the compression process can be clearly seen from images taken with a high-speed multi-frame CCD camera. The process is also studied with two-dimensional magneto hydrodynamic code MPF-2D theoretically, and the results agree well with the experiment. Combining the experimental data and the theoretical analysis, the length of the formed FRC is about 39 cm, the diameter is about 2-2. 7cm, the average density is 1.3× 1016 cm-3, and the average temperature is 137eV.
摘要采用激光粉末床熔融(laser powder bed fusion,LPBF)技术制备K418B高温合金,利用光学显微镜、扫描电镜和硬度仪分析工艺参数激光功率(140~220 W)和扫描速度(600~1400 mm/s)对显微缺陷、致密度、微观组织及硬度的影响。结果表明,激光功率和扫描速度均显著影响样品的相对密度与缺陷分布。低能量密度易产生不规则孔洞,高能量密度则易形成球形气孔与凝固裂纹;体积能量密度(volume energy density,VED)过低或过高都会降低致密度和性能。最佳工艺参数为激光功率180 W、扫描速度1400 mm/s,在该条件下样品致密度可达99.95%以上,表面缺陷少,仅有少量凝固裂纹,显微组织呈明显熔池边界和胞状结构,维氏硬度达366.8HV0.2。微观组织观察显示,熔池边界处晶粒较粗大,内部可见细胞状柱状晶,局部连续跨越多个熔池,表现出快速凝固特征。硬度随VED先升后降,与孔隙含量及致密度变化一致。研究揭示热应力是裂纹产生的主要原因,为K418B合金LPBF成形的参数优化提供依据,对提升航空发动机关键部件制造质量具有工程应用价值。