Background: Lysine is used widely in livestock production due to the shortage of feed protein resources.Llysine·H2SO4 contains L-lysine sulphate as well as fermentation co-products which contain other amino acids...Background: Lysine is used widely in livestock production due to the shortage of feed protein resources.Llysine·H2SO4 contains L-lysine sulphate as well as fermentation co-products which contain other amino acids and phosphorus.However,there are few articles about L-lysine·H2SO4 product regarding intestinal morphology and liver pathology of broiler chickens.In this article,we focus on the absorption and metabolism of L-lysine·H2SO4 revealed in the variation of intestinal morphology and liver pathology to determine the tolerance of chicks for L-lysine·H2SO4.Methods: To evaluate the tolerance of broilers for L-lysine·H2SO4,240 one day old broilers were allocated randomly to one of five dietary treatments which included corn-soybean diets containing 0,1%,4%,7% or 10% L-lysine·H2SO4(L-lysine content = 55%).Results: Supplementation of 1% L-lysine·H2SO4 in the diet had no negative effects.However,4%,7% or 10% Llysine·H2SO4 supplementation produced negative responses on broiler performance,carcass characteristics,blood biochemistry,and particularly on intestinal morphology and liver pathology compared with broilers fed the control diet.Conclusion: Our results show that supplementation with 1% L-lysine·H2SO4 had no negative effects on performance,carcass characteristics,blood biochemistry,intestinal morphology and liver pathology in broilers,but supplementation with 4%,7% or 10% L-lysine·H2SO4 produced a negative response,particularly with respect to intestinal morphology and liver pathology.展开更多
The blast furnace slag bearing Ti02 in Panzhihua, China, is an important resource to be utilized. In the present paper, the effects of the ratio of slag to H2S04, the reaction temperature, the particle size of the sla...The blast furnace slag bearing Ti02 in Panzhihua, China, is an important resource to be utilized. In the present paper, the effects of the ratio of slag to H2S04, the reaction temperature, the particle size of the slag, and the concentration of H2S04 on the reaction rate and the acidolysis ratio of Ti were studied. The results indicated that the maximum acidolysis ratio reached 98%, which can serve as an experimental basis for the production of titania from the slag.展开更多
The configurations of molecular clusters have significant impacts on their growth into fine particles in atmosphere.In this paper,we explore the topology space of the structure of H2SO4·NH3 dimer with a novel sam...The configurations of molecular clusters have significant impacts on their growth into fine particles in atmosphere.In this paper,we explore the topology space of the structure of H2SO4·NH3 dimer with a novel sampling technique of meta-dynamics(MTD)method and ab initio molecular dynamics simulations.The simulations are carried out at the temperatures of both 50 K and 242 K,which represent the typical high and low latitudes of troposphere.The results show that,compared with only traditional MD simulations,the structure samplings are significantly accelerated with MTD method.Therefore,more isomers of the dimer are discovered within the same simulation time scale.In addition,the results show that MTD is more efficient for circumstances with high temperature.展开更多
F-PbO2 electrode and polytetrafluoroethylene (PTFE) doped F-PbO2 electrode (PTFE-F-PbO2) were prepared on a plexiglas sheet substrate by a series of procedure including chemical and electrochemical depositions. Th...F-PbO2 electrode and polytetrafluoroethylene (PTFE) doped F-PbO2 electrode (PTFE-F-PbO2) were prepared on a plexiglas sheet substrate by a series of procedure including chemical and electrochemical depositions. The electrochemical activities of these two electrodes for oxygen evolution (OE) reaction were examined by electrochemical tests. In comparison with F-PbO2, PTFE-F-PbO2 electrode exhibited larger active surface area and higher oxygen vacancy deficiency, which resulted in its higher electrocatalytic activity for OE. In addition, both exchange current density and activation energy of the electrodes for OE were calculated in terms of active surface area. The values of exchange current density and activation energy in 0.5 mol·L^-1 H2SO4 aqueous solution were 1.125×10^ -3 mA·cm^-2 and 18.62 kJ·mol^-1 for PTFE-F-PbO2, and 8.384×10^-4 mA·cm^- 2 and 28.98 kJ·mol^-1 for F-PbO2, respectively. Because these values are calculated on the basis of the active surface areas of the electrodes, the enhanced activity of PTFE-F-PbO2 can be attributed to an increase in oxygen vacancy deficiency of PbO2 due to doping by PTFE. The influence of PTFE adulteration on the activity of PbO2 film electrode for OE was investigated in detail in this study.展开更多
Acid doped Polyaniline(PANI)due to their increased electrical conductivity,are considered to be the most promising conducting filler materials.Hence,the present study,reports the synthesis of the PANI followed by acid...Acid doped Polyaniline(PANI)due to their increased electrical conductivity,are considered to be the most promising conducting filler materials.Hence,the present study,reports the synthesis of the PANI followed by acid doping,electrical conductivity and dielectric properties measurements of H2SO4;HCl and(Conc.HCl+NaNO2mixture)doped PANI.In order to know the effect of acetone washing on the electrical properties of acid doped PANI samples,the electrical properties of the non-acetone washed acid doped PANI samples are compared with that of their acetone washed counterparts.The PANI salt was prepared by conventional route using aniline hydrochloride and ammonium persulphate as an oxidant.PANI salt was subjected to 0.5M NaOH to form PANI base,which was further doped separately with H2SO4;HCl and(Conc.HCl+NaNO2mixture)respectively followed by acetone washing.A comparative electrical conductivity study between the acetone washed and unwashed PANI salt and H2SO4,HCl and Conc.HCl+NaNO2 mixture doped PANI were characterized by dielectric and impedance study.展开更多
基金The present study was supported by the 111 Project(B16044)of China
摘要Background: Lysine is used widely in livestock production due to the shortage of feed protein resources.Llysine·H2SO4 contains L-lysine sulphate as well as fermentation co-products which contain other amino acids and phosphorus.However,there are few articles about L-lysine·H2SO4 product regarding intestinal morphology and liver pathology of broiler chickens.In this article,we focus on the absorption and metabolism of L-lysine·H2SO4 revealed in the variation of intestinal morphology and liver pathology to determine the tolerance of chicks for L-lysine·H2SO4.Methods: To evaluate the tolerance of broilers for L-lysine·H2SO4,240 one day old broilers were allocated randomly to one of five dietary treatments which included corn-soybean diets containing 0,1%,4%,7% or 10% L-lysine·H2SO4(L-lysine content = 55%).Results: Supplementation of 1% L-lysine·H2SO4 in the diet had no negative effects.However,4%,7% or 10% Llysine·H2SO4 supplementation produced negative responses on broiler performance,carcass characteristics,blood biochemistry,and particularly on intestinal morphology and liver pathology compared with broilers fed the control diet.Conclusion: Our results show that supplementation with 1% L-lysine·H2SO4 had no negative effects on performance,carcass characteristics,blood biochemistry,intestinal morphology and liver pathology in broilers,but supplementation with 4%,7% or 10% L-lysine·H2SO4 produced a negative response,particularly with respect to intestinal morphology and liver pathology.
摘要The blast furnace slag bearing Ti02 in Panzhihua, China, is an important resource to be utilized. In the present paper, the effects of the ratio of slag to H2S04, the reaction temperature, the particle size of the slag, and the concentration of H2S04 on the reaction rate and the acidolysis ratio of Ti were studied. The results indicated that the maximum acidolysis ratio reached 98%, which can serve as an experimental basis for the production of titania from the slag.
摘要The configurations of molecular clusters have significant impacts on their growth into fine particles in atmosphere.In this paper,we explore the topology space of the structure of H2SO4·NH3 dimer with a novel sampling technique of meta-dynamics(MTD)method and ab initio molecular dynamics simulations.The simulations are carried out at the temperatures of both 50 K and 242 K,which represent the typical high and low latitudes of troposphere.The results show that,compared with only traditional MD simulations,the structure samplings are significantly accelerated with MTD method.Therefore,more isomers of the dimer are discovered within the same simulation time scale.In addition,the results show that MTD is more efficient for circumstances with high temperature.
基金Supported by the National Natural Science Foundation of China (20406019).
摘要F-PbO2 electrode and polytetrafluoroethylene (PTFE) doped F-PbO2 electrode (PTFE-F-PbO2) were prepared on a plexiglas sheet substrate by a series of procedure including chemical and electrochemical depositions. The electrochemical activities of these two electrodes for oxygen evolution (OE) reaction were examined by electrochemical tests. In comparison with F-PbO2, PTFE-F-PbO2 electrode exhibited larger active surface area and higher oxygen vacancy deficiency, which resulted in its higher electrocatalytic activity for OE. In addition, both exchange current density and activation energy of the electrodes for OE were calculated in terms of active surface area. The values of exchange current density and activation energy in 0.5 mol·L^-1 H2SO4 aqueous solution were 1.125×10^ -3 mA·cm^-2 and 18.62 kJ·mol^-1 for PTFE-F-PbO2, and 8.384×10^-4 mA·cm^- 2 and 28.98 kJ·mol^-1 for F-PbO2, respectively. Because these values are calculated on the basis of the active surface areas of the electrodes, the enhanced activity of PTFE-F-PbO2 can be attributed to an increase in oxygen vacancy deficiency of PbO2 due to doping by PTFE. The influence of PTFE adulteration on the activity of PbO2 film electrode for OE was investigated in detail in this study.
摘要Acid doped Polyaniline(PANI)due to their increased electrical conductivity,are considered to be the most promising conducting filler materials.Hence,the present study,reports the synthesis of the PANI followed by acid doping,electrical conductivity and dielectric properties measurements of H2SO4;HCl and(Conc.HCl+NaNO2mixture)doped PANI.In order to know the effect of acetone washing on the electrical properties of acid doped PANI samples,the electrical properties of the non-acetone washed acid doped PANI samples are compared with that of their acetone washed counterparts.The PANI salt was prepared by conventional route using aniline hydrochloride and ammonium persulphate as an oxidant.PANI salt was subjected to 0.5M NaOH to form PANI base,which was further doped separately with H2SO4;HCl and(Conc.HCl+NaNO2mixture)respectively followed by acetone washing.A comparative electrical conductivity study between the acetone washed and unwashed PANI salt and H2SO4,HCl and Conc.HCl+NaNO2 mixture doped PANI were characterized by dielectric and impedance study.