To explore mix proportion design of RAC with aggregates tightly packed,the dry and wet packing density of recycled coarse aggregates mixture system and recycled coarse and fine aggregates were tested,then the influenc...To explore mix proportion design of RAC with aggregates tightly packed,the dry and wet packing density of recycled coarse aggregates mixture system and recycled coarse and fine aggregates were tested,then the influence of replacement rate and particle size ratio on the packing density of particle system was explored,the packing density prediction model of recycled coarse aggregates based on particle morphology was constructed,and the mix proportion optimization for recycled aggregate concrete with dry-wet packing model was carried out.The experimental results show that,with the increasing of recycled aggregate replacement rate or fine-grained volume ratio,the dry packing density of recycled coarse aggregates decreases gradually.With the increasing of replacement rate,the particle gradation can be optimized by increasing coarsegrained volume ratio.There is a significant effect for particle morphology parameter K and the particle size ratio on the packing density of the binary mixed system,and the packing density prediction model of recycled coarse aggregates based on particle morphology was constructed.The maximum increase in compressive strength and tensile strength of RAC with mix proportion optimized by the dry-wet packing model are 12.94%and 11.09%,and the cementitious materials is reduced by 21.83%,then the superiority of the mix proportion optimization of RAC with the dry-wet close packing model is confirmed.The results of this paper can provide a theoretical basis for the mix proportion design of RAC.展开更多
To address the challenge of large-scale packing problems,this paper proposes a novel hierarchical algorithm based on the geometrical classification of parts.The algorithm begins by classifying parts into three levels ...To address the challenge of large-scale packing problems,this paper proposes a novel hierarchical algorithm based on the geometrical classification of parts.The algorithm begins by classifying parts into three levels based on their area and fullness and then applies distinct packing strategies to each category.An innovative“shape matching”method is introduced,which,together with the“box stacking”(for rectangular parts)and“gravity packing,”forms a comprehensive hierarchical packing system.Level-1 comprises large rectangular parts,which are arranged using the box stacking algorithm.By aligning the corner points of the parts’bounding boxes,this method avoids the hooking issue commonly encountered in gravity packing.Level-2 includes both large,irregular parts and medium-sized parts.They are first processed using the shape matching algorithm,where rotation and translation are applied to achieve contour complementarity.The quality of the match is evaluated using the shape matching coefficient(SMC).If the SMC fails to reach the preset quality threshold,the system switches to box stacking(for large,irregular parts)or gravity packing(for medium-sized parts).Level-3 comprises the remaining smaller parts and those that failed to pack in the previous two levels.For these parts,shape matching is attempted first,and the system resorts to gravity packing in case of failure.The experimental and comparative results demonstrate that the proposed hierarchical algorithm achieves higher material utilization than the traditional gravity packing algorithm.This improvement is facilitated by the box stacking and shape matching strategies,which promote a more orderly and compact arrangement of parts.展开更多
Operating Lithium-ion batteries at their temperature limits is a challenging design task due to explosion risk at high temperatures and rapid degradation at low temperatures.Depending on the battery package design,tho...Operating Lithium-ion batteries at their temperature limits is a challenging design task due to explosion risk at high temperatures and rapid degradation at low temperatures.Depending on the battery package design,those risks can be solved with passive solutions,which require no active cooling or heating.Thecurrentwork aims to optimize the pack design and materials of the type-NCR18650B battery based on a wide range of operation temperature.The lower limit was denoted by cold case while the maximum limit was expressed by hot case.A combined analyticalnumerical approach was developed to model the heat generation inside the battery.A thermal resistance analysis was used to determine the boundary conditions of the numerical model.The governing differential equations for the 1-D heat generation model were solved analytically.The numerical analysis was considered to determine the best battery pack design based on material parameters,number of batteries,and geometrical arrangement.The analytical results revealedthat the cold case canbe selectedas theworst case and thebestmodel wasobtainedusing thehexagonal-shaped 10-battery pack that was covered with Delrin of 1.8 mm in thickness.The numerical results showed that the best model was the hexagonal-shaped 10-battery pack with Delrin of 2 mm in thickness that achieved the largest temperature of−20.6℃ in the cold case.展开更多
The propylene/propane(C3H6/C3H8)separation is particularly challenging due to their highly similar physical properties,but of industrial importance.Herein,we report a bifunctional ultramicroporous metal-or...The propylene/propane(C3H6/C3H8)separation is particularly challenging due to their highly similar physical properties,but of industrial importance.Herein,we report a bifunctional ultramicroporous metal-organic framework(Co-aip-pyz)with customized pore environment and selective binding sites for the challenging C3H6/C3H8 separation.Co-aip-pyz exhibits a good C3H6 uptake with an ultrahigh C3H6 packing density(931 g/L),as well as possesses a remarkable C3H6/C3H8 uptake ratio with 911% and distinguished C3H6/C3H8 selectivity(>104)at 298 K and 1.0 bar.Furthermore,Co-aip-pyz possesses a record high C3H6 packing density with 859 g/L at 313 K and 1.0 bar,which is unprecedented in the C3H6/C3H8 separation.Its high performance for the C3H6/C3H8 separation has been further confirmed by breakthrough experiments and molecular simulations.Combined with good stability,facilely synthesized procedure by low-cost precursors,record-high C3H6 packing density,as well as good C3H6/C3H8 separation performance,it highlights Co-aip-pyz as a benchmark adsorbent to address daunting challenge for industrial C3H6/C3H8 separation.This work provides valuable insights into constructing top-performing MOF materials for addressing the industrial separation challenges.展开更多
Two-dimensional energetic materials(2DEMs),characterized by their exceptional interlayer sliding properties,are recognized as exemplar of low-sensitivity energetic materials.However,the diversity of available 2DEMs is...Two-dimensional energetic materials(2DEMs),characterized by their exceptional interlayer sliding properties,are recognized as exemplar of low-sensitivity energetic materials.However,the diversity of available 2DEMs is severely constrained by the absence of efficient methods for rapidly predicting crystal packing modes from molecular structures,impeding the high-throughput rational design of such materials.In this study,we employed quantified indicators,such as hydrogen bond dimension and maximum planar separation,to quickly screen 172DEM and 16 non-2DEM crystal structures from a crystal database.They were subsequently compared and analyzed,focusing on hydrogen bond donor-acceptor combinations,skeleton features,and intermolecular interactions.Our findings suggest that theπ-πpacking interaction energy is a key determinant in the formation of layered packing modes by planar energetic molecules,with its magnitude primarily influenced by the strongest dimericπ-πinteraction(π-π2max).Consequently,we have delineated a critical threshold forπ-π2max to discern layered packing modes and formulated a theoretical model for predictingπ-π2max,grounded in molecular electrostatic potential and dipole moment analysis.The predictive efficacy of this model was substantiated through external validation on a test set comprising 31 planar energetic molecular crystals,achieving an accuracy of 84%and a recall of 75%.Furthermore,the proposed model shows superior classification predictive performance compared to typical machine learning methods,such as random forest,on the external validation samples.This contribution introduces a novel methodology for the identification of crystal packing modes in 2DEMs,potentially accelerating the design and synthesis of high-energy,low-sensitivity 2DEMs.展开更多
To improve the compactness and properties of C/C-SiC-ZrC composites produced by precursor infiltration and pyrolysis(PIP)method,the low-temperature reactive melt infiltration(RMI)process was used to seal the composite...To improve the compactness and properties of C/C-SiC-ZrC composites produced by precursor infiltration and pyrolysis(PIP)method,the low-temperature reactive melt infiltration(RMI)process was used to seal the composites using Zr2Cu as the filler.The microstructure,mechanical properties,and ablation properties of the Zr2Cu packed composites were analyzed.Results show that during Zr2Cu impregnation,the melt efficiently fills the large pores of the composites and is converted to ZrCu due to a partial reaction of zirconium with carbon.This results in an increase in composite density from 1.91 g/cm3to 2.24 g/cm3and a reduction in open porosity by 27.35%.Additionally,the flexural strength of Zr2Cu packed C/C-SiC-ZrC composites is improved from 122.78±8.09 MPa to 135.53±5.40 MPa.After plasma ablation for 20 s,the modified composites demonstrate superior ablative resistance compared to PIP C/C-SiC-ZrC,with mass ablation and linear ablation rates of 2.77×10−3g/s and 2.60×10−3mm/s,respectively.The“selftranspiration”effect of the low-melting point copper-containing phase absorbs the heat of the plasma flame,further reducing the ablation temperature and promoting the formation of refined ZrO2particles within the SiO2melting layer.This provides more stable erosion protection for Zr2Cu packed C/C-SiC-ZrC composites.展开更多
AIM:To assess the variations in photoreceptor cell packing density(PCPD)across the retina among young healthy individuals with emmetropia,low and moderate myopia.METHODS:High-resolution adaptive optics scanning laser ...AIM:To assess the variations in photoreceptor cell packing density(PCPD)across the retina among young healthy individuals with emmetropia,low and moderate myopia.METHODS:High-resolution adaptive optics scanning laser ophthalmoscopy(AOSLO)systems were utilized for retinal imaging with a large sampling window of 700μm×700μm.The study cohort included 14 emmetropic[spherical equivalent(SE)ranged+0.5 to-0.5 D],15 low myopic(SE ranged-0.5 to-3 D)and 21 moderate myopic(SE ranged-3 to-6 D)healthy young adults.Photoreceptors at 3°temporal,6°superior and inferior 6°were captured.Statistical analysis was then performed to obtain PCPD and cell spacing.RESULTS:The average age of participants was 22.54±2.86(ranged 20–30y)with no difference among 3 groups.At 3°temporal,the emmetropic group exhibited the highest PCPD of 15186.16±2050.54 cells/mm2,while the low and moderate myopic groups had PCPD of 14009.15±1073.01 and 13466.92±1121.71 cells/mm2,respectively.At 3°temporal,the emmetropic group also had the smallest cell spacing at 6.66±0.26 mm,compared to 6.85±0.26 and 6.91±0.28 mm for the low and moderate myopic groups,respectively.Compared to the emmetropic group,at 3°temporal,the myopic groups showed significantly reduced PCPD(low myopia:P=0.032;moderate myopia:P=0.001).At 6°inferior,the moderate myopic group exhibited a significant decrease in PCPD(P=0.013),while at 6°superior,there were no significant statistical differences in PCPD for the low and moderate myopic groups(P>0.05).In comparison to the emmetropic group,only the moderate myopic group showed significantly increased cell spacing at all three positions(temporal 3°:P=0.011,superior 6°:P=0.046,inferior 6°:P=0.013).Correlation analysis revealed a positive correlation between PCPD and axial length changes(P<0.05).CONCLUSION:Reduced PCPD and increased cell spacing strongly correlated with refractive error in mild to moderate myopic eyes,especially at 6°inferior to the fovea and the decreased PCPD in the macular region of myopic patients may be associated with increased axial lengthinduced retinal stretching.展开更多
We study the character of Thurston’s circle packings with obtuse exterior intersection angles,and we get some simple criteria for the existence of hyperbolic circle packings.Moreover,the compactness theorem of combin...We study the character of Thurston’s circle packings with obtuse exterior intersection angles,and we get some simple criteria for the existence of hyperbolic circle packings.Moreover,the compactness theorem of combinatorial Ricci flows in hyperbolic background geometry with the weight function Ф∈[0,π)is obtained.As a consequence,We generalize G.Lin’s result[12]from acute exterior intersection angles case to obtuse exterior intersection angles case.展开更多
Random packings of spherical particles have attracted attention for many years.An algorithm based on compression is developed to generate random packings of spherical particles in this paper.This method is different f...Random packings of spherical particles have attracted attention for many years.An algorithm based on compression is developed to generate random packings of spherical particles in this paper.This method is different from previous compression-based algorithm.In order to increase the packing density,a process of shaking is applied during packing process.The algorithm is mainly composed of three procedures:generating initial packing configuration by using random sequential adsorption(RSA),compressing packing domain,and shaking.The packing structure is characterized by packing density and coordinate number.The packing density increases with iteration number and a stable packing configuration is obtained after the iteration number is more than 34 000.The packing density is 0.85 and the average coordinate number is 3.7 in a stable packing configuration.展开更多
Let X be a metric space and u a finite Borel measure on X. Let P^- u^q,t and P u^q,t be the packing premeasure and the packing measure on X, respectively, defined by the gauge (uB(x, r))^q(2r)^t, where q, t ∈ R...Let X be a metric space and u a finite Borel measure on X. Let P^- u^q,t and P u^q,t be the packing premeasure and the packing measure on X, respectively, defined by the gauge (uB(x, r))^q(2r)^t, where q, t ∈ R. For any compact set E of finite packing premeasure the authors prove: (1) if q ≤ 0 then P^- u^q,t(E) =P u^q,t (E); (2) if q 〉 0 and u is doubling on E then P^- u^q,t (E) and P u^q,t (E) are both zero or neither.展开更多
In order to produce the high quality optical aspheric lens,the shrinkage of lens should be strictly controlled during the injection process.Serials of experiments are done to find the factors that affect the lens shri...In order to produce the high quality optical aspheric lens,the shrinkage of lens should be strictly controlled during the injection process.Serials of experiments are done to find the factors that affect the lens shrinkage during the injection molding process.The study is focused on the effect of gate size,packing time and pressure on the shrinkage.The gate size decides the effective packing time.Only when the effective packing time is enough,the shrinkage size will be decreased along with the packing pressure increased.However the packing time is determined by the gate size.But big gate size is not easily to be cut and the cutting difficulty will cause the part quality problems.The experiments show that packing pressure not only determines the part shrinkage size and also affects the part shrinkage uniformity.When the packing pressure is more than a critical one,the effect of packing pressure on the shrinkage size becomes smaller.And the shrinkage uniformity is guaranteed.展开更多
Let Bn(X,Y)denote the complete bipartite graph of order n with vertex partition sets X and Y.We prove that for each tree T of order n,there is a packing of k copies of T into a complete bipartite graph Bn+m(X,Y)...Let Bn(X,Y)denote the complete bipartite graph of order n with vertex partition sets X and Y.We prove that for each tree T of order n,there is a packing of k copies of T into a complete bipartite graph Bn+m(X,Y).The ideal of the work comes from the"Tree packing conjecture"made by Gyráfás and Lehel.Bollobás confirmed the"Tree packing conjecture"for many small trees,who showed that one can pack T1,T2,…,Tn/√2into Knand that a better bound would follow from a famous conjecture of Erdo s.In a similar direction,Hobbs,Bour geois and Kasiraj made the following conjecture:Any sequence of trees T2,…,Tn,with Tihaving order i,can be packed into Kn-1,(n/2).Further Hobbs,Bourgeois and Kasiraj proved that any two trees can be packed into a complete bipartite graph Kn-1,(n/2).Motivated by these results,Wang Hong proposed the conjecture:For each tree T of order n,there is a k-packing of T in some complete bipartite graph Bn+k-1(X,Y).In this paper,we prove a weak version of this conjecture.展开更多
A packing of the complete directed symmetric graph DK v with m circuits, denoted by ( v,m) DCP, is defined to be a family of arc disjoint m circuits of DK v such that any one arc of DK v \ occurs in at most one m circ...A packing of the complete directed symmetric graph DK v with m circuits, denoted by ( v,m) DCP, is defined to be a family of arc disjoint m circuits of DK v such that any one arc of DK v \ occurs in at most one m circuit. The packing number P(v,m) is the maximum number of m circuits in such a packing. The packing problem is to determine the value P(v,m) for every integer v≥m. In this paper, the problem is reduced to the case m+6≤v≤2m- 4m-3+12 , for any fixed even integer m≥4 . In particular, the values of P(v,m) are completely determined for m=12 , 14 and 16.展开更多
The jet co-flow packing tray(JCPT) with three different types of perforation in equal opening fraction was tested in two rectangular columns with 0.12m in width and 0.27m in length operated with air-water system. The ...The jet co-flow packing tray(JCPT) with three different types of perforation in equal opening fraction was tested in two rectangular columns with 0.12m in width and 0.27m in length operated with air-water system. The influences of gas phase orifice F-factor and clear liquid height Hc on the amount of liquid lifted, Q, were examined. The corresponding correlation between Q with F-factor and equivalent diameter of perforated holes as well as Hc was obtained. Furthermore, the non-steady state mass transfer performance of JCPT was tested by the humidification of air with water. Finally, by the analysis of data and comparison, it was found that the JCPT tray with single cap and two holes exhibited the highest mass transfer efficiency and best performance.展开更多
For graphs G and H,an embedding of G into H is an injection ϕ:V(G)→V(H)such that ϕ(a)ϕ(b)∈E(H)whenever ab∈E(G).A packing of p graphs G1,G2,…,Gp into H is a p-tupleΦ=(ϕ1,ϕ2,…,ϕp)such that,for i=...For graphs G and H,an embedding of G into H is an injection ϕ:V(G)→V(H)such that ϕ(a)ϕ(b)∈E(H)whenever ab∈E(G).A packing of p graphs G1,G2,…,Gp into H is a p-tupleΦ=(ϕ1,ϕ2,…,ϕp)such that,for i=1,2,…,p,ϕi is an embedding of Gi into H and the p sets ϕi(E(Gi))are mutually disjoint.Motivated by the"Tree Packing Conjecture"made by Gyar fas and Lehel,Wang Hong conjectured that for each k-partite tree,there is a packing of two copies of T(X)into a complete k-partite graph Bn+m(Y),where m=■k/2」..In this paper,we confirm this conjecture for k=4.展开更多
In the present work,a computer model was developed to simulate random packing of aggregates.For the sake of simplicity,two dimensional situation was considered and all of the aggregates in concrete were assumed as ell...In the present work,a computer model was developed to simulate random packing of aggregates.For the sake of simplicity,two dimensional situation was considered and all of the aggregates in concrete were assumed as ellipse.2D elliptical models of random packing were firstly demonstrated in periodic boundary condition.In addition,the ellipse random packing model was employed for the influence of aspect ratios on the packing fraction of ellipses.The modeling results demonstrate that the packing fraction of ellipses firstly increases then drops down with increasing aspect ratio.The maximal random packing fraction is 0.66 when aspect ratio is 1.04 in the periodic boundary condition.展开更多
A high-performance concrete (HPC) is required to have superior performance in various aspects such as workability,strength, durability, dimensional stability, segregation stability, and passing ability. The mix desi...A high-performance concrete (HPC) is required to have superior performance in various aspects such as workability,strength, durability, dimensional stability, segregation stability, and passing ability. The mix design of HPC is rather complicatedbecause the number of ingredients in HPC is usually more than those in conventional concrete and some of the required propertiesare conflicting with each other in the sense that improvement in one property would at the same time cause impairment of anotherproperty. However, there is still lack of understanding regarding how the various mix parameters should be optimised forachieving best overall performance. Most practitioners are still conducting mix design primarily through trial concrete mixing,which is laborious, ineffective, and often unable to timely respond to fluctuations in the properties of raw materials. To addressthese issues, the authors have been developing the packing and film thickness theories of concrete materials, in order to revamp themix design philosophy of HPC in terms of the water film thickness (WFT), paste film thickness (PFT), and mortar film thickness(MFT) in the concrete. Based on the findings from an extensive experimental programme, suitable ranges ofWFT, PFT, and MFThave been recommended.展开更多
基金Funded by joint Funds of the National Natural Science Foundation of China(No.U1904188)the Key Research Project of Henan Province for Colleges and Universities(No.26A560009)+3 种基金the Jiaozuo City Science and Technology Planning Project(No.2025210099)the Henan Provincial Science and Technology Research Project(No.252102320305)the Natural Science Foundation of Henan Province(No.252300421917)the Project by Key Laboratory of Intelligent Construction and Safety Operation and Maintenance of Underground Engineering in Henan Province(No.KFKT2024-01)。
摘要To explore mix proportion design of RAC with aggregates tightly packed,the dry and wet packing density of recycled coarse aggregates mixture system and recycled coarse and fine aggregates were tested,then the influence of replacement rate and particle size ratio on the packing density of particle system was explored,the packing density prediction model of recycled coarse aggregates based on particle morphology was constructed,and the mix proportion optimization for recycled aggregate concrete with dry-wet packing model was carried out.The experimental results show that,with the increasing of recycled aggregate replacement rate or fine-grained volume ratio,the dry packing density of recycled coarse aggregates decreases gradually.With the increasing of replacement rate,the particle gradation can be optimized by increasing coarsegrained volume ratio.There is a significant effect for particle morphology parameter K and the particle size ratio on the packing density of the binary mixed system,and the packing density prediction model of recycled coarse aggregates based on particle morphology was constructed.The maximum increase in compressive strength and tensile strength of RAC with mix proportion optimized by the dry-wet packing model are 12.94%and 11.09%,and the cementitious materials is reduced by 21.83%,then the superiority of the mix proportion optimization of RAC with the dry-wet close packing model is confirmed.The results of this paper can provide a theoretical basis for the mix proportion design of RAC.
基金supported by the funding from Hudong-Zhonghua Ship-building(Group)Co.,Ltd.
摘要To address the challenge of large-scale packing problems,this paper proposes a novel hierarchical algorithm based on the geometrical classification of parts.The algorithm begins by classifying parts into three levels based on their area and fullness and then applies distinct packing strategies to each category.An innovative“shape matching”method is introduced,which,together with the“box stacking”(for rectangular parts)and“gravity packing,”forms a comprehensive hierarchical packing system.Level-1 comprises large rectangular parts,which are arranged using the box stacking algorithm.By aligning the corner points of the parts’bounding boxes,this method avoids the hooking issue commonly encountered in gravity packing.Level-2 includes both large,irregular parts and medium-sized parts.They are first processed using the shape matching algorithm,where rotation and translation are applied to achieve contour complementarity.The quality of the match is evaluated using the shape matching coefficient(SMC).If the SMC fails to reach the preset quality threshold,the system switches to box stacking(for large,irregular parts)or gravity packing(for medium-sized parts).Level-3 comprises the remaining smaller parts and those that failed to pack in the previous two levels.For these parts,shape matching is attempted first,and the system resorts to gravity packing in case of failure.The experimental and comparative results demonstrate that the proposed hierarchical algorithm achieves higher material utilization than the traditional gravity packing algorithm.This improvement is facilitated by the box stacking and shape matching strategies,which promote a more orderly and compact arrangement of parts.
摘要Operating Lithium-ion batteries at their temperature limits is a challenging design task due to explosion risk at high temperatures and rapid degradation at low temperatures.Depending on the battery package design,those risks can be solved with passive solutions,which require no active cooling or heating.Thecurrentwork aims to optimize the pack design and materials of the type-NCR18650B battery based on a wide range of operation temperature.The lower limit was denoted by cold case while the maximum limit was expressed by hot case.A combined analyticalnumerical approach was developed to model the heat generation inside the battery.A thermal resistance analysis was used to determine the boundary conditions of the numerical model.The governing differential equations for the 1-D heat generation model were solved analytically.The numerical analysis was considered to determine the best battery pack design based on material parameters,number of batteries,and geometrical arrangement.The analytical results revealedthat the cold case canbe selectedas theworst case and thebestmodel wasobtainedusing thehexagonal-shaped 10-battery pack that was covered with Delrin of 1.8 mm in thickness.The numerical results showed that the best model was the hexagonal-shaped 10-battery pack with Delrin of 2 mm in thickness that achieved the largest temperature of−20.6℃ in the cold case.
基金financially supported by the National Natural Science Foundation of China(No.22275102)NCC Fund(No.NCC2022FH01)。
摘要The propylene/propane(C3H6/C3H8)separation is particularly challenging due to their highly similar physical properties,but of industrial importance.Herein,we report a bifunctional ultramicroporous metal-organic framework(Co-aip-pyz)with customized pore environment and selective binding sites for the challenging C3H6/C3H8 separation.Co-aip-pyz exhibits a good C3H6 uptake with an ultrahigh C3H6 packing density(931 g/L),as well as possesses a remarkable C3H6/C3H8 uptake ratio with 911% and distinguished C3H6/C3H8 selectivity(>104)at 298 K and 1.0 bar.Furthermore,Co-aip-pyz possesses a record high C3H6 packing density with 859 g/L at 313 K and 1.0 bar,which is unprecedented in the C3H6/C3H8 separation.Its high performance for the C3H6/C3H8 separation has been further confirmed by breakthrough experiments and molecular simulations.Combined with good stability,facilely synthesized procedure by low-cost precursors,record-high C3H6 packing density,as well as good C3H6/C3H8 separation performance,it highlights Co-aip-pyz as a benchmark adsorbent to address daunting challenge for industrial C3H6/C3H8 separation.This work provides valuable insights into constructing top-performing MOF materials for addressing the industrial separation challenges.
基金support from National Natural Science Foundation of China(Grant Nos.22275145,22305189and 21875184)Natural Science Foundation of Shaanxi Province(Grant Nos.2022JC-10 and 2024JC-YBQN-0112).
摘要Two-dimensional energetic materials(2DEMs),characterized by their exceptional interlayer sliding properties,are recognized as exemplar of low-sensitivity energetic materials.However,the diversity of available 2DEMs is severely constrained by the absence of efficient methods for rapidly predicting crystal packing modes from molecular structures,impeding the high-throughput rational design of such materials.In this study,we employed quantified indicators,such as hydrogen bond dimension and maximum planar separation,to quickly screen 172DEM and 16 non-2DEM crystal structures from a crystal database.They were subsequently compared and analyzed,focusing on hydrogen bond donor-acceptor combinations,skeleton features,and intermolecular interactions.Our findings suggest that theπ-πpacking interaction energy is a key determinant in the formation of layered packing modes by planar energetic molecules,with its magnitude primarily influenced by the strongest dimericπ-πinteraction(π-π2max).Consequently,we have delineated a critical threshold forπ-π2max to discern layered packing modes and formulated a theoretical model for predictingπ-π2max,grounded in molecular electrostatic potential and dipole moment analysis.The predictive efficacy of this model was substantiated through external validation on a test set comprising 31 planar energetic molecular crystals,achieving an accuracy of 84%and a recall of 75%.Furthermore,the proposed model shows superior classification predictive performance compared to typical machine learning methods,such as random forest,on the external validation samples.This contribution introduces a novel methodology for the identification of crystal packing modes in 2DEMs,potentially accelerating the design and synthesis of high-energy,low-sensitivity 2DEMs.
基金Open Fund of Zhijian Laboratory,Rocket Force University of Engineering(2024-ZJSYS-KF02-09)National Natural Science Foundation of China(51902028,52272034)+1 种基金Key Research and Development Program of Shaanxi(2023JBGS-15)Fundamental Research Funds for the Central Universities(Changan University,300102313202,300102312406)。
摘要To improve the compactness and properties of C/C-SiC-ZrC composites produced by precursor infiltration and pyrolysis(PIP)method,the low-temperature reactive melt infiltration(RMI)process was used to seal the composites using Zr2Cu as the filler.The microstructure,mechanical properties,and ablation properties of the Zr2Cu packed composites were analyzed.Results show that during Zr2Cu impregnation,the melt efficiently fills the large pores of the composites and is converted to ZrCu due to a partial reaction of zirconium with carbon.This results in an increase in composite density from 1.91 g/cm3to 2.24 g/cm3and a reduction in open porosity by 27.35%.Additionally,the flexural strength of Zr2Cu packed C/C-SiC-ZrC composites is improved from 122.78±8.09 MPa to 135.53±5.40 MPa.After plasma ablation for 20 s,the modified composites demonstrate superior ablative resistance compared to PIP C/C-SiC-ZrC,with mass ablation and linear ablation rates of 2.77×10−3g/s and 2.60×10−3mm/s,respectively.The“selftranspiration”effect of the low-melting point copper-containing phase absorbs the heat of the plasma flame,further reducing the ablation temperature and promoting the formation of refined ZrO2particles within the SiO2melting layer.This provides more stable erosion protection for Zr2Cu packed C/C-SiC-ZrC composites.
基金Supported by National Natural Science Foundation of China(No.82271107).
摘要AIM:To assess the variations in photoreceptor cell packing density(PCPD)across the retina among young healthy individuals with emmetropia,low and moderate myopia.METHODS:High-resolution adaptive optics scanning laser ophthalmoscopy(AOSLO)systems were utilized for retinal imaging with a large sampling window of 700μm×700μm.The study cohort included 14 emmetropic[spherical equivalent(SE)ranged+0.5 to-0.5 D],15 low myopic(SE ranged-0.5 to-3 D)and 21 moderate myopic(SE ranged-3 to-6 D)healthy young adults.Photoreceptors at 3°temporal,6°superior and inferior 6°were captured.Statistical analysis was then performed to obtain PCPD and cell spacing.RESULTS:The average age of participants was 22.54±2.86(ranged 20–30y)with no difference among 3 groups.At 3°temporal,the emmetropic group exhibited the highest PCPD of 15186.16±2050.54 cells/mm2,while the low and moderate myopic groups had PCPD of 14009.15±1073.01 and 13466.92±1121.71 cells/mm2,respectively.At 3°temporal,the emmetropic group also had the smallest cell spacing at 6.66±0.26 mm,compared to 6.85±0.26 and 6.91±0.28 mm for the low and moderate myopic groups,respectively.Compared to the emmetropic group,at 3°temporal,the myopic groups showed significantly reduced PCPD(low myopia:P=0.032;moderate myopia:P=0.001).At 6°inferior,the moderate myopic group exhibited a significant decrease in PCPD(P=0.013),while at 6°superior,there were no significant statistical differences in PCPD for the low and moderate myopic groups(P>0.05).In comparison to the emmetropic group,only the moderate myopic group showed significantly increased cell spacing at all three positions(temporal 3°:P=0.011,superior 6°:P=0.046,inferior 6°:P=0.013).Correlation analysis revealed a positive correlation between PCPD and axial length changes(P<0.05).CONCLUSION:Reduced PCPD and increased cell spacing strongly correlated with refractive error in mild to moderate myopic eyes,especially at 6°inferior to the fovea and the decreased PCPD in the macular region of myopic patients may be associated with increased axial lengthinduced retinal stretching.
摘要We study the character of Thurston’s circle packings with obtuse exterior intersection angles,and we get some simple criteria for the existence of hyperbolic circle packings.Moreover,the compactness theorem of combinatorial Ricci flows in hyperbolic background geometry with the weight function Ф∈[0,π)is obtained.As a consequence,We generalize G.Lin’s result[12]from acute exterior intersection angles case to obtuse exterior intersection angles case.
基金National Key Basic Research and Developing Project,China(973 program) (No. 2005CB623902)A Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions,China
摘要Random packings of spherical particles have attracted attention for many years.An algorithm based on compression is developed to generate random packings of spherical particles in this paper.This method is different from previous compression-based algorithm.In order to increase the packing density,a process of shaking is applied during packing process.The algorithm is mainly composed of three procedures:generating initial packing configuration by using random sequential adsorption(RSA),compressing packing domain,and shaking.The packing structure is characterized by packing density and coordinate number.The packing density increases with iteration number and a stable packing configuration is obtained after the iteration number is more than 34 000.The packing density is 0.85 and the average coordinate number is 3.7 in a stable packing configuration.
基金Supported by Natural Science Foundation of China (10571063)
摘要Let X be a metric space and u a finite Borel measure on X. Let P^- u^q,t and P u^q,t be the packing premeasure and the packing measure on X, respectively, defined by the gauge (uB(x, r))^q(2r)^t, where q, t ∈ R. For any compact set E of finite packing premeasure the authors prove: (1) if q ≤ 0 then P^- u^q,t(E) =P u^q,t (E); (2) if q 〉 0 and u is doubling on E then P^- u^q,t (E) and P u^q,t (E) are both zero or neither.
摘要In order to produce the high quality optical aspheric lens,the shrinkage of lens should be strictly controlled during the injection process.Serials of experiments are done to find the factors that affect the lens shrinkage during the injection molding process.The study is focused on the effect of gate size,packing time and pressure on the shrinkage.The gate size decides the effective packing time.Only when the effective packing time is enough,the shrinkage size will be decreased along with the packing pressure increased.However the packing time is determined by the gate size.But big gate size is not easily to be cut and the cutting difficulty will cause the part quality problems.The experiments show that packing pressure not only determines the part shrinkage size and also affects the part shrinkage uniformity.When the packing pressure is more than a critical one,the effect of packing pressure on the shrinkage size becomes smaller.And the shrinkage uniformity is guaranteed.
基金Supported by the National Natural Science Foundation of China(12071334)
摘要Let Bn(X,Y)denote the complete bipartite graph of order n with vertex partition sets X and Y.We prove that for each tree T of order n,there is a packing of k copies of T into a complete bipartite graph Bn+m(X,Y).The ideal of the work comes from the"Tree packing conjecture"made by Gyráfás and Lehel.Bollobás confirmed the"Tree packing conjecture"for many small trees,who showed that one can pack T1,T2,…,Tn/√2into Knand that a better bound would follow from a famous conjecture of Erdo s.In a similar direction,Hobbs,Bour geois and Kasiraj made the following conjecture:Any sequence of trees T2,…,Tn,with Tihaving order i,can be packed into Kn-1,(n/2).Further Hobbs,Bourgeois and Kasiraj proved that any two trees can be packed into a complete bipartite graph Kn-1,(n/2).Motivated by these results,Wang Hong proposed the conjecture:For each tree T of order n,there is a k-packing of T in some complete bipartite graph Bn+k-1(X,Y).In this paper,we prove a weak version of this conjecture.
摘要A packing of the complete directed symmetric graph DK v with m circuits, denoted by ( v,m) DCP, is defined to be a family of arc disjoint m circuits of DK v such that any one arc of DK v \ occurs in at most one m circuit. The packing number P(v,m) is the maximum number of m circuits in such a packing. The packing problem is to determine the value P(v,m) for every integer v≥m. In this paper, the problem is reduced to the case m+6≤v≤2m- 4m-3+12 , for any fixed even integer m≥4 . In particular, the values of P(v,m) are completely determined for m=12 , 14 and 16.
摘要The jet co-flow packing tray(JCPT) with three different types of perforation in equal opening fraction was tested in two rectangular columns with 0.12m in width and 0.27m in length operated with air-water system. The influences of gas phase orifice F-factor and clear liquid height Hc on the amount of liquid lifted, Q, were examined. The corresponding correlation between Q with F-factor and equivalent diameter of perforated holes as well as Hc was obtained. Furthermore, the non-steady state mass transfer performance of JCPT was tested by the humidification of air with water. Finally, by the analysis of data and comparison, it was found that the JCPT tray with single cap and two holes exhibited the highest mass transfer efficiency and best performance.
基金Supported by the National Natural Science Foundation of China(12071334)。
摘要For graphs G and H,an embedding of G into H is an injection ϕ:V(G)→V(H)such that ϕ(a)ϕ(b)∈E(H)whenever ab∈E(G).A packing of p graphs G1,G2,…,Gp into H is a p-tupleΦ=(ϕ1,ϕ2,…,ϕp)such that,for i=1,2,…,p,ϕi is an embedding of Gi into H and the p sets ϕi(E(Gi))are mutually disjoint.Motivated by the"Tree Packing Conjecture"made by Gyar fas and Lehel,Wang Hong conjectured that for each k-partite tree,there is a packing of two copies of T(X)into a complete k-partite graph Bn+m(Y),where m=■k/2」..In this paper,we confirm this conjecture for k=4.
基金Funded by the National Natural Science Foundation of China(No.50708018)the Chinese Ministry of Education Project(No.20070286018)the Ministry of Science and Technology of China"973 Project"(No.2009CB623203)
摘要In the present work,a computer model was developed to simulate random packing of aggregates.For the sake of simplicity,two dimensional situation was considered and all of the aggregates in concrete were assumed as ellipse.2D elliptical models of random packing were firstly demonstrated in periodic boundary condition.In addition,the ellipse random packing model was employed for the influence of aspect ratios on the packing fraction of ellipses.The modeling results demonstrate that the packing fraction of ellipses firstly increases then drops down with increasing aspect ratio.The maximal random packing fraction is 0.66 when aspect ratio is 1.04 in the periodic boundary condition.
基金supported by the Research Grants Council of the Hong Kong Special Administrative Region,China(No.17203514)the Guangdong Provincial Natural Science Foundation(No.2015A030310282)the Guangzhou Science(Technology)Research Project of China(No.20160701329)
摘要A high-performance concrete (HPC) is required to have superior performance in various aspects such as workability,strength, durability, dimensional stability, segregation stability, and passing ability. The mix design of HPC is rather complicatedbecause the number of ingredients in HPC is usually more than those in conventional concrete and some of the required propertiesare conflicting with each other in the sense that improvement in one property would at the same time cause impairment of anotherproperty. However, there is still lack of understanding regarding how the various mix parameters should be optimised forachieving best overall performance. Most practitioners are still conducting mix design primarily through trial concrete mixing,which is laborious, ineffective, and often unable to timely respond to fluctuations in the properties of raw materials. To addressthese issues, the authors have been developing the packing and film thickness theories of concrete materials, in order to revamp themix design philosophy of HPC in terms of the water film thickness (WFT), paste film thickness (PFT), and mortar film thickness(MFT) in the concrete. Based on the findings from an extensive experimental programme, suitable ranges ofWFT, PFT, and MFThave been recommended.