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Preparation and characterization of ZrO_2/TiO_2 composite photocatalytic film by micro-arc oxidation 认领 引用 被引量:9
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作者 罗强 蔡启舟 +4 位作者 李欣蔚 潘振华 李玉洁 陈喜娣 严青松 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第10期2945-2950,共6页
ZrO2/TiO2 composite photocatalytic film was produced on the pure titanium substrate using in-situ Zr(OH)4 colloidal particle by the micro-arc oxidation technique and characterized by scanning electron microscope (... ZrO2/TiO2 composite photocatalytic film was produced on the pure titanium substrate using in-situ Zr(OH)4 colloidal particle by the micro-arc oxidation technique and characterized by scanning electron microscope (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD) and ultraviolet-visible (UV-Vis) spectrophotometer. The composite film shows a lamellar and porous structure which consists of anatase, futile and ZrO2 phases. The optical absorption edge of film is shifted to longer wavelength when ZrO2 is introduced to TiO2. Furthermore, the photocatalytic reaction rate constants of degradation of rhodamine B solution with ZrO2/TiO2 composite film and pure TiO2 film under ultraviolet irradiation are measured as 0.0442 and 0.0186 h 1, respectively. 展开更多
关键词 pure titanium micro-arc oxidation Zr(OH)4 colloidal particle ZrO2/TiO2 composite photocatalytic film
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Morphology and conductivity of in-situ PEO-LiClO_4-TiO_2 composite polymer electrolyte 认领 引用 被引量:3
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作者 潘春跃 冯庆 +2 位作者 王丽君 张倩 巢猛 《Journal of Central South University of Technology》 2007年第3期348-352,共5页
PEO-LiClO4-TiO2 composite polymer electrolyte films were prepared. TiO2 was formed directly in matrix by hydrolysis and condensation reaction of tetrabutyl titanate. The crystallinity, morphology and ionic conductivit... PEO-LiClO4-TiO2 composite polymer electrolyte films were prepared. TiO2 was formed directly in matrix by hydrolysis and condensation reaction of tetrabutyl titanate. The crystallinity, morphology and ionic conductivity of composite polymer electrolyte films were examined by differential scanning calorimetry, scanning electron microscopy, atom force microscopy and alternating current impedance spectroscopy, respectively. The glass transition temperature and the crystallinity of composite polymer electrolytes are decreased compared with those of PEO-LiClO4 polymer electrolyte film. The results show that TiO2 particles are uniformly dispersed in PEO-LiClO4-5%TiO2 composite polymer electrolyte film. The maximal conductivity of 5.5×10、5 Scm at 20 ℃ of PEO-LiClO4-TiO2 film is obtained at 5% mass fraction of TiO2. 展开更多
关键词 polyethylene oxide (PEO) TiO2 composite polymer electrolyte in-situ composite conductivity
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Preparation of defect free ceramic/Ti composite membranes by surface modification and in situ oxidation 认领 引用 被引量:1
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作者 ZHANG Dong-qiang YANG Ping +2 位作者 WU Jian-yang ZHAO Jing CHEN Yan-an 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第12期3295-3304,共10页
Al2O3 ceramic powder was applied to modify the large pores defects on the surface of the porous metal Ti support,in situ oxidation method was a convenient method to prepare defect free ceramic/Ti composite membranes o... Al2O3 ceramic powder was applied to modify the large pores defects on the surface of the porous metal Ti support,in situ oxidation method was a convenient method to prepare defect free ceramic/Ti composite membranes on this basis.In situ oxidation conditions experimental results show that the best condition for preparing the TiO2-Al2O3/Ti composite membrane is under 800°C for 2 h,and the microstructure and pore sizes of the TiO2-Al2O3/Ti composite membranes are affected obviously.The thickness and composition of the TiO2/Ti composite membranes are determined by SEM and XRD completely.The pore size distribution of the composite membrane is measured by bubble pressure method,the most probable aperture is about 3.12μm,while the average pore size of defect free TiO2-Al2O3/Ti is about 3.23μm.After ultrasonic treatment,the slight weight change of membranes reveals no observable change,which indicates that TiO2-Al2O3/Ti composite membranes maintain a good stability. 展开更多
关键词 porous Ti ceramic TiO2 layer in situ oxidation composite membrane surface modification
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Reduction Band Gap Energy of TiO2Assembled with Graphene Oxide Nanosheets 认领 引用 被引量:1
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作者 Abdelmajid Timoumi 《Graphene》 2018年第4期31-38,共8页
This research work aims to reduce the band gap of thin layers of titanium oxide by the incorporation of graphene oxide sheets. Thin layers of the TiO2-GO composites were prepared on a glass substrate by the spin-coati... This research work aims to reduce the band gap of thin layers of titanium oxide by the incorporation of graphene oxide sheets. Thin layers of the TiO2-GO composites were prepared on a glass substrate by the spin-coating technique from GO and an aqueous solution of TiO2. A significant decrease in optical band gap was observed at the TiO2-GO compound compared to that of pure TiO2. Samples as prepared were characterized using XRD, SEM and UV-visible spectra. XRD analysis revealed the amorphous nature of the deposited layers. Scanning electron microscope reveals the dispersion of graphene nanofiles among titanium oxide nanoparticles distributed at the surface with an almost uniform size distribution. The band gap has been calculated and is around 2 eV after incorporation of Graphene oxide. The chemical bond C-Ti between the titanium oxide and graphene sheets is at the origin of this reduction. 展开更多
关键词 Titanium (IV) Oxide Graphene Oxide TiO2-GO Thin Films Composite Materials
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聚3,4-乙烯二氧噻吩/碳纳米管/TiO2电化学传感器构建及其在细胞检测中的应用 认领 引用
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作者 厉婷 徐加泉 黄卫华 《分析科学学报》 CAS CSCD 北大核心 2020年第5期701-709,共9页
本文结合TiO2优良的光催化降解性能,以及电化学传感材料PEDOT/PSS和CNTs的优良电化学性能及抗污染性能,采用一种直接拉制技术,简便、快捷地制备了PEDOT/CNTs/TiO2复合纤维,其长度可达10cm,直径最小可至3μm。在此基础上,分别构建了兼具... 本文结合TiO2优良的光催化降解性能,以及电化学传感材料PEDOT/PSS和CNTs的优良电化学性能及抗污染性能,采用一种直接拉制技术,简便、快捷地制备了PEDOT/CNTs/TiO2复合纤维,其长度可达10cm,直径最小可至3μm。在此基础上,分别构建了兼具抗污染性能和光致清洁性能的平面微米线电极及单根微米线电极,用于监测内皮细胞释放NO。结果显示,所制电极具有良好的电化学性能,对NO的检出限可达4nmol/mL;在培养基中浸泡34h后,其电化学性能无明显变化,表现出良好的抗污染性能;在彻底污染后(无电化学响应),经紫外光照30min后,其电化学性能可恢复至初始的30%,表现出一定的光致清洁能力。 展开更多
关键词 电化学传感器 光致清洁 PEDOT/CNTs/TiO_2纤维 抗污染 一氧化氮
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Electrochemical Performance of PEO10LiX-Li_2TiO_3 Composite Polymer Electrolytes 认领 引用 被引量:1
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作者 路密 史鹏飞 《Chinese Journal of Chemistry》 SCIE CAS 2004年第1期47-50,共4页
The conductivities of polyethylene oxide (PEO)-based polymer electrolytes (PE) can be improved by the addition of inorganic inert powder. The composite polymer electrolytes (CPE) PEO10LiX (X=4ClO- or 322N(CFSO)-)-Li2T... The conductivities of polyethylene oxide (PEO)-based polymer electrolytes (PE) can be improved by the addition of inorganic inert powder. The composite polymer electrolytes (CPE) PEO10LiX (X=4ClO- or 322N(CFSO)-)-Li2TiO3 were prepared by solution casting with inorganic solid electrolyte Li2TiO3 powder as a filler. Results showed that the conductivities of PEO10LiClO4-3wt% Li2TiO3 and PEO10LiN(CF3SO2)2-10wt% Li2TiO3 at 30 ℃ were 8.6×10-6 and 5.6×10-5 S·cm-1, respectively. The conductivities of CPE increased with the decrease of filler抯 particle size. The ionic conduction mechanism analysis showed that there may be three conduction routes in the CPE, i.e., PEO bulk, polymer-filler interface and Li2TiO3 crystal. 展开更多
关键词 rechargeable lithium batteries polymer electrolyte composite polymer electrolyte conductivities polyethylene oxide Li2TiO3
Novel Pd/TiO2-Al2O3 Catalysts for Methane Total Oxidation at Low Temperature and Their ^18O-Isotope Exchange Behavior 认领 引用 被引量:6
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作者 林伟 林莉 +3 位作者 朱月香 谢有畅 SCHEURELL, K KEMNITZ, E. 《Chinese Journal of Chemistry》 SCIE CAS 2005年第10期1333-1338,共6页
Pd supported on TiO2-Al2O3 binary oxides prepared by coprecipitation method has been investigated for the total oxidation of methane. All Pd/TiO2-Al2O3 catalysts show higher activity than Pd/Al2O3 and Pd/TiO2. Among t... Pd supported on TiO2-Al2O3 binary oxides prepared by coprecipitation method has been investigated for the total oxidation of methane. All Pd/TiO2-Al2O3 catalysts show higher activity than Pd/Al2O3 and Pd/TiO2. Among them, Pd/2Ti-3Al with a Ti/Al ratio of 2 to 3 has a T90% of 395 ℃ at a gas hourly mass velocity of 33000 mL/(h*g), which is at least 50 ℃ lower than that of Pd supported on single metal oxide Al2O3 or TiO2. The results of TPR and ^180-isotope exchange experiments demonstrated that the excellent activity of Pd/2Ti-3Al was due to its high oxygen mobility and moderate reducibility, which is in accordance with our previous work, XPS results indicated that the dispersion of Pd was not the key factor to influence the catalytic activity. 展开更多
关键词 methane total oxidation palladium TiO2-Al2O3 composite reducibility oxygen mobility
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