In the intricate tapestry of life,the cell stands as the fundamental unit,orchestrating its survival and functionality through a symphony of meticulously regulated biochemical processes.However,just as the Earth’s ec...In the intricate tapestry of life,the cell stands as the fundamental unit,orchestrating its survival and functionality through a symphony of meticulously regulated biochemical processes.However,just as the Earth’s ecosystem has a carrying capacity,cells also face their own“survival limits”in maintaining normal function.Although the concept has not yet been clearly articulated by researchers,the survival limit of a cell implies the threshold of extreme conditions or parameters that a cell can withstand in order to maintain normal function and survival.These conditions include,but are not limited to,extreme ranges of key parameters such as energy metabolism,redox balance,molecular crowding,and signaling.Breaching these limits may lead to cellular dysfunction,senescence or even death.展开更多
Gradient microstructures strengthened by serrated Grain Boundaries(GBs)were achieved through a combination of Gradient Strain Deformation(GSD)and Serration Heat Treatment(SHT),with particular focus on microstructural ...Gradient microstructures strengthened by serrated Grain Boundaries(GBs)were achieved through a combination of Gradient Strain Deformation(GSD)and Serration Heat Treatment(SHT),with particular focus on microstructural evolution,underlying mechanisms,and the critical influencing factors.Dynamic recrystallization governed the microstructural evolution in the fine-grained and transition regions during GSD,where multiple nucleation mechanisms were active.Plastic deformation facilitated the dissolution ofγ'phase in fine-grained regions,ultimately resulting in its morphological transformation.During the subsequent SHT,serrated GBs formed within the gradient microstructures produced by prior GSD without disrupting the grain size gradient,thereby enhancing creep resistance.Two distinct mechanisms associated withγ'gbparticles governed the formation of the serrations at GBs.Owing to the stronger dragging effect of grain boundary junctions in fine-grained regions,the amplitude and wavelength of serrations in these regions were smaller than those in coarse-grained regions.Moreover,the formation of serrations exhibited a strong dependence on the inherent properties of the GBs.The random high-angle grain boundaries(HAGBs)with misorientation angles in the range of 30-59°tended to become serrated more easily during SHT due to their high mobility and the accelerated precipitation ofγ'gbparticles at them.Low-ΣHAGBs and low-angle GBs were not prone to form serrations.In particular,serration formation was completely inhibited atΣ3 twin boundaries due to their extremely low mobility and the absence ofγ'gbparticles.展开更多
Although lithium metal has been regarded as an ideal anode material for high-energy-density batteries,its practical applications remain hindered by many serious challenges.Three-dimensional(3D)porous Cu current collec...Although lithium metal has been regarded as an ideal anode material for high-energy-density batteries,its practical applications remain hindered by many serious challenges.Three-dimensional(3D)porous Cu current collectors demonstrate potential in ensuring uniform Li deposition.However,notable drawbacks of 3D Cu collectors—such as poor lithophilic properties,unordered interface microstructure,and insufficient surface area—still hamper their effectiveness.Herein,a 3D porous Cu skeleton with lithiophilic Cu0.64Zn0.36 alloy“skins”and curvature boundaries(CuZn@Cu)is developed.In CuZn@Cu,the Cu0.64Zn0.36 alloy layer endows the collector with good lithium affinity and low surface reaction activation energy,thereby promoting uniform lithium deposition.In addition,the abundant curvature boundaries in CuZn@Cu regulate the distributions of the electric field and lithium ion flux,guiding the selective nucleation and growth of lithium.Consequently,compact and dendrite-free lithium deposition is achieved on CuZn@Cu,and the CuZn@Cu collector enables a high average Coulombic efficiency of 98.15%in 1000 cycles.The lithium symmetric cells with the CuZn@Cu exhibit a long cycle life of more than 1400 h at1 m A cm-2.展开更多
Grain boundaries(GBs),particularlyΣ7 coincidence site lattice(CSL)defects experimentally observed in MXenes,significantly influence their performance as lithium-ion battery(LIB)anodes.This work systematically investi...Grain boundaries(GBs),particularlyΣ7 coincidence site lattice(CSL)defects experimentally observed in MXenes,significantly influence their performance as lithium-ion battery(LIB)anodes.This work systematically investigates the impact ofΣ7 GBs on MXene electrochemical properties,with a focus on rate capability.The results indicated thatΣ7 GB formation is thermodynamically favored in Ti2C,Nb2C,and Mo2C MXenes compared to other M2C compositions,with stability further enhanced by oxygen and sulfur surface functionalization.These GBs induce substantial geometric distortions that reduce surface charge localization while enhancing electrical conductivity in Ti2CO2.The altered electronic structure at GB sites weakens lithium adsorption strength without promoting lithium dendrite formation.Furthermore,diffusion kinetics calculations reveal significantly reduced lithium diffusion barriers atΣ7 GBs in Ti2C,Mo2C,and Mo2CS2compared to pristine materials.Mechanistic analysis attributes this enhancement to diminished charge localization at GB regions,which generates a“charge pool”effect—a zone of uniformly distributed free charge observed in Ti2C and Mo2C.This charge pool not only facilitates ultra-low lithium diffusion barriers(as low as 11 meV in M2C at 0.1 V vs.Li+/Li)but also enhances potential responsiveness of diffusion kinetics.Our findings establish the intentional introduction ofΣ7 GBs as an effective strategy for designing high-rate MXene anodes.This work provides fundamental insights into GB-enhanced electrochemical mechanisms in 2D materials,offering crucial theoretical guidance for the design of high-rate anode materials.展开更多
Bloch points and transverse walls can serve as topological boundaries within a magnetic domain wall.Here,we investigate the stability and dynamics of these topological boundaries for potential spintronic applications....Bloch points and transverse walls can serve as topological boundaries within a magnetic domain wall.Here,we investigate the stability and dynamics of these topological boundaries for potential spintronic applications.Using micromagnetic simulations,we reveal the coexistence regimes of Bloch points and transverse walls in thin films with perpendicular magnetic anisotropy.An external in-plane field enables reversible transitions between these states through boundary-mediated Bloch point nucleation and annihilation processes.Under spin-transfer torque,transverse walls exhibit transverse drift and deformation.In contrast,Bloch points move strictly along the domain wall without transverse deflection and feature a Walker breakdown threshold an order of magnitude higher than conventional domain walls.Our findings establish a device concept where binary states correspond to in-plane magnetization orientations separated by mobile topological boundaries,offering new opportunities for spintronic architectures.展开更多
Traditional oilfields face increasing extraction challenges, primarily due to reservoir quality degradation and production decline, which are further exacerbated by volatile international crude oil prices—illustrated...Traditional oilfields face increasing extraction challenges, primarily due to reservoir quality degradation and production decline, which are further exacerbated by volatile international crude oil prices—illustrated by Brent Crude’s trajectory from pandemic-induced negative pricing to geopolitically driven surges exceeding USD 100 per barrel. This study addresses these complexities through an integrated methodological framework applied to medium-permeability sandstone reservoirs in the Xinjiang oilfield by combining advanced numerical simulations with multivariate regression analysis. The methodology employs Latin Hypercube Sampling (LHS) to stratify geological parameter distributions and constructs heterogeneous reservoir models using Petrel software, rigorously validated through historical production data matching. Production forecasting integrates numerical simulation and Decline Curve Analysis (DCA), while investment estimation utilizes Ordinary Least Squares (OLS) regression to correlate engineering parameters with drilling and completion costs. Economic evaluation incorporates Discounted Cash Flow (DCF) modeling and breakeven analysis, establishing techno-economic boundaries via oil price sensitivity analysis ranging from USD 40 to 90 per barrel. Visualization tools, including 3D heatmaps, delineate nonlinear interactions among engineering, geological, and investment datasets under economic constraints. Key findings demonstrate that for the target reservoirs, as oil prices increase from USD 40 to USD 90 per barrel, the minimum economic thickness threshold decreases from approximately 5.7 m to about 2.5 m, with model prediction errors consistently below 25% across validation datasets. This framework provides scientifically grounded decision support for optimizing capital allocation and offers actionable insights to enhance undeveloped hydrocarbon development planning amid market uncertainty. Ultimately, it supports national energy security through technically robust and economically viable resource exploitation strategies.展开更多
Rapid urban expansion in mountainous cities exacerbates ecological fragility and intensifies tensions between development and environmental sustainability.Achieving a dynamic balance between ecological protection and ...Rapid urban expansion in mountainous cities exacerbates ecological fragility and intensifies tensions between development and environmental sustainability.Achieving a dynamic balance between ecological protection and urban growth boundaries(UGBs)is therefore essential.However,existing UGB delineation methods rarely account for the unique ecological indicators and spatial complexities of mountain regions,limiting their effectiveness in guiding sustainable land use planning.To address this gap,we propose a framework that integrates ecological constraints(ECs)into the PLUS model for UGB delineation in mountainous cities.Key ecological indicators are systematically evaluated and embedded as model constraints,while mathematical morphology techniques are applied to optimize UGB boundaries.Using Chongqing,a representative mountainous city in China,as a case study,we identified 1,641 km²of EC zones.Results indicate that soil and water conservation,water retention,and biodiversity maintenance are the primary ecosystem service functions in mountainous urban settings.Validation of the PLUS model demonstrated robust simulation performance(overall accuracy=0.86,Kappa=0.79,FoM=0.34).Elevation,residential areas,and water bodies were identified as the main drivers of urban expansion.The EC-based approach yielded 1,280 km²of UGBs—slightly less than the 1,305 km²projected under the natural growth scenario—effectively curbing encroachment into ecologically sensitive areas while accommodating urban growth and reducing landscape fragmentation.The proposed framework provides practical guidance for sustainable land use planning and offers transferable insights for UGB delineation in other ecologically fragile mountainous cities.展开更多
Slip transfer/blocking at grain boundaries was studied in a WE43 Mg alloy through a combined experimental approach involving electron backscatter diffraction(EBSD),slip trace modified lattice rotation analysis(ST-MLRA...Slip transfer/blocking at grain boundaries was studied in a WE43 Mg alloy through a combined experimental approach involving electron backscatter diffraction(EBSD),slip trace modified lattice rotation analysis(ST-MLRA),and diffraction contrast tomography(DCT).Slip(basal slip)transfer occurred exclusively across low-angle grain boundaries(<20°),while slip blocking was dominant(80.4%),and slip to twin transfer typically occurred at higher misorientation angles.Among the geometric descriptors analyzed,low values ofκ(angle between slip directions),ψ(angle between slip plane normals),andθ(angle between the traces of the incoming and outgoing slip planes with the GB plane)were consistently associated with the slip transfer cases.Notably,slip transfer events were tightly gathered in the high-compatibility region where both the Luster-Morris parameter(m)and the LRB factor exceeded 0.9,suggesting that both serve as robust criteria for basal slip transmission across grain boundaries.The integration of 3D grain morphology with actual slip system identification provides a comprehensive framework for evaluating intergranular deformation in Mg alloys.展开更多
A large-scale view of the magnetospheric cusp is expected to be obtained by the Soft X-ray Imager(SXI)onboard the Solar wind Magnetosphere Ionosphere Link Explorer(SMILE).However,it is challenging to trace the three-d...A large-scale view of the magnetospheric cusp is expected to be obtained by the Soft X-ray Imager(SXI)onboard the Solar wind Magnetosphere Ionosphere Link Explorer(SMILE).However,it is challenging to trace the three-dimensional cusp boundary from a two-dimensional X-ray image because the detected X-ray signals will be integrated along the line of sight.In this work,a global magnetohydrodynamic code was used to simulate the X-ray images and photon count images,assuming an interplanetary magnetic field with a pure Bz component.The assumption of an elliptic cusp boundary at a given altitude was used to trace the equatorward and poleward boundaries of the cusp from a simulated X-ray image.The average discrepancy was less than 0.1 RE.To reduce the influence of instrument effects and cosmic X-ray backgrounds,image denoising was considered before applying the method above to SXI photon count images.The cusp boundaries were reasonably reconstructed from the noisy X-ray image.展开更多
Enhancing the strength of nanotwinned aluminum(Al)is essential for the development of nextgeneration high-end chip technology.To better understand the detwinning behavior of nanotwinned Al under conditions with no res...Enhancing the strength of nanotwinned aluminum(Al)is essential for the development of nextgeneration high-end chip technology.To better understand the detwinning behavior of nanotwinned Al under conditions with no resolved shear stress acting on the twin boundaries,we conducted molecular dynamics simulations of uniaxial tensile deformation in nanotwinned single-crystal Al at room temperature.Detwinning is observed only when the twin boundary spacing is 7.01 A.At larger spacings,twin boundaries remain parallel to the loading direction,with no rotation or bending,indicating negligible migration.Detwinning is triggered by localized stress from dislocation interactions,with detwinning fraction evolving synchronously with dislocation density.In the absence of detwinning,dislocations inclined toward twin boundaries interact frequently with them,leading to a loss of coherency that intensifies with increasing twin boundary spacing.These findings enhance understanding of the plastic deformation mechanisms in nanotwinned metals at very small twin boundary spacings,supplement the conventional understanding of twin boundary stability,and therefore suggest potential pathways for designing Al-based nanostructures with enhanced stability or controllable plastic deformation.展开更多
Ferrite-carbon composites effectively absorb electromagnetic(EM)waves via coupled mechanisms.However,the dynamic evolution of intrinsic polarization and magnetic loss mechanisms following interfacial coupling has long...Ferrite-carbon composites effectively absorb electromagnetic(EM)waves via coupled mechanisms.However,the dynamic evolution of intrinsic polarization and magnetic loss mechanisms following interfacial coupling has long been overlooked,impeding broadening of the ultra-broadband EM wave absorption performance in heterostructures.Herein,via surface ligand modulation,in situ growth of 0D Fe3O4quantum dots(QDs)on the surface of 1D carbon nanotubes triggers grain boundary coupling.The energy rebalancing effect at the interface induces an extreme charge rearrangement within the Fe3O4QDs.This rearrangement enhances dipole orientation hysteresis and charge accumulation,resulting in charge and interfacial polarization losses.Meanwhile,for subcritical Fe3O4QDs,short-range magnetic resonance and magnetic exchange-triggered magnetic resonance transfer synergistically enhance the magnetic loss.Through charge rearrangement/magnetic resonance induced by0D/1D grain boundary coupling,an effective bandwidth of nearly 10 GHz is achieved at a minimal thickness of 2 mm,covering the X and Ku bands.This strategy provides an effective paradigm and novel theoretical insights for ultra-broadband electromagnetic wave absorption applications.展开更多
Triple phase boundary(TPB)and pore structure in the cathode catalyst layer(CCL)play vital roles in the uti-lization of Pt-based catalyst in proton exchange membrane fuel cells(PEMFCs).The excellent TPBs on the catalys...Triple phase boundary(TPB)and pore structure in the cathode catalyst layer(CCL)play vital roles in the uti-lization of Pt-based catalyst in proton exchange membrane fuel cells(PEMFCs).The excellent TPBs on the catalyst surface and pore structure should be able to increase oxygen transport channels while maintaining proton transport,and simultaneously facilitate the efficient removal of product water.Here,we design a precision-regulated structure for the Pt/ionomer interfacial and pores using a gas breakthrough method driven by high evolution pressure.The highly efficient oxygen transport channels are created through enhanced TPB accessibility and opened pore structure in CCLs,leading to an 11% improvement in PEMFC performance at an appropriate HER current density and bubble intensity conditions.The proposed strategy provides a direction to tune the Pt/ionomer interface and improve the catalytic activity of Pt in membrane electrode assembly(MEA).展开更多
In an era marked by unprecedented digital transformation across the glboe, industries are experiencing profound shifts in their operational paradigms and competitive dynamics. However, existing research has predominan...In an era marked by unprecedented digital transformation across the glboe, industries are experiencing profound shifts in their operational paradigms and competitive dynamics. However, existing research has predominantly focused on the internal impacts of corporate digital transformation, overlooking the external effects it generates, particularly the spillover effects within vertical supply chain relationships. This study provides an in-depth examination of how corporate digital transformation affects the governance efficiency of upstream and downstream supply chain partners and explores the underlying transmission mechanisms. The research reveals that corporate digital transformation has a dual impact on the governance efficiency of upstream and downstream supply chain partners. Furthermore, the study demonstrates that resource endowment conditions across different industries and regions significantly influence both the transmission mechanisms and outcomes of digital transformation. Finally, this study proposes corresponding managerial implications based on the theoretical analysis.展开更多
William Faulkner's A Rose for Emily has long been interpreted as an allegory of the conflict between Southern tradition and modern civilization. This paper attempts to examine Emily Grierson from the dual perspect...William Faulkner's A Rose for Emily has long been interpreted as an allegory of the conflict between Southern tradition and modern civilization. This paper attempts to examine Emily Grierson from the dual perspectives of "spatial boundaries" and "cultural reproduction", exploring how she is constructed by the old Southern order as a "monument" and how she moves toward both cultural and physical death under the penetration of Northern modernity.The study finds that Emily's house is not merely a physically enclosed entity but constitutes a superimposition of three boundaries: physical, social, and bodily. Her poisoning of the Northern suitor, Homer Barron, is not simply a matter of personal love or hatred, but an extreme response triggered by the complete failure of the “cultural reproduction” mechanism when Southern aristocratic culture encounters Northern capitalist values. Through this interpretation, this paper seeks to reveal Faulkner's ambivalent attitude toward the fate of the South-mourning the passing of tradition while keenly perceiving its inherent decay and violence.展开更多
To elucidate the deformation mechanisms ofγ-TiAl,the nanoindentation experiments and crystal plasticity finite element(CPFE)simulation were employed to investigate the effects of crystal orientations and GBs on the m...To elucidate the deformation mechanisms ofγ-TiAl,the nanoindentation experiments and crystal plasticity finite element(CPFE)simulation were employed to investigate the effects of crystal orientations and GBs on the mechanical properties ofγ-TiAl alloys.A crystal plasticity constitutive model was developed,and load-displacement curves,hardness,and Young's modulus were obtained for both single grains and GBs inγ-TiAl alloys.Based on the aforementioned model,this study investigated the distribution patterns of surface morphology around the indentation sites of individual grain and GBs.It also analyzed the cumulative shear strain distribution,slip system activation,and the interaction between GBs and dislocation slip for various crystal orientations.The results indicate that the mechanical response and pileup behavior exhibit significant anisotropy due to the interplay among the indenter geometry,material slip systems,and cumulative shear strain distribution.Moreover,the interaction between GBs and dislocation slip substantially alters dislocation distribution,thereby influencing material flow and playing a critical role in the mechanical response and plastic deformation of the material.展开更多
High-performance lead-free piezoelectric single crystals are urgently needed for next-generation actuators and transducers.In this study,we reveal that a compositionally driven tetragonal-pseudocubic(T-PC)phase bounda...High-performance lead-free piezoelectric single crystals are urgently needed for next-generation actuators and transducers.In this study,we reveal that a compositionally driven tetragonal-pseudocubic(T-PC)phase boundary,in conjunction with an octahedral order-disorder tilting transition,significantly enhances the piezoelectric response in Nb5+-substitution(Bi0.48Na0.425K0.055Ba0.04)(Ti0.98Nb0.02)O3(BNKBT-2Nb)single crystals.The crystal achieves an outstanding piezoelectric coefficient of d33=662 pC/N at room temperature.In situ X-ray diffraction confirms an electric field-induced transition from the PC to T phase.Atomic-resolution HADDF-STEM analysis reveals an increase in the c/a ratio(c/a>1.01)on the local scale and ordered octahe-dral tilting of the a0a0c+type driven by the poling field.The single crystals exhibit excellent piezoelectric per-formance over a broad temperature range,achieving a peak d33 of 920 pC/N at approximately 92℃.Furthermore,the polar states exhibit a pronounced frequency dependence near the depolarization temperature.These findings provide critical insight into the structure-property relationship and offer a promising pathway for designing advanced lead-free piezoelectric crystals for functional electromechanical applications.展开更多
On February 8,2025,a remote area in the Caribbean Sea was rocked by a large MW7.6(USGS,2025) earthquake,centered 209 km SSW of Georgetown,the capital of the Cayman Islands,and the largest city(population~41 000) of...On February 8,2025,a remote area in the Caribbean Sea was rocked by a large MW7.6(USGS,2025) earthquake,centered 209 km SSW of Georgetown,the capital of the Cayman Islands,and the largest city(population~41 000) of the British Overseas Territories(Figure 1).The earthquake was significant due to its large magnitude,potential regional impact,and the possibility of generating a tsunami.展开更多
Grain boundary(GB)characteristics in relation to texture development were investigated in an extruded Mg−Zn−Gd alloy subjected to isothermal annealing at 400°C for 5−155 min.Quasi in-situ electron backscatter dif...Grain boundary(GB)characteristics in relation to texture development were investigated in an extruded Mg−Zn−Gd alloy subjected to isothermal annealing at 400°C for 5−155 min.Quasi in-situ electron backscatter diffraction(EBSD)was employed to analyze grain growth(GG),grain rotation,and GB character evolution.GG was found to proceed via two distinct mechanisms:nucleation at triple junction followed by subsequent growth,and GB migration governed by the Burke–Turnbull mechanism.The rotation angle of(0001)basal pole ranged from 31°to 40°,contributing to the observed non-basal texture.Misfit strain(δ)associated with various coincidence site lattice(CSL)boundaries was evaluated,showing that the length fractions forΣ7,Σ13b andΣ45a boundaries decreased in the isothermal annealing due to their higherδvalues,while those forΣ9,Σ21a andΣ43b boundaries increased.Grain growth kinetics was evaluated after isothermal annealing and grain growth exponent was also determined.Collectively,these findings demonstrate that GB characteristics significantly influence texture evolution by promoting energetically favorable boundary configurations.展开更多
Quasi-linear convective systems(QLCSs)frequently produce severe weather in North China,with multiple QLCSs often forming successively within a short period.However,their formation mechanisms under such conditions rema...Quasi-linear convective systems(QLCSs)frequently produce severe weather in North China,with multiple QLCSs often forming successively within a short period.However,their formation mechanisms under such conditions remain unclear.This study investigated the formation mechanisms of three successive QLCSs that affected Beijing and its vicinity from the afternoon to evening on 12 June 2022,using in-situ and remote sensing observations as well as high-resolution Weather Research and Forecasting model simulations with a 9-,3-,1-km nested grid.The event occurred within the trough of a mature cold vortex,which induced dry westerlies over the western mountainous areas and moist southerlies over the eastern plains of North China.Diurnal solar heating further intensified the zonal thermal and moisture contrasts between the eastern and western domains.Therefore,a southwest-northeast-oriented dryline with a dynamical confluence persisted along the eastern Taihang Mountains.To the west of the dryline,sustained boundary layer turbulent activities eliminated convective inhibition.Meanwhile,episodic weak cold advections induced by the cold vortex modestly increased the convective available potential energy over the northern mountains,providing energy for the generation of convective cell clusters(CCs).These sequentially initiated CCs propagated southeastward under the steering airflow,with distinct outflow boundaries forming at their leading edges.Crucially,the continuous merging between the southeastward-moving CC outflow boundaries and the quasi-stationary dryline strengthened the low-level convergence both in depth and intensity along segments of the dryline zone.The intensified dynamical lifting ultimately triggered convection along these segments,corresponding to the successive formation of three QLCSs.This paper highlights the synergistic effects of cold-vortex forcing,complex-terrain modulation,and dryline-outflow boundary interactions on the formation of organized convection over mountainous areas.The findings benefit the forecasting and early warning of similar severe convective events in North China.展开更多
Solute atoms and precipitates significantly influence the mechanical properties of Mg alloys.Previous studies have mainly focused on the segregation behaviors of Mg alloys after annealing.In this study,we investigated...Solute atoms and precipitates significantly influence the mechanical properties of Mg alloys.Previous studies have mainly focused on the segregation behaviors of Mg alloys after annealing.In this study,we investigated the segregation behaviors of an Mg-RE alloy under deformation.We found that the enrichment of solute atoms occurred in{101-1}compressive twin boundaries under compression at 298 K without any annealing in an Mg-RE alloy by scanning transmission electron microscopy and energy-dispersive X-ray analysis.The segregated solutes and precipitates impeded the twin growth,partially contributing to the formation of small-sized{101-1}compressive twins.This research indicates the twin boundaries can be strengthened by segregated solutes and precipitates formed under deformation at room temperature.展开更多
摘要In the intricate tapestry of life,the cell stands as the fundamental unit,orchestrating its survival and functionality through a symphony of meticulously regulated biochemical processes.However,just as the Earth’s ecosystem has a carrying capacity,cells also face their own“survival limits”in maintaining normal function.Although the concept has not yet been clearly articulated by researchers,the survival limit of a cell implies the threshold of extreme conditions or parameters that a cell can withstand in order to maintain normal function and survival.These conditions include,but are not limited to,extreme ranges of key parameters such as energy metabolism,redox balance,molecular crowding,and signaling.Breaching these limits may lead to cellular dysfunction,senescence or even death.
基金co-supported by the National Natural Science Foundation of China(Nos.52305421 and 52175363)the General Research Fund of Hong Kong,China(No.15223520)the projects from the Hong Kong Polytechnic University,China(Nos.4-W418,1-ZE1W,4-WZ4W and 1-CD4H)。
摘要Gradient microstructures strengthened by serrated Grain Boundaries(GBs)were achieved through a combination of Gradient Strain Deformation(GSD)and Serration Heat Treatment(SHT),with particular focus on microstructural evolution,underlying mechanisms,and the critical influencing factors.Dynamic recrystallization governed the microstructural evolution in the fine-grained and transition regions during GSD,where multiple nucleation mechanisms were active.Plastic deformation facilitated the dissolution ofγ'phase in fine-grained regions,ultimately resulting in its morphological transformation.During the subsequent SHT,serrated GBs formed within the gradient microstructures produced by prior GSD without disrupting the grain size gradient,thereby enhancing creep resistance.Two distinct mechanisms associated withγ'gbparticles governed the formation of the serrations at GBs.Owing to the stronger dragging effect of grain boundary junctions in fine-grained regions,the amplitude and wavelength of serrations in these regions were smaller than those in coarse-grained regions.Moreover,the formation of serrations exhibited a strong dependence on the inherent properties of the GBs.The random high-angle grain boundaries(HAGBs)with misorientation angles in the range of 30-59°tended to become serrated more easily during SHT due to their high mobility and the accelerated precipitation ofγ'gbparticles at them.Low-ΣHAGBs and low-angle GBs were not prone to form serrations.In particular,serration formation was completely inhibited atΣ3 twin boundaries due to their extremely low mobility and the absence ofγ'gbparticles.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.52001066 and 21805039)the Natural Science Foundation of Fujian Province(Grant Nos.2023J01500 and2021J01157)Fuzhou Science and Technology Project(Grant No.2024-Y-001)。
摘要Although lithium metal has been regarded as an ideal anode material for high-energy-density batteries,its practical applications remain hindered by many serious challenges.Three-dimensional(3D)porous Cu current collectors demonstrate potential in ensuring uniform Li deposition.However,notable drawbacks of 3D Cu collectors—such as poor lithophilic properties,unordered interface microstructure,and insufficient surface area—still hamper their effectiveness.Herein,a 3D porous Cu skeleton with lithiophilic Cu0.64Zn0.36 alloy“skins”and curvature boundaries(CuZn@Cu)is developed.In CuZn@Cu,the Cu0.64Zn0.36 alloy layer endows the collector with good lithium affinity and low surface reaction activation energy,thereby promoting uniform lithium deposition.In addition,the abundant curvature boundaries in CuZn@Cu regulate the distributions of the electric field and lithium ion flux,guiding the selective nucleation and growth of lithium.Consequently,compact and dendrite-free lithium deposition is achieved on CuZn@Cu,and the CuZn@Cu collector enables a high average Coulombic efficiency of 98.15%in 1000 cycles.The lithium symmetric cells with the CuZn@Cu exhibit a long cycle life of more than 1400 h at1 m A cm-2.
基金financially supported by the National Natural Science Foundation of China(52463025 and 52062035)the Major Discipline Academic and Technical Leaders Training Program of Jiangxi Province(20213BCJ22056)+2 种基金Jiangxi Province Key Laboratory of Lithium-ion Battery Materials and Application(2024SSY05202)the Guangdong Basic and Applied Basic Research Foundation(2025A1515010442)Basic Research Program of Shenzhen(JCYJ20240813103559008)。
摘要Grain boundaries(GBs),particularlyΣ7 coincidence site lattice(CSL)defects experimentally observed in MXenes,significantly influence their performance as lithium-ion battery(LIB)anodes.This work systematically investigates the impact ofΣ7 GBs on MXene electrochemical properties,with a focus on rate capability.The results indicated thatΣ7 GB formation is thermodynamically favored in Ti2C,Nb2C,and Mo2C MXenes compared to other M2C compositions,with stability further enhanced by oxygen and sulfur surface functionalization.These GBs induce substantial geometric distortions that reduce surface charge localization while enhancing electrical conductivity in Ti2CO2.The altered electronic structure at GB sites weakens lithium adsorption strength without promoting lithium dendrite formation.Furthermore,diffusion kinetics calculations reveal significantly reduced lithium diffusion barriers atΣ7 GBs in Ti2C,Mo2C,and Mo2CS2compared to pristine materials.Mechanistic analysis attributes this enhancement to diminished charge localization at GB regions,which generates a“charge pool”effect—a zone of uniformly distributed free charge observed in Ti2C and Mo2C.This charge pool not only facilitates ultra-low lithium diffusion barriers(as low as 11 meV in M2C at 0.1 V vs.Li+/Li)but also enhances potential responsiveness of diffusion kinetics.Our findings establish the intentional introduction ofΣ7 GBs as an effective strategy for designing high-rate MXene anodes.This work provides fundamental insights into GB-enhanced electrochemical mechanisms in 2D materials,offering crucial theoretical guidance for the design of high-rate anode materials.
基金supported by the National Key R&D Program of China(Grant No.2024YFA1611204)the National Natural Science Foundation of China(Grant Nos.12274437 and 12574137)+1 种基金the Chinese Academy of Sciences(CAS)Project for Young Scientists in Basic Research(Grant No.YSBR-084)the CAS Youth Interdisciplinary Team and the Chinese Academy of Sciences(Contract No.JZHKYPT-2021-08)。
摘要Bloch points and transverse walls can serve as topological boundaries within a magnetic domain wall.Here,we investigate the stability and dynamics of these topological boundaries for potential spintronic applications.Using micromagnetic simulations,we reveal the coexistence regimes of Bloch points and transverse walls in thin films with perpendicular magnetic anisotropy.An external in-plane field enables reversible transitions between these states through boundary-mediated Bloch point nucleation and annihilation processes.Under spin-transfer torque,transverse walls exhibit transverse drift and deformation.In contrast,Bloch points move strictly along the domain wall without transverse deflection and feature a Walker breakdown threshold an order of magnitude higher than conventional domain walls.Our findings establish a device concept where binary states correspond to in-plane magnetization orientations separated by mobile topological boundaries,offering new opportunities for spintronic architectures.
摘要Traditional oilfields face increasing extraction challenges, primarily due to reservoir quality degradation and production decline, which are further exacerbated by volatile international crude oil prices—illustrated by Brent Crude’s trajectory from pandemic-induced negative pricing to geopolitically driven surges exceeding USD 100 per barrel. This study addresses these complexities through an integrated methodological framework applied to medium-permeability sandstone reservoirs in the Xinjiang oilfield by combining advanced numerical simulations with multivariate regression analysis. The methodology employs Latin Hypercube Sampling (LHS) to stratify geological parameter distributions and constructs heterogeneous reservoir models using Petrel software, rigorously validated through historical production data matching. Production forecasting integrates numerical simulation and Decline Curve Analysis (DCA), while investment estimation utilizes Ordinary Least Squares (OLS) regression to correlate engineering parameters with drilling and completion costs. Economic evaluation incorporates Discounted Cash Flow (DCF) modeling and breakeven analysis, establishing techno-economic boundaries via oil price sensitivity analysis ranging from USD 40 to 90 per barrel. Visualization tools, including 3D heatmaps, delineate nonlinear interactions among engineering, geological, and investment datasets under economic constraints. Key findings demonstrate that for the target reservoirs, as oil prices increase from USD 40 to USD 90 per barrel, the minimum economic thickness threshold decreases from approximately 5.7 m to about 2.5 m, with model prediction errors consistently below 25% across validation datasets. This framework provides scientifically grounded decision support for optimizing capital allocation and offers actionable insights to enhance undeveloped hydrocarbon development planning amid market uncertainty. Ultimately, it supports national energy security through technically robust and economically viable resource exploitation strategies.
基金funded by the National Natural Science Foundation of China (Grant NO. 42001231, 42501324)the Natural Science Foundation of Hubei Province (Grant NO. 2024AFB102)the China Scholarship Council
摘要Rapid urban expansion in mountainous cities exacerbates ecological fragility and intensifies tensions between development and environmental sustainability.Achieving a dynamic balance between ecological protection and urban growth boundaries(UGBs)is therefore essential.However,existing UGB delineation methods rarely account for the unique ecological indicators and spatial complexities of mountain regions,limiting their effectiveness in guiding sustainable land use planning.To address this gap,we propose a framework that integrates ecological constraints(ECs)into the PLUS model for UGB delineation in mountainous cities.Key ecological indicators are systematically evaluated and embedded as model constraints,while mathematical morphology techniques are applied to optimize UGB boundaries.Using Chongqing,a representative mountainous city in China,as a case study,we identified 1,641 km²of EC zones.Results indicate that soil and water conservation,water retention,and biodiversity maintenance are the primary ecosystem service functions in mountainous urban settings.Validation of the PLUS model demonstrated robust simulation performance(overall accuracy=0.86,Kappa=0.79,FoM=0.34).Elevation,residential areas,and water bodies were identified as the main drivers of urban expansion.The EC-based approach yielded 1,280 km²of UGBs—slightly less than the 1,305 km²projected under the natural growth scenario—effectively curbing encroachment into ecologically sensitive areas while accommodating urban growth and reducing landscape fragmentation.The proposed framework provides practical guidance for sustainable land use planning and offers transferable insights for UGB delineation in other ecologically fragile mountainous cities.
基金supported by the project(MAD2DCM)-IMDEA Materials funded by Comunidad de Madrid and by the Recovery,Transformation and Resilience Plan and by NextGenerationEU from the European Union.
摘要Slip transfer/blocking at grain boundaries was studied in a WE43 Mg alloy through a combined experimental approach involving electron backscatter diffraction(EBSD),slip trace modified lattice rotation analysis(ST-MLRA),and diffraction contrast tomography(DCT).Slip(basal slip)transfer occurred exclusively across low-angle grain boundaries(<20°),while slip blocking was dominant(80.4%),and slip to twin transfer typically occurred at higher misorientation angles.Among the geometric descriptors analyzed,low values ofκ(angle between slip directions),ψ(angle between slip plane normals),andθ(angle between the traces of the incoming and outgoing slip planes with the GB plane)were consistently associated with the slip transfer cases.Notably,slip transfer events were tightly gathered in the high-compatibility region where both the Luster-Morris parameter(m)and the LRB factor exceeded 0.9,suggesting that both serve as robust criteria for basal slip transmission across grain boundaries.The integration of 3D grain morphology with actual slip system identification provides a comprehensive framework for evaluating intergranular deformation in Mg alloys.
基金funded by the National Natural Science Foundation of China(NNSFC)under Grant Numbers 42322408,42188101,and 42441809Additional support was provided by the Climbing Program of the National Space Science Center(NSSC,Grant No.E4PD3005)as well as the Specialized Research Fund for State Key Laboratories of China.
摘要A large-scale view of the magnetospheric cusp is expected to be obtained by the Soft X-ray Imager(SXI)onboard the Solar wind Magnetosphere Ionosphere Link Explorer(SMILE).However,it is challenging to trace the three-dimensional cusp boundary from a two-dimensional X-ray image because the detected X-ray signals will be integrated along the line of sight.In this work,a global magnetohydrodynamic code was used to simulate the X-ray images and photon count images,assuming an interplanetary magnetic field with a pure Bz component.The assumption of an elliptic cusp boundary at a given altitude was used to trace the equatorward and poleward boundaries of the cusp from a simulated X-ray image.The average discrepancy was less than 0.1 RE.To reduce the influence of instrument effects and cosmic X-ray backgrounds,image denoising was considered before applying the method above to SXI photon count images.The cusp boundaries were reasonably reconstructed from the noisy X-ray image.
基金founded by the National Natural Science Foundation of China under grant numbers 52375325,52105410Anhui Provincial Natural Science Foundation under grant number 2308085ME164.
摘要Enhancing the strength of nanotwinned aluminum(Al)is essential for the development of nextgeneration high-end chip technology.To better understand the detwinning behavior of nanotwinned Al under conditions with no resolved shear stress acting on the twin boundaries,we conducted molecular dynamics simulations of uniaxial tensile deformation in nanotwinned single-crystal Al at room temperature.Detwinning is observed only when the twin boundary spacing is 7.01 A.At larger spacings,twin boundaries remain parallel to the loading direction,with no rotation or bending,indicating negligible migration.Detwinning is triggered by localized stress from dislocation interactions,with detwinning fraction evolving synchronously with dislocation density.In the absence of detwinning,dislocations inclined toward twin boundaries interact frequently with them,leading to a loss of coherency that intensifies with increasing twin boundary spacing.These findings enhance understanding of the plastic deformation mechanisms in nanotwinned metals at very small twin boundary spacings,supplement the conventional understanding of twin boundary stability,and therefore suggest potential pathways for designing Al-based nanostructures with enhanced stability or controllable plastic deformation.
基金supported by The Youth Innovation Team of Shaanxi Universities and The Innovation and Entrepreneurship Team of Special Support Program for‘Sanqin’Talentthe Special Support Program for High-level Talents of Shaanxi Province(No.2020-44)the China Postdoctoral Science Foundation(2022M723884)。
摘要Ferrite-carbon composites effectively absorb electromagnetic(EM)waves via coupled mechanisms.However,the dynamic evolution of intrinsic polarization and magnetic loss mechanisms following interfacial coupling has long been overlooked,impeding broadening of the ultra-broadband EM wave absorption performance in heterostructures.Herein,via surface ligand modulation,in situ growth of 0D Fe3O4quantum dots(QDs)on the surface of 1D carbon nanotubes triggers grain boundary coupling.The energy rebalancing effect at the interface induces an extreme charge rearrangement within the Fe3O4QDs.This rearrangement enhances dipole orientation hysteresis and charge accumulation,resulting in charge and interfacial polarization losses.Meanwhile,for subcritical Fe3O4QDs,short-range magnetic resonance and magnetic exchange-triggered magnetic resonance transfer synergistically enhance the magnetic loss.Through charge rearrangement/magnetic resonance induced by0D/1D grain boundary coupling,an effective bandwidth of nearly 10 GHz is achieved at a minimal thickness of 2 mm,covering the X and Ku bands.This strategy provides an effective paradigm and novel theoretical insights for ultra-broadband electromagnetic wave absorption applications.
基金supported by the National Natural Science Foundation of China(No.22509119)the China Postdoctoral Science Foundation(No.2024M761941).
摘要Triple phase boundary(TPB)and pore structure in the cathode catalyst layer(CCL)play vital roles in the uti-lization of Pt-based catalyst in proton exchange membrane fuel cells(PEMFCs).The excellent TPBs on the catalyst surface and pore structure should be able to increase oxygen transport channels while maintaining proton transport,and simultaneously facilitate the efficient removal of product water.Here,we design a precision-regulated structure for the Pt/ionomer interfacial and pores using a gas breakthrough method driven by high evolution pressure.The highly efficient oxygen transport channels are created through enhanced TPB accessibility and opened pore structure in CCLs,leading to an 11% improvement in PEMFC performance at an appropriate HER current density and bubble intensity conditions.The proposed strategy provides a direction to tune the Pt/ionomer interface and improve the catalytic activity of Pt in membrane electrode assembly(MEA).
基金Major Project of the National Social Science Fund of China (Grant No. 25&ZD189)Research on the Practical Pathways of High-Quality New Energy Development and Energy System Transition。
摘要In an era marked by unprecedented digital transformation across the glboe, industries are experiencing profound shifts in their operational paradigms and competitive dynamics. However, existing research has predominantly focused on the internal impacts of corporate digital transformation, overlooking the external effects it generates, particularly the spillover effects within vertical supply chain relationships. This study provides an in-depth examination of how corporate digital transformation affects the governance efficiency of upstream and downstream supply chain partners and explores the underlying transmission mechanisms. The research reveals that corporate digital transformation has a dual impact on the governance efficiency of upstream and downstream supply chain partners. Furthermore, the study demonstrates that resource endowment conditions across different industries and regions significantly influence both the transmission mechanisms and outcomes of digital transformation. Finally, this study proposes corresponding managerial implications based on the theoretical analysis.
摘要William Faulkner's A Rose for Emily has long been interpreted as an allegory of the conflict between Southern tradition and modern civilization. This paper attempts to examine Emily Grierson from the dual perspectives of "spatial boundaries" and "cultural reproduction", exploring how she is constructed by the old Southern order as a "monument" and how she moves toward both cultural and physical death under the penetration of Northern modernity.The study finds that Emily's house is not merely a physically enclosed entity but constitutes a superimposition of three boundaries: physical, social, and bodily. Her poisoning of the Northern suitor, Homer Barron, is not simply a matter of personal love or hatred, but an extreme response triggered by the complete failure of the “cultural reproduction” mechanism when Southern aristocratic culture encounters Northern capitalist values. Through this interpretation, this paper seeks to reveal Faulkner's ambivalent attitude toward the fate of the South-mourning the passing of tradition while keenly perceiving its inherent decay and violence.
基金National Natural Science Foundation of China(52065036,52365018)Natural Science Foundation of Gansu(23JRRA760,24JRRA175,25JRRA060)+1 种基金Hongliu Outstanding Youth Foundation of Lanzhou University of TechnologyLeading Innovative Talents Project of Changzhou(CQ20210111)。
摘要To elucidate the deformation mechanisms ofγ-TiAl,the nanoindentation experiments and crystal plasticity finite element(CPFE)simulation were employed to investigate the effects of crystal orientations and GBs on the mechanical properties ofγ-TiAl alloys.A crystal plasticity constitutive model was developed,and load-displacement curves,hardness,and Young's modulus were obtained for both single grains and GBs inγ-TiAl alloys.Based on the aforementioned model,this study investigated the distribution patterns of surface morphology around the indentation sites of individual grain and GBs.It also analyzed the cumulative shear strain distribution,slip system activation,and the interaction between GBs and dislocation slip for various crystal orientations.The results indicate that the mechanical response and pileup behavior exhibit significant anisotropy due to the interplay among the indenter geometry,material slip systems,and cumulative shear strain distribution.Moreover,the interaction between GBs and dislocation slip substantially alters dislocation distribution,thereby influencing material flow and playing a critical role in the mechanical response and plastic deformation of the material.
基金supported by the National Natural Science Foundation of China(Grant No.11704301)the Natural Science Basic Research Plan in Shaanxi Province of China(Program No.2022JM212)supported by the Ministry of Science and Higher Education of the Russian Federation(FSEG-2023-0016).
摘要High-performance lead-free piezoelectric single crystals are urgently needed for next-generation actuators and transducers.In this study,we reveal that a compositionally driven tetragonal-pseudocubic(T-PC)phase boundary,in conjunction with an octahedral order-disorder tilting transition,significantly enhances the piezoelectric response in Nb5+-substitution(Bi0.48Na0.425K0.055Ba0.04)(Ti0.98Nb0.02)O3(BNKBT-2Nb)single crystals.The crystal achieves an outstanding piezoelectric coefficient of d33=662 pC/N at room temperature.In situ X-ray diffraction confirms an electric field-induced transition from the PC to T phase.Atomic-resolution HADDF-STEM analysis reveals an increase in the c/a ratio(c/a>1.01)on the local scale and ordered octahe-dral tilting of the a0a0c+type driven by the poling field.The single crystals exhibit excellent piezoelectric per-formance over a broad temperature range,achieving a peak d33 of 920 pC/N at approximately 92℃.Furthermore,the polar states exhibit a pronounced frequency dependence near the depolarization temperature.These findings provide critical insight into the structure-property relationship and offer a promising pathway for designing advanced lead-free piezoelectric crystals for functional electromechanical applications.
摘要On February 8,2025,a remote area in the Caribbean Sea was rocked by a large MW7.6(USGS,2025) earthquake,centered 209 km SSW of Georgetown,the capital of the Cayman Islands,and the largest city(population~41 000) of the British Overseas Territories(Figure 1).The earthquake was significant due to its large magnitude,potential regional impact,and the possibility of generating a tsunami.
基金financial supports from the National Natural Science Foundation of China(Nos.52301164,52271107,52371121)the Natural Science Foundation of Shandong Province,China(No.ZR2021ME241)the Natural Science Foundation of Liaoning Province,China(No.2025-BS-0365)。
摘要Grain boundary(GB)characteristics in relation to texture development were investigated in an extruded Mg−Zn−Gd alloy subjected to isothermal annealing at 400°C for 5−155 min.Quasi in-situ electron backscatter diffraction(EBSD)was employed to analyze grain growth(GG),grain rotation,and GB character evolution.GG was found to proceed via two distinct mechanisms:nucleation at triple junction followed by subsequent growth,and GB migration governed by the Burke–Turnbull mechanism.The rotation angle of(0001)basal pole ranged from 31°to 40°,contributing to the observed non-basal texture.Misfit strain(δ)associated with various coincidence site lattice(CSL)boundaries was evaluated,showing that the length fractions forΣ7,Σ13b andΣ45a boundaries decreased in the isothermal annealing due to their higherδvalues,while those forΣ9,Σ21a andΣ43b boundaries increased.Grain growth kinetics was evaluated after isothermal annealing and grain growth exponent was also determined.Collectively,these findings demonstrate that GB characteristics significantly influence texture evolution by promoting energetically favorable boundary configurations.
基金Supported by the National Natural Science Foundation of China(U2442204 and 42475014)Science&Technology Fundamental Resources Investigation Program(2025FY101505)+1 种基金Program for Innovation and Development of China Meteorological Administration(CXFZ2026J021)State Key Laboratory of Severe Weather Meteorological Science and Technology(LaSW)(2025QZA08)。
摘要Quasi-linear convective systems(QLCSs)frequently produce severe weather in North China,with multiple QLCSs often forming successively within a short period.However,their formation mechanisms under such conditions remain unclear.This study investigated the formation mechanisms of three successive QLCSs that affected Beijing and its vicinity from the afternoon to evening on 12 June 2022,using in-situ and remote sensing observations as well as high-resolution Weather Research and Forecasting model simulations with a 9-,3-,1-km nested grid.The event occurred within the trough of a mature cold vortex,which induced dry westerlies over the western mountainous areas and moist southerlies over the eastern plains of North China.Diurnal solar heating further intensified the zonal thermal and moisture contrasts between the eastern and western domains.Therefore,a southwest-northeast-oriented dryline with a dynamical confluence persisted along the eastern Taihang Mountains.To the west of the dryline,sustained boundary layer turbulent activities eliminated convective inhibition.Meanwhile,episodic weak cold advections induced by the cold vortex modestly increased the convective available potential energy over the northern mountains,providing energy for the generation of convective cell clusters(CCs).These sequentially initiated CCs propagated southeastward under the steering airflow,with distinct outflow boundaries forming at their leading edges.Crucially,the continuous merging between the southeastward-moving CC outflow boundaries and the quasi-stationary dryline strengthened the low-level convergence both in depth and intensity along segments of the dryline zone.The intensified dynamical lifting ultimately triggered convection along these segments,corresponding to the successive formation of three QLCSs.This paper highlights the synergistic effects of cold-vortex forcing,complex-terrain modulation,and dryline-outflow boundary interactions on the formation of organized convection over mountainous areas.The findings benefit the forecasting and early warning of similar severe convective events in North China.
基金support from Interdisciplinary Research Project for Young Teachers of USTB Fundamental Research Funds for the Central Universities(Grant no.FRF-IDRY-23-030).
摘要Solute atoms and precipitates significantly influence the mechanical properties of Mg alloys.Previous studies have mainly focused on the segregation behaviors of Mg alloys after annealing.In this study,we investigated the segregation behaviors of an Mg-RE alloy under deformation.We found that the enrichment of solute atoms occurred in{101-1}compressive twin boundaries under compression at 298 K without any annealing in an Mg-RE alloy by scanning transmission electron microscopy and energy-dispersive X-ray analysis.The segregated solutes and precipitates impeded the twin growth,partially contributing to the formation of small-sized{101-1}compressive twins.This research indicates the twin boundaries can be strengthened by segregated solutes and precipitates formed under deformation at room temperature.