期刊文献+
任意字段
题名或关键词
题名
关键词
摘要
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息
共找到1篇文章
< 1 >
每页显示 20 50 100
已选0条
引用分析
参考文献
引证文献
 统计分析
检索结果
已选文献
显示方式：
Development of high-performance and low-cost BCC type hydrogen storage alloys from FeV80 master alloy refined by cerium 认领 引用 被引量：1
1
作者 Xiaoxuan Zhang Yang Liu +7 位作者 Huazhou Hu Songsong Li Ruizhu Tang Chenyu Li Yuehai Li Luocai Yi Chuanming Ma Qingjun Chen 《Journal of Rare Earths》 SCIE EI CAS CSCD 2026年第3期860-868,I0005,共9页
The use of industrial-grade FeV80 master alloy in the synthesis of solid hydrogen storage alloys,rather than pure V,offers substantial economic advantages.However,FeV80 master alloy contains about 5 wt%of Al,Si,O and ... The use of industrial-grade FeV80 master alloy in the synthesis of solid hydrogen storage alloys,rather than pure V,offers substantial economic advantages.However,FeV80 master alloy contains about 5 wt%of Al,Si,O and other impurities,which adversely affect the hydrogen storage performance.In this work,the effective dehydrogenation capacity of Ti31Cr35(FeV80-Ce)34 alloy prepared by Ce pre-refining FeV80master alloy process reaches 2.42 wt%.By comparing the phase distribution and composition before and after pre-refining,Ce pre-refining significantly reduces the presence of Al and O,inhibits the formation of Ti-rich phase and the generation of SiO2 in Ti31Cr35(FeV80-Ce)34 alloys.By X-ray photoelectron spectroscopy(XPS)analysis,the metal content of the matrix element increases and the binding energy decreases after Ce pre-refining.The slope factor of pressure-composition-temperature(PCT)curve decreases from 0.60 to 0.48 after Ce pre-refining,which improves the dehydrogenation perfo rmance.The dehydrogenation activation energy and enthalpy change of the Ti31Cr35(FeV80-Ce)34 alloy before and after pre-refining are also calculated using kinetics and PCT curves.Furthermore,the Ti31Cr35(FeV80-Ce)34 alloy exhibits a capacity retention of 81%after 200 cycles,surpassing reported values for FeV80-based hydrogen storage alloys.It provides a new idea for developing low-cost and high-capacity FeV80-base hydrogen storage alloys. 展开更多
关键词 Hydrogen storage alloys Rare earths FeV80 alloy pre-refining Kinetics Cycling properties
暂未订购 下载PDF
已选0条
引用分析
参考文献
引证文献
 统计分析
检索结果
已选文献
上一页 1 下一页 到第 页
在线咨询 使用帮助 返回顶部 意见反馈