Although numerousfindings show that people experience both positive and negative experiences with regards to solitude,the relationship between solitude capacity and emotional experience remains unclear.The current stud...Although numerousfindings show that people experience both positive and negative experiences with regards to solitude,the relationship between solitude capacity and emotional experience remains unclear.The current study investigated the extent to which emotion regulation may play a suppressive role in the relationship between solitude capacity and emotional experience.Questionnaires on solitude capacity,emotion regulation,and emotional experience were completed by a sample of Chinese college students(n=844;432 females;Meanage=19.79 years,SD=1.43 years).The results of the indirect effect test showed that cognitive reappraisal suppresses the prediction of solitude capacity on positive emotions,while the solitude capacity prediction of negative emotions was suppressed by both cognitive reappraisal and expressive suppression.This suggests that solitude capacity does not predict emotional experience directly,but instead is realized through an antagonistic system consisting of adaptive and nonadaptive emotion regulation strategies.Thesefindings provide cross-sectional empirical support for the ecological niche hypothesis of solitude,and are of theoretical significance in clarifying the role of internal mechanisms of solitude capacity on the human emotional experience.展开更多
Li metal is widely recognized as the desired anode for next-generation energy storage,Li metal batteries,due to its highest theoretical capacity and lowest potential.Nonetheless,it suffers from unstable electrochemica...Li metal is widely recognized as the desired anode for next-generation energy storage,Li metal batteries,due to its highest theoretical capacity and lowest potential.Nonetheless,it suffers from unstable electrochemical behaviors like dendrite growth and side reactions in practical application.Herein,we report a highly stable anode with collector,Li5Mg@Cu,realized by the melting-rolling process.The Li5Mg@Cu anode delivers ultrahigh cycle stability for 2000 and 1000 h at the current densities of 1 and 2 mA cm-2,respectively in symmetric cells.Meanwhile,the Li5Mg@Cu|LFP cell exhibits a high-capacity retention of 91.8% for 1000 cycles and 78.8% for 2000 cycles at 1 C.Moreover,we investigate the suppression effects of Mg on the dendrite growth by studying the performance of LixMg@Cu electrodes with different Mg contents(2.0-16.7 at%).The exchange current density,surface energy,Li+diffusion coefficient,and chemical stability of LixMg@Cu concretely reveal this improving suppression effect when Mg content becomes higher.In addition,a Mg-rich phase with“hollow brick”morphology forming in the high Mg content LixMg@Cu guides the uniform deposition of Li.This study reveals the suppression effects of Mg on Li dendrites growth and offers a perspective for finding the optimal component of Li-Mg alloys.展开更多
Zn-I2 batteries have emerged as promising next-generation energy storage systems owing to their inherent safety,environmental compatibility,rapid reaction kinetics,and small voltage hysteresis.Nevertheless,two crit...Zn-I2 batteries have emerged as promising next-generation energy storage systems owing to their inherent safety,environmental compatibility,rapid reaction kinetics,and small voltage hysteresis.Nevertheless,two critical challenges,i.e.,zinc dendrite growth and polyiodide shuttle effect,severely impede their commercial viability.To conquer these limitations,this study develops a multifunctional separator fabricated from straw-derived carboxylated nanocellulose,with its negative charge density further reinforced by anionic polyacrylamide incorporation.This modification simultaneously improves the separator’s mechanical properties,ionic conductivity,and Zn2+ion transfer number.Remarkably,despite its ultrathin 20μm profile,the engineered separator demonstrates exceptional dendrite suppression and parasitic reaction inhibition,enabling Zn//Zn symmetric cells to achieve impressive cycle life(>1800 h at 2 m A cm-2/2 m Ah cm-2)while maintaining robust performance even at ultrahigh areal capacities(25 m Ah cm-2).Additionally,the separator’s anionic characteristic effectively blocks polyiodide migration through electrostatic repulsion,yielding Zn-I2 batteries with outstanding rate capability(120.7 m Ah g-1at 5 A g-1)and excellent cyclability(94.2%capacity retention after 10,000 cycles).And superior cycling stability can still be achieved under zinc-deficient condition and pouch cell configuration.This work establishes a new paradigm for designing high-performance zinc-based energy storage systems through rational separator engineering.展开更多
Lithium-oxygen(Li-O2)batteries are perceived as a promising breakthrough in sustainable electrochemical energy storage,utilizing ambient air as an energy source,eliminating the need for costly cathode materials,and of...Lithium-oxygen(Li-O2)batteries are perceived as a promising breakthrough in sustainable electrochemical energy storage,utilizing ambient air as an energy source,eliminating the need for costly cathode materials,and offering the highest theoretical energy density(~3.5 k Wh kg-1)among discussed candidates.Contributing to the poor cycle life of currently reported Li-O2cells is singlet oxygen(1O2)formation,inducing parasitic reactions,degrading key components,and severely deteriorating cell performance.Here,we harness the chirality-induced spin selectivity effect of chiral cobalt oxide nanosheets(Co3O4NSs)as cathode materials to suppress 1O2in Li-O2batteries for the first time.Operando photoluminescence spectroscopy reveals a 3.7-fold and 3.23-fold reduction in 1O2during discharge and charge,respectively,compared to conventional carbon paperbased cells,consistent with differential electrochemical mass spectrometry results,which indicate a near-theoretical charge-to-O2ratio(2.04 e-/O2).Density functional theory calculations demonstrate that chirality induces a peak shift near the Fermi level,enhancing Co 3d-O 2p hybridization,stabilizing reaction intermediates,and lowering activation barriers for Li2O2formation and decomposition.These findings establish a new strategy for improving the stability and energy efficiency of sustainable Li-O2batteries,abridging the current gap to commercialization.展开更多
The built-up effect of inorganic compounds containing more active metal ions, such as Ca^2+ , Al^3+ , Cu^2+ , and Zn^2+ , as additives adding to phosphorus-containing flame retarding systems in suppression of smok...The built-up effect of inorganic compounds containing more active metal ions, such as Ca^2+ , Al^3+ , Cu^2+ , and Zn^2+ , as additives adding to phosphorus-containing flame retarding systems in suppression of smoke was studied. The data presented herein suggested that the amount of smoke in the burning process can be better suppressed after the cotton fabric finishing with built-up system was burnt. Some general principles were identified, and the likely causes of the observed effects were analyzed according to test data.展开更多
The unavoidable dendrite growth and shuttle effect have long been stranglehold challenges limiting the safety and practicality of lithium-sulfur batteries.Herein,we propose a dual-action strategy to address the lithiu...The unavoidable dendrite growth and shuttle effect have long been stranglehold challenges limiting the safety and practicality of lithium-sulfur batteries.Herein,we propose a dual-action strategy to address the lithium dendrite issue in stages by constructing a multifunctional surface-negatively-charged nanodiamond layer with high ductility and robust puncture resistance on polypropylene (PP) separator.The uniformly loaded compact negative layer can not only significantly enhance electron transmission efficiency and promote uniform lithium deposition,but also reduce the formation of dendrite during early deposition stage.Most importantly,under the strong puncture stress encountered during the deterioration of lithium dendrite growth under limiting current,the high ductility and robust puncture resistance(145.88 MPa) of as-obtained nanodiamond layer can effectively prevent short circuits caused by unavoidable lithium dendrite.The Li||Li symmetrical cells assembled with nanodiamond layer modified PP demonstrated a stable cycle of over 1000 h at 2 mA cm-2with a polarization voltage of only 29.3 mV.Additionally,the negative charged layer serves as a physical barrier blocking lithium polysulfide ions,effectively mitigating capacity attenuation.The improved cells achieved a capacity decay of only 0.042%per cycle after 700 cycles at 3 C,demonstrating effective suppression of dendrite growth and capacity attenuation,showing promising prospect.展开更多
Current-voltage electrical characteristics of Er silicide/Si(001) nanocontacts are measured in situ in a scanning tunneling microscopy system. Introduced as a new technique to suppress surface leakage conduction on...Current-voltage electrical characteristics of Er silicide/Si(001) nanocontacts are measured in situ in a scanning tunneling microscopy system. Introduced as a new technique to suppress surface leakage conduction on Si(001),a silver wetting layer is evaporated onto the substrate surface kept at room temperature with Er Si2 nanoislands already existing. The effects of the silver layer on the current-voltage characteristics of nanocontacts are discussed.Our experimental results reveal that the silver layer at coverage of 0.4–0.7 monolayer can suppress effectively the current contribution from the surface conduction path. After the surface leakage path of nanocontacts is obstructed, the ideality factor and the Schottky barrier height are determined using the thermionic emission theory, about 2 and 0.5 eV, respectively. The approach adopted here could shed light on the intrinsic transport properties of metal-semiconductor nanocontacts.展开更多
BACKGROUND: Stereo-tactic radiation therapy (SRT) is widely used to treat intracranial diseases, but some patients suffered from radiation induced brain edema after SRT. Once radiation induced brain edema occurs, t...BACKGROUND: Stereo-tactic radiation therapy (SRT) is widely used to treat intracranial diseases, but some patients suffered from radiation induced brain edema after SRT. Once radiation induced brain edema occurs, the treatment is quite difficult, and it always leads to a poor outcome. Dexamethasone has certain therapeutic effect on traumatic brain edema, but the biological mechanism is still unclear. OBJECTIVE : To observe the effect of dexamethasone on the neutrophil expression of CD18.DESIGN : A randomized control observation.SETTING: Changhai Hospital of the Second Military Medical University of Chinese PLA. MATERIALS : The experiment was carried out in Changhai Hospital of the Second Military Medical University of Chinese PLA from January 1999 to December 1999. Twenty SD rats (male and female each in half) weighing (250±50) g were used. METHODS: Twenty SD rats were divided into four groups at random. ① Blank control group (n=5): The rats were not treated without dexamethasone or irradiation;② Irradiation group (n=5): The rats were given irradiation but no dexamethasone treatment; ③ Irradiation+1 mg/kg dexamethasone group (n=5); The rats were treated with irradiation and dexamethasone of 1 mg/kg; ④Irradiation+5 mg/kg dexamethasone group (n=5): The rats were treated with irradiation and dexamethasone of 5 mg/kg. The heads of the rats were irradiated with 10 MeV X-ray (30 Gy), and brain tissue was removed after 2 weeks to observe the pathological changes. Blood samples were taken from the carotid artery, gradient centrifugation was used, and neutrophile layer was obtained, the level of neutrophile expression of CD18 mRNA and quantity of membrane proteins in blood were detected with Northern blot and flow cytometry respectively. MAIN OUTCOME MEASURES: ① Blood cell count; ② Pathological results; ③ level of neutrophile expression of CD18 mRNA and quantity of membrane proteins. RESULTS : All the 20 SD rats were involved in the analysis of results without deletion. At 2 weeks after irradiation, obvious cell injury could be observed under light microscope. The level of neutrophile expression of CD18 mRNA and quantity of membrane proteins in blood were obviously increased, but the severity of cell injury was relieved in the irradiation+1 and 5 mg/kg dexamethasone groups, and the CD18 expression was markedly suppressed (P 〈 0.05), and the suppression was more obvious in the irradiation+5 mg/kg dexamethasone group than in the irradiation+1 mg/kg dexamethasone group (P 〈 0.01 ). CONCLUSION: Dexamethasone can reduce the radiation induced brain edema by inhibiting the expression of CD18.展开更多
This study examined how social desirability responses confound the relationship between gender and social media addiction.A total of 496 college student social media users(females=310,62.5%,mean age=20.15,SD=1.26)comp...This study examined how social desirability responses confound the relationship between gender and social media addiction.A total of 496 college student social media users(females=310,62.5%,mean age=20.15,SD=1.26)completed an online questionnaire on Social Media Addiction and Social Desirability.Mediation analysis revealed that females were at higher risk for social media addiction.On the other hand,the indirect effect of gender on social media addiction via social desirability is associated with lower social media addiction,which suggests that social desirability had a suppression effect on social media addiction associated with gender.ANOVA results showed that females reported higher social media addiction scores than males in the low social desirability group;in the high group,gender differences were insignificant.This study’s unique contribution is to suggest that females are at higher risk than males for developing addictive social media behaviors.Based on this finding,student social media safety interventions should be gender sensitive to the social desirability effect on females who may hide their true addiction as a result.展开更多
Developing multivalent-ion storage systems demands cathode materials that combine high structural adaptability with favorable orbital interactions to host sluggish,highly charged carriers such as Ca2+.Herein,a mult...Developing multivalent-ion storage systems demands cathode materials that combine high structural adaptability with favorable orbital interactions to host sluggish,highly charged carriers such as Ca2+.Herein,a multi-synergistic interlayer engineering strategy is proposed via Ca2+interlayer coordination.The pre-coordination of Ca2+ions establishes Mn-O-Ca bridges that not only expand the interlayer distance but also reshape the local orbital field of Mn,thereby stabilizing the high-valence Mn states and suppressing Jahn-Teller distortion.Defect-induced orbital reconfiguration simultaneously enhances electronic delocalization and interlayer polarity by creating localized charge imbalances at oxygen vacancies.As a result,efficient charge transfer and Ca2+diffusion are promoted,and more surface-active sites are exposed.Electrochemical evaluations reveal that Ca-MnO2exhibits significantly improved reversible capacity(~100 mA h g-1at 0.1 A g-1)and long-term cycling stability(1200 cycles at 1 A g-1),outperforming pristineδ-MnO2.Kinetic analysis through CV,GITT,and EIS demonstrates enhanced Ca2+diffusion coefficients and reduced polarization in the pre-intercalated material.These results demonstrate an orbital-coupled interlayer engineering route toward high-performance Mn-based hosts for nextgeneration multivalent batteries.展开更多
基金supported by grants from the Doctoral Research Project of Yan’an University(2003-205040349)the 2022 General Special Scientific Research Plan Project of the Shaanxi Provincial Department of Education(YDZZYB23-40)the Social Science Foundation of Shaanxi Province(2023P013 and 2024P028).
摘要Although numerousfindings show that people experience both positive and negative experiences with regards to solitude,the relationship between solitude capacity and emotional experience remains unclear.The current study investigated the extent to which emotion regulation may play a suppressive role in the relationship between solitude capacity and emotional experience.Questionnaires on solitude capacity,emotion regulation,and emotional experience were completed by a sample of Chinese college students(n=844;432 females;Meanage=19.79 years,SD=1.43 years).The results of the indirect effect test showed that cognitive reappraisal suppresses the prediction of solitude capacity on positive emotions,while the solitude capacity prediction of negative emotions was suppressed by both cognitive reappraisal and expressive suppression.This suggests that solitude capacity does not predict emotional experience directly,but instead is realized through an antagonistic system consisting of adaptive and nonadaptive emotion regulation strategies.Thesefindings provide cross-sectional empirical support for the ecological niche hypothesis of solitude,and are of theoretical significance in clarifying the role of internal mechanisms of solitude capacity on the human emotional experience.
基金supported by the Qingdao Jiuhuanxinyue New Energy Technology Co.,Ltd.the Guangdong Basic and Applied Basic Research Foundation(Grant No.2021B1515120071)+2 种基金the 21C Innovation Laboratory,Contemporary Amperex Technology Ltd.(Grant No.21C-OP-202112)the financial support from the Guangdong Basic and Applied Basic Research Foundation(Grant No.2024A1515011873)the Shenzhen Science and Technology Program(Grant No.JCYJ20220531095212027).
摘要Li metal is widely recognized as the desired anode for next-generation energy storage,Li metal batteries,due to its highest theoretical capacity and lowest potential.Nonetheless,it suffers from unstable electrochemical behaviors like dendrite growth and side reactions in practical application.Herein,we report a highly stable anode with collector,Li5Mg@Cu,realized by the melting-rolling process.The Li5Mg@Cu anode delivers ultrahigh cycle stability for 2000 and 1000 h at the current densities of 1 and 2 mA cm-2,respectively in symmetric cells.Meanwhile,the Li5Mg@Cu|LFP cell exhibits a high-capacity retention of 91.8% for 1000 cycles and 78.8% for 2000 cycles at 1 C.Moreover,we investigate the suppression effects of Mg on the dendrite growth by studying the performance of LixMg@Cu electrodes with different Mg contents(2.0-16.7 at%).The exchange current density,surface energy,Li+diffusion coefficient,and chemical stability of LixMg@Cu concretely reveal this improving suppression effect when Mg content becomes higher.In addition,a Mg-rich phase with“hollow brick”morphology forming in the high Mg content LixMg@Cu guides the uniform deposition of Li.This study reveals the suppression effects of Mg on Li dendrites growth and offers a perspective for finding the optimal component of Li-Mg alloys.
基金the financial support from the Natural Science Foundation of Jiangsu Province(BK20231292)the Jiangsu Agricultural Science and Technology Innovation Fund(CX(24)3091)+6 种基金the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX25_1429)the National Key R&D Program of China(2024YFE0109200)the Fundamental Research Funds for the Central Universities(No.2024300440)Guangdong Basic and Applied Basic Research Foundation(2025A1515011098)the National Natural Science Foundation of China(12464032)the Natural Science Foundation of Jiangxi Province(20232BAB201032)Ji'an Science and Technology Plan Project(2024H-100301)。
摘要Zn-I2 batteries have emerged as promising next-generation energy storage systems owing to their inherent safety,environmental compatibility,rapid reaction kinetics,and small voltage hysteresis.Nevertheless,two critical challenges,i.e.,zinc dendrite growth and polyiodide shuttle effect,severely impede their commercial viability.To conquer these limitations,this study develops a multifunctional separator fabricated from straw-derived carboxylated nanocellulose,with its negative charge density further reinforced by anionic polyacrylamide incorporation.This modification simultaneously improves the separator’s mechanical properties,ionic conductivity,and Zn2+ion transfer number.Remarkably,despite its ultrathin 20μm profile,the engineered separator demonstrates exceptional dendrite suppression and parasitic reaction inhibition,enabling Zn//Zn symmetric cells to achieve impressive cycle life(>1800 h at 2 m A cm-2/2 m Ah cm-2)while maintaining robust performance even at ultrahigh areal capacities(25 m Ah cm-2).Additionally,the separator’s anionic characteristic effectively blocks polyiodide migration through electrostatic repulsion,yielding Zn-I2 batteries with outstanding rate capability(120.7 m Ah g-1at 5 A g-1)and excellent cyclability(94.2%capacity retention after 10,000 cycles).And superior cycling stability can still be achieved under zinc-deficient condition and pouch cell configuration.This work establishes a new paradigm for designing high-performance zinc-based energy storage systems through rational separator engineering.
基金supported by Basic Science Research Program(Priority Research Institute)through the NRF of Korea funded by the Ministry of Education(2021R1A6A1A10039823)by the Korea Basic Science Institute(National Research Facilities and Equipment Center)grant funded by the Ministry of Education(2020R1A6C101B194)。
摘要Lithium-oxygen(Li-O2)batteries are perceived as a promising breakthrough in sustainable electrochemical energy storage,utilizing ambient air as an energy source,eliminating the need for costly cathode materials,and offering the highest theoretical energy density(~3.5 k Wh kg-1)among discussed candidates.Contributing to the poor cycle life of currently reported Li-O2cells is singlet oxygen(1O2)formation,inducing parasitic reactions,degrading key components,and severely deteriorating cell performance.Here,we harness the chirality-induced spin selectivity effect of chiral cobalt oxide nanosheets(Co3O4NSs)as cathode materials to suppress 1O2in Li-O2batteries for the first time.Operando photoluminescence spectroscopy reveals a 3.7-fold and 3.23-fold reduction in 1O2during discharge and charge,respectively,compared to conventional carbon paperbased cells,consistent with differential electrochemical mass spectrometry results,which indicate a near-theoretical charge-to-O2ratio(2.04 e-/O2).Density functional theory calculations demonstrate that chirality induces a peak shift near the Fermi level,enhancing Co 3d-O 2p hybridization,stabilizing reaction intermediates,and lowering activation barriers for Li2O2formation and decomposition.These findings establish a new strategy for improving the stability and energy efficiency of sustainable Li-O2batteries,abridging the current gap to commercialization.
摘要The built-up effect of inorganic compounds containing more active metal ions, such as Ca^2+ , Al^3+ , Cu^2+ , and Zn^2+ , as additives adding to phosphorus-containing flame retarding systems in suppression of smoke was studied. The data presented herein suggested that the amount of smoke in the burning process can be better suppressed after the cotton fabric finishing with built-up system was burnt. Some general principles were identified, and the likely causes of the observed effects were analyzed according to test data.
基金National Natural Science Foundation of China (Grant 52372083, 52173255)Opening Project of the Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials (JSKC24025)+1 种基金Special Funds for the Trans-formation of Scientific and Technological Achievements in Jiangsu Province(BA2023003)Collaborative Innovation Center for Advanced Micro/nanomaterials and Equipment (Co-constructed by Jiangsu Province and Ministry of Education)。
摘要The unavoidable dendrite growth and shuttle effect have long been stranglehold challenges limiting the safety and practicality of lithium-sulfur batteries.Herein,we propose a dual-action strategy to address the lithium dendrite issue in stages by constructing a multifunctional surface-negatively-charged nanodiamond layer with high ductility and robust puncture resistance on polypropylene (PP) separator.The uniformly loaded compact negative layer can not only significantly enhance electron transmission efficiency and promote uniform lithium deposition,but also reduce the formation of dendrite during early deposition stage.Most importantly,under the strong puncture stress encountered during the deterioration of lithium dendrite growth under limiting current,the high ductility and robust puncture resistance(145.88 MPa) of as-obtained nanodiamond layer can effectively prevent short circuits caused by unavoidable lithium dendrite.The Li||Li symmetrical cells assembled with nanodiamond layer modified PP demonstrated a stable cycle of over 1000 h at 2 mA cm-2with a polarization voltage of only 29.3 mV.Additionally,the negative charged layer serves as a physical barrier blocking lithium polysulfide ions,effectively mitigating capacity attenuation.The improved cells achieved a capacity decay of only 0.042%per cycle after 700 cycles at 3 C,demonstrating effective suppression of dendrite growth and capacity attenuation,showing promising prospect.
基金Supported by the National Natural Science Foundation of China under Grant No 11374058
摘要Current-voltage electrical characteristics of Er silicide/Si(001) nanocontacts are measured in situ in a scanning tunneling microscopy system. Introduced as a new technique to suppress surface leakage conduction on Si(001),a silver wetting layer is evaporated onto the substrate surface kept at room temperature with Er Si2 nanoislands already existing. The effects of the silver layer on the current-voltage characteristics of nanocontacts are discussed.Our experimental results reveal that the silver layer at coverage of 0.4–0.7 monolayer can suppress effectively the current contribution from the surface conduction path. After the surface leakage path of nanocontacts is obstructed, the ideality factor and the Schottky barrier height are determined using the thermionic emission theory, about 2 and 0.5 eV, respectively. The approach adopted here could shed light on the intrinsic transport properties of metal-semiconductor nanocontacts.
摘要BACKGROUND: Stereo-tactic radiation therapy (SRT) is widely used to treat intracranial diseases, but some patients suffered from radiation induced brain edema after SRT. Once radiation induced brain edema occurs, the treatment is quite difficult, and it always leads to a poor outcome. Dexamethasone has certain therapeutic effect on traumatic brain edema, but the biological mechanism is still unclear. OBJECTIVE : To observe the effect of dexamethasone on the neutrophil expression of CD18.DESIGN : A randomized control observation.SETTING: Changhai Hospital of the Second Military Medical University of Chinese PLA. MATERIALS : The experiment was carried out in Changhai Hospital of the Second Military Medical University of Chinese PLA from January 1999 to December 1999. Twenty SD rats (male and female each in half) weighing (250±50) g were used. METHODS: Twenty SD rats were divided into four groups at random. ① Blank control group (n=5): The rats were not treated without dexamethasone or irradiation;② Irradiation group (n=5): The rats were given irradiation but no dexamethasone treatment; ③ Irradiation+1 mg/kg dexamethasone group (n=5); The rats were treated with irradiation and dexamethasone of 1 mg/kg; ④Irradiation+5 mg/kg dexamethasone group (n=5): The rats were treated with irradiation and dexamethasone of 5 mg/kg. The heads of the rats were irradiated with 10 MeV X-ray (30 Gy), and brain tissue was removed after 2 weeks to observe the pathological changes. Blood samples were taken from the carotid artery, gradient centrifugation was used, and neutrophile layer was obtained, the level of neutrophile expression of CD18 mRNA and quantity of membrane proteins in blood were detected with Northern blot and flow cytometry respectively. MAIN OUTCOME MEASURES: ① Blood cell count; ② Pathological results; ③ level of neutrophile expression of CD18 mRNA and quantity of membrane proteins. RESULTS : All the 20 SD rats were involved in the analysis of results without deletion. At 2 weeks after irradiation, obvious cell injury could be observed under light microscope. The level of neutrophile expression of CD18 mRNA and quantity of membrane proteins in blood were obviously increased, but the severity of cell injury was relieved in the irradiation+1 and 5 mg/kg dexamethasone groups, and the CD18 expression was markedly suppressed (P 〈 0.05), and the suppression was more obvious in the irradiation+5 mg/kg dexamethasone group than in the irradiation+1 mg/kg dexamethasone group (P 〈 0.01 ). CONCLUSION: Dexamethasone can reduce the radiation induced brain edema by inhibiting the expression of CD18.
基金supported by the Guangdong Education Science Planning Project(2024GXJK612).
摘要This study examined how social desirability responses confound the relationship between gender and social media addiction.A total of 496 college student social media users(females=310,62.5%,mean age=20.15,SD=1.26)completed an online questionnaire on Social Media Addiction and Social Desirability.Mediation analysis revealed that females were at higher risk for social media addiction.On the other hand,the indirect effect of gender on social media addiction via social desirability is associated with lower social media addiction,which suggests that social desirability had a suppression effect on social media addiction associated with gender.ANOVA results showed that females reported higher social media addiction scores than males in the low social desirability group;in the high group,gender differences were insignificant.This study’s unique contribution is to suggest that females are at higher risk than males for developing addictive social media behaviors.Based on this finding,student social media safety interventions should be gender sensitive to the social desirability effect on females who may hide their true addiction as a result.
基金supported by the National Natural Science Foundation of China(Grant No.22209013)。
摘要Developing multivalent-ion storage systems demands cathode materials that combine high structural adaptability with favorable orbital interactions to host sluggish,highly charged carriers such as Ca2+.Herein,a multi-synergistic interlayer engineering strategy is proposed via Ca2+interlayer coordination.The pre-coordination of Ca2+ions establishes Mn-O-Ca bridges that not only expand the interlayer distance but also reshape the local orbital field of Mn,thereby stabilizing the high-valence Mn states and suppressing Jahn-Teller distortion.Defect-induced orbital reconfiguration simultaneously enhances electronic delocalization and interlayer polarity by creating localized charge imbalances at oxygen vacancies.As a result,efficient charge transfer and Ca2+diffusion are promoted,and more surface-active sites are exposed.Electrochemical evaluations reveal that Ca-MnO2exhibits significantly improved reversible capacity(~100 mA h g-1at 0.1 A g-1)and long-term cycling stability(1200 cycles at 1 A g-1),outperforming pristineδ-MnO2.Kinetic analysis through CV,GITT,and EIS demonstrates enhanced Ca2+diffusion coefficients and reduced polarization in the pre-intercalated material.These results demonstrate an orbital-coupled interlayer engineering route toward high-performance Mn-based hosts for nextgeneration multivalent batteries.